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Trimethylsulfonium Methanesulfonate, Frank R. Fronczek, Rolanda J. Johnson, Robert M. Strongin
Trimethylsulfonium Methanesulfonate, Frank R. Fronczek, Rolanda J. Johnson, Robert M. Strongin
Chemistry Faculty Publications and Presentations
In the title compound, C3H9S+.CH3O3S-, a thermal decomposition product of dimethyl sulfoxide, both cation and anion lie on mirror planes. In the cation, the S atom lies 0.792 (2) Å out of the plane defined by the three C atoms, with S-C distances of 1.781 (2) and 1.786 (3) Å. In the anion, the S-O distances are 1.4556 (14) and 1.4646 (19) Å, and the S-C distance is 1.759 (3) Å.