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Molecular Fluorescence At A Rough Surface: The Orientation Effects, William Lee Blacke
Molecular Fluorescence At A Rough Surface: The Orientation Effects, William Lee Blacke
Dissertations and Theses
The interaction between an emitting molecular dipole and a conducting substrate with a periodic surface roughness is looked at with particular interest in the different orientations of the dipole with respect to the substrate surface. A previous dynamical, perturbative theory for the effects of perpendicular dipole is extended to treat a dipole oriented parallel to the surface of the substrate. The results are then applied to study the modified fluorescence characteristics of the emitting dipoles. Numerical results demonstrate that some fluorescence characteristics are extremely sensitive to the molecular orientation with the dipole oriented along the grating (x direction) exhibiting unique …