Physical Sciences and Mathematics Commons^™

Influence Of Line Tension On Spherical Colloidal Particles At Liquid-Vapor Interfaces, Sean P. Mcbride, Bruce M. Law

Dr. Sean P. McBride

Atomic force microscopy (AFM) imaging of isolated submicron dodecyltrichlorosilane coated silica spheres, immobilized at the liquid polystyrene- (PS-) air interface at the PS glass transition temperature, Tg , allows for determination of the contact angle θ versus particle radius R . At Tg , all θ versus R measurements are well described by the modified Young’s equation for a line tension τ=0.93  nN . The AFM measurements are also consistent with a minimum contact angle θmin and minimum radius Rmin , below which single isolated silica spheres cannot exist at the PS-air interface.

Fracture And Failure Of Nanoparticle Monolayers And Multilayers, Yifan Wang, Pongsakorn Kanjanaboos, Edward Barry Edward Barry, Sean P. Mcbride, Xiao-Min Lin, Heinrich M. Jaeger

Dr. Sean P. McBride

We present an experimental investigation of fracture in self-assembled gold nanoparticle mono- and multilayers attached to elastomer substrates and subjected to tensile stress. Imaging the fracture patterns down to the scale of single particles provides detailed information about the crack width distribution and allows us to compare the scaling of the average crack spacing as a function of strain with predictions by shear-lag models. With increasing particle size, the fracture strength is found to increase while it decreases as the film thickness is built up layer by layer, indicating stress inhomogeneity in the thickness dimension.

Nanoparticle Plasmonics: Going Practical With Transition Metal Nitrides, U. Guler, V. M. Shalaev, A. Boltasseva

U. Guler

Promising designs and experimental realizations of devices with unusual properties in the field of plasmonics have attracted a great deal of attention over the past few decades. However, the high expectations for realized technology products have not been met so far. The main complication is the absence of robust, high performance, low cost plasmonic materials that can be easily integrated into already established technologies such as microelectronics. This review provides a brief discussion on alternative plasmonic materials for localized surface plasmon applications and focuses on transition metal nitrides, in particular, titanium nitride, which has recently been shown to be a …

Real-Time Mri-Guided Catheter Tracking Using Hyperpolarized Silicon Particles, Nicholas Whiting, Jingzhe Hu, Jay V. Shah, Maja C. Cassidy, Erik Cressman, Niki Zacharias Millward, David G. Menter, Charles M. Marcus, Pratip K. Bhattacharya

Nicholas Whiting

Magnetism Of Zn-Doped Sno2: Role Of Surfaces, Pushpa Raghani, Balaji Ramanujam

Pushpa Raghani

Surface effects on the magnetization of Zn-doped SnO2 are investigated using first principles method. Magnetic behavior of Zn-doped bulk and highest and lowest energy surfaces—(001) and (110), respectively, are investigated in presence and absence of other intrinsic defects. The Zn-doped (110) and (001) surfaces of SnO2 show appreciable increase in the magnetic moment (MM) compared to Zn-doped bulk SnO2. Formation energies of Zn defects on both the surfaces are found to be lower than those in bulk SnO2. Zn doping favors the formation of oxygen vacancies. The density of states analysis on the Zn-doped (110) surface reveals that the spin …

Superspin Glass Behaviour Of Interacting Ferromagnetic Nanoparticles In Discontinuous Magnetic Multilayers, Christian Binek

Christian Binek

Discontinuous magnetic multilayers [Co80Fe20(t)/Al2O3(3nm)]10 with t = 0.9 and 1.0nm are studied by SQUID magnetometry and ac susceptibility. Owing to dipolar interaction the superparamagnetic cluster systems undergo collective glass-like freezing upon cooling. While both samples exhibit very similar glass temperatures Tg » 45 K and critical exponents zn » 10 and g » 1.4 as obtained from the temperature dependencies of the relaxation time, t, and the nonlinear susceptibility, c3, dynamical scaling reveals different critical exponents, b(0.9nm) »1.0 and b(1.0nm) » 0.6, respectively.

Nonextensivity In Magnetic Nanoparticle Ensembles, Christian Binek, Srinivas Polisetty, Xi He, Tathagata Mukherjee, Rajasekaran Rajesh, Jody G. Redepenning

Christian Binek

A superconducting quantum interference device and Faraday rotation technique are used to study dipolar interacting nanoparticles embedded in a polystyrene matrix. Magnetization isotherms are measured for three cylindrically shaped samples of constant diameter but various heights. Detailed analysis of the isotherms supports Tsallis' conjecture of a magnetic equation of state that involves temperature and magnetic field variables scaled by the logarithm of the number of magnetic nanoparticles. This unusual scaling of thermodynamic variables, which are conventionally considered to be intensive, originates from the nonextensivity of the Gibbs free energy in three-dimensional dipolar interacting particle ensembles. Our experimental evidence for nonextensivity …

Ordering Of Glass Rods In Nematic And Cholesteric Liquid Crystals, A. T. Juhl, Deng-Ke Yang, V. P. Tondiglia, L. V. Natarajan, Timothy J. White, Timothy J. Bunning

Deng-Ke Yang

The orientational assembly of glass rods (3 x similar to 15 mu m) in nematic, twisted nematic, and cholesteric liquid crystal cells was observed and quantified with optical microscopy. At this size, the rods were affected strongly by gravity and sedimented to the bottom of the cells. Temporal visualization of the sedimentation process (induced by flipping the cell over) shed insight into the effect the liquid crystal order had on the glass rod orientation. For nematic and twisted nematic geometries, the glass rods were aligned parallel to the local director orientation. Control experiments indicate that the rod alignment is not …

A Benchmark Study On The Thermal Conductivity Of Nanofluids, Jacopo Buongiomo, David C. Venerus, Naveen Prabhat, Thomas Mckrell, Jessica Townsend, Rebecca Christianson, Yuriv V. Tolmachev, Pawel Keblinski, Lin-Wen Hu, Jorge L. Alvarado, In Cheol Bang, Sandra W. Bishnoi, Marco Bonetti, Anselmo Cecere, Yun Chang, Gang Chen, Haisheng Chen, Sung Jae Chung, Minking K. Chyu, Sarit K. Das, Roberto Di Paola, Yulong Ding, Frank Dubois, Grzegorz Dzido, Jacob Eapen, Denis Funfschilling, Quentin Galand, Jinwei Gao, Patricia E. Gharagozloo, Kenneth E. Goodson, Jorge Gustavo Gutierrez, Haiping Hong, Mark Horton, Kyo Sik Hwang, Carlo S. Iorio, Seok Pil Jang, Andrzej B. Jarzebski, Yiran Jiang, Stephan Kabelac, Liwen Jin, Aravind Kamath, Chongyoup Kim, Ji-Hyun Kim, Seokwon Kim, Seung Hyun Lee, Kai Choong Leong, Indranil Manna, Rui Ni, Hrishikesh E. Patel, Cecil Reynaud, Raffaele Savino, Pawan K. Singh, Pengxiang Song, Thirumalachari Sundararajan, Alekzandr N. Turanov, Stefan Van Vaerenbergh, Dongsheng Wen, Sanjeeva Witharana, Chun Yang, Wei-Hsun Yeh, Xiao-Zheng Zhao, Sheng-Qi Zhou

Rebecca J. Christianson

This article reports on the International Nanofluid Property Benchmark Exercise, or INPBE, in which the thermal conductivity of identical samples of colloidally stable dispersions of nanoparticles or “nanofluids,” was measured by over 30 organizations worldwide, using a variety of experimental approaches, including the transient hot wire method, steady-state methods, and optical methods. The nanofluids tested in the exercise were comprised of aqueous and nonaqueous basefluids, metal and metal oxide particles, near-spherical and elongated particles, at low and high particle concentrations. The data analysis reveals that the data from most organizations lie within a relatively narrow band (±10% or less) about …

Effect Of Particle Properties And Light Polarization On The Plasmonic Resonances In Metallic Nanoparticles, U. Guler, R. Turan

U. Guler

The resonance behavior of localized surface plasmons in silver and gold nanoparticles was studied in the visible and near-infrared regions of the electromagnetic spectrum. Arrays of nano-sized gold (Au) and silver (Ag) particles with different properties were produced with electron-beam lithography technique over glass substrates. The effect of the particle size, shape variations, period, thickness, metal type, substrate type and sulfidation were studied via transmission and reflectance measurements. The results are compared with the theoretical calculations based on the DDA simulations performed by software developed in this study. We propose a new intensity modulation technique based on localized surface plasmons …

Organo-Soluble Photoresponsive Azo Thiol Monolayer-Protected Gold Nanorods, Jouliana M. El Khoury, Xiaoli Zhou, Liangti Qu, Liming Dai, Augustine Urbas, Quan Li

Quan Li

Organo-soluble photoresponsive azo thiol monolayer-protected gold nanorods were synthesized; the resulting gold nanorods encapsulated by thiols on their entire surface with strong covalent Au-S linkages were very stable in both organic solvents and in the solid state without aggregation or decomposition.

Cavity Resonances Of Metal-Dielectric-Metal Nanoantennas, Bhuwan Joshi, Qi-Huo Wei

Qi-Huo Wei

We propose a new design of optical nanoantennas and numerically study their optical properties. The nanoantennas are composed of two cylindrical metal nanorods stacked vertically with a circular dielectric disk spacer. Simulation results show that when the dielectric disk is less than 5nm in thickness, such nanoantennas exhibit two types of resonances: one corresponding to antenna resonance, the other corresponding to cavity resonances. The antenna resonance generates a peak in scattering spectra, while the cavity resonances lead to multiple dips in the scattering spectra. The cavity resonant frequency can be tuned by varying the size of the dielectric disk. The …