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Selected Works

2014

Shi Xue Dou

High

Articles 1 - 8 of 8

Full-Text Articles in Physical Sciences and Mathematics

High Performance Pure Sulfur Honeycomb-Like Architectures Synthesized By A Cooperative Self-Assembly Strategy For Lithium Sulfur Batteries, Xin Liang, Mohammad Kaiser, Konstantin Konstantinov, Richard Tandiono, Zhaoxiang Prof Zhaoxiang Wang, Hua-Kun Liu, S X. Dou, Jiazhao Wang Oct 2014

High Performance Pure Sulfur Honeycomb-Like Architectures Synthesized By A Cooperative Self-Assembly Strategy For Lithium Sulfur Batteries, Xin Liang, Mohammad Kaiser, Konstantin Konstantinov, Richard Tandiono, Zhaoxiang Prof Zhaoxiang Wang, Hua-Kun Liu, S X. Dou, Jiazhao Wang

Shi Xue Dou

Honeycomb-like pure sulfur architectures were synthesized by a cooperative self-assembly strategy, in which a soft template is used to form the porous structure. Their electrochemical performance is significantly improved comparing with the commercial sulfur powder and the as-prepared sulfur without honeycomb morphology. There has been no report on using a soft template to prepare honeycomb-like sulfur particles.


High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou Oct 2014

High-Performance Sodium-Ion Batteries And Sodium-Ion Pseudocapacitors Based On Mos2/Graphene Composites, Yunxiao Wang, Shulei Chou, David Wexler, Hua-Kun Liu, S X. Dou

Shi Xue Dou

Sodium-ion energy storage, including sodium-ion batteries (NIBs) and electrochemical capacitive storage (NICs), is considered as a promising alternative to lithium-ion energy storage. It is an intriguing prospect, especially for large-scale applications, owing to its low cost and abundance. MoS2 sodiation/desodiation with Na ions is based on the conversion reaction, which is not only able to deliver higher capacity than the intercalation reaction, but can also be applied in capacitive storage owing to its typically sloping charge/discharge curves. Here, NIBs and NICs based on a graphene composite (MoS2/G) were constructed. The enlarged d-spacing, a contribution of the graphene matrix, and the …


Ultra-High Performance, High-Temperature Superconducting Wires Via Cost-Effective, Scalable, Co-Evaporation Process, Ho-Sup Kim, Sang-Soo Oh, Hong-Soo Ha, Dojun Youm, Seung-Hyun Moon, Jung Ho Kim, S X. Dou, Yoon-Uk Heo, Sung-Hun Wee, Amit Goyal Oct 2014

Ultra-High Performance, High-Temperature Superconducting Wires Via Cost-Effective, Scalable, Co-Evaporation Process, Ho-Sup Kim, Sang-Soo Oh, Hong-Soo Ha, Dojun Youm, Seung-Hyun Moon, Jung Ho Kim, S X. Dou, Yoon-Uk Heo, Sung-Hun Wee, Amit Goyal

Shi Xue Dou

Long-length, high-temperature superconducting (HTS) wires capable of carrying high critical current, Ic, are required for a wide range of applications. Here, we report extremely high performance HTS wires based on 5 μm thick SmBa2Cu3O7 − δ (SmBCO) single layer films on textured metallic templates. SmBCO layer wires over 20 meters long were deposited by a cost-effective, scalable co-evaporation process using a batch-type drum in a dual chamber. All deposition parameters influencing the composition, phase, and texture of the films were optimized via a unique combinatorial method that is broadly applicable for co-evaporation of other promising complex materials containing several cations. …


Formation Of Magnesium Diboride-Based Materials With High Critical Currents And Mechanical Characteristics By High-Pressure Synthesis, Tetiana Prikhna, W. Gawalek, Ya M. Savchuk, N. V. Sergienko, V. E. Moshchil, M. Wendt, M. Zeisberger, T. Habisreuther, V. B. Sverdun, S X. Dou, S. N. Dub, V. S. Melnikov, Ch Schmidt, J. Dellith, P. A. Nagorny Mar 2014

Formation Of Magnesium Diboride-Based Materials With High Critical Currents And Mechanical Characteristics By High-Pressure Synthesis, Tetiana Prikhna, W. Gawalek, Ya M. Savchuk, N. V. Sergienko, V. E. Moshchil, M. Wendt, M. Zeisberger, T. Habisreuther, V. B. Sverdun, S X. Dou, S. N. Dub, V. S. Melnikov, Ch Schmidt, J. Dellith, P. A. Nagorny

Shi Xue Dou

The developed method of high-pressure synthesis (HPS) allows producing nanostructural highly dense material based on MGB2, which possesses the highest superconducting and mechanical characteristics among the known world analogues, in the form of blocks that are suitable for application in SC electromotors and pumps. Additions of Zr can increase critical current density (jc) of synthesized at 2 GPa and 750-800 °C MGB2 in the same manner as additions of Ta or Ti, i.e. due to the absorption of impurity hydrogen forming the ZrH2. The formation of ZrB2 phase at higher synthesis temperatures (about 950 °C) in HPS MGB2 does not …


Three-Dimensional-Network Li3v2(Po4) 3/C Composite As High Rate Lithium Ion Battery Cathode Material And Its Compatibility With Ionic Liquid Electrolytes, Jiantie Xu, Shulei Chou, Cuifeng Zhou, Qinfen Gu, Hua-Kun Liu, S X. Dou Mar 2014

Three-Dimensional-Network Li3v2(Po4) 3/C Composite As High Rate Lithium Ion Battery Cathode Material And Its Compatibility With Ionic Liquid Electrolytes, Jiantie Xu, Shulei Chou, Cuifeng Zhou, Qinfen Gu, Hua-Kun Liu, S X. Dou

Shi Xue Dou

A high performance Li3V2(PO4)3 cathode material for lithium ion batteries was synthesized by the microwave-assisted hydrothermal method followed by a post annealing process. The synchrotron X-ray diffraction analysis results confirmed that single-phase Li3V2(PO4)3 with monoclinic structure was obtained. Scanning electron microscope and transmission electron microscope images revealed that the as-prepared Li3V 2(PO4)3 was composed of nanowires and microsized particles. Electrochemical results demonstrated that the Li 3V2(PO4)3 electrode measured at 10 C after 500 cycles can deliver discharge capacities of 85.4 mAh g-1 and 103.4 mAh g-1, with a capacity retention of 99.3% and 95.9%, in the voltage ranges of 3.0-4.3 …


Synergetic Combination Of Limd With Chpd For The Production Of Economical And High Performance Mgb2 Wires, Minoru Maeda, Md Shahriar Ai Hossain, Ashkan Motaman, Jung Ho Kim, Anna Kario, Matt Rindfleisch, Mike Tomsic, S X. Dou Mar 2014

Synergetic Combination Of Limd With Chpd For The Production Of Economical And High Performance Mgb2 Wires, Minoru Maeda, Md Shahriar Ai Hossain, Ashkan Motaman, Jung Ho Kim, Anna Kario, Matt Rindfleisch, Mike Tomsic, S X. Dou

Shi Xue Dou

We propose an economical fabrication concept, the localized internal magnesium diffusion (IMD) method. Instead of using a single magnesium (Mg) rod in the center of a metal sheath tube, we use large-sized Mg particles (20-50 mesh) mixed well with cheap 97% crystalline boron powder to fill the metal sheath tube. After a repeated drawing process, the coarse Mg is elongated along the core wire axis of the metal sheath tube. Textured MgB2 grains are then formed during the sintering process. In the localized IMD process, however, there is still a need to improve the overall density. In order to increase …


A Hybrid Electrolyte Energy Storage Device With High Energy And Long Life Using Lithium Anode And Mno2 Nanoflake Cathode, Shulei Chou, Yun-Xiao Wang, Jiantie Xu, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou Mar 2014

A Hybrid Electrolyte Energy Storage Device With High Energy And Long Life Using Lithium Anode And Mno2 Nanoflake Cathode, Shulei Chou, Yun-Xiao Wang, Jiantie Xu, Jia-Zhao Wang, Hua-Kun Liu, S X. Dou

Shi Xue Dou

A hybrid electrolyte energy storage system combining the features of supercapacitors and lithium batteries has been constructed. It consists of MnO2 nanoflakes in 1 M Li2SO4 aqueous electrolyte as the cathode and lithium foil in ionic liquid (1 M lithium bis(trifluoromethanesulfonyl)imide (LiNTf2) in N-methyl-N-propyl pyrrolidinium bis(trifluoromethanesulfonyl)imide ([C(3)mpyr][NTf2])) electrolyte as the anode, separated by a lithium super ionic conductor glass ceramic film (LiSICON). This system shows the advantages of both a supercapacitor (long cycle life) and a lithium battery (high energy), as well as low cost and improved safety due to the combination of ionic liquid and ceramic solid state electrolyte …


The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou Mar 2014

The Electrochemical Properties Of High-Capacity Sulfur/Reduced Graphene Oxide With Different Electrolyte Systems, Yunxiao Wang, Shulei Chou, Hua-Kun Liu, S X. Dou

Shi Xue Dou

The lithium/sulfur battery is a promising electrochemical system with high capacity, which is well-known to undergo a complex multistep reaction during the discharge process. Two types of electrolytes including poly (ethylene glycol) dimethyl ether (PEGDME)-based and 1.3 - dioxolane (DOL)/ dimethoxyethane (DME)-based electrolytes were investigated here. Furthermore, LiNO3 additive was introduced into the electrolyte in order to effectively eliminate the overcharge effect. The lithium sulfur battery with 1.0 M LiN(CF3SO2)2 in PEGME with 0.1 M LiNo3 shows highly stable reversible capacity of 624.8 mAh g-1 after 200 cycles and improved average coulombic efficiency of 98 percent.