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Full-Text Articles in Physical Sciences and Mathematics
Formaldehyde Hemiacetal Sampling, Recovery, And Quantification From Electronic Cigarette Aerosols, James C. Salamanca, Ian Munhenzva, Jorge O. Escodedo, R. Paul Jensen, Angela Shaw, Robert Campbell, Wentai Luo, David H. Peyton, Robert Strongin
Formaldehyde Hemiacetal Sampling, Recovery, And Quantification From Electronic Cigarette Aerosols, James C. Salamanca, Ian Munhenzva, Jorge O. Escodedo, R. Paul Jensen, Angela Shaw, Robert Campbell, Wentai Luo, David H. Peyton, Robert Strongin
Chemistry Faculty Publications and Presentations
The electronic cigarette solvents propylene glycol and glycerol are known to produce toxic byproducts such as formaldehyde, acetaldehyde and acrolein. However, the aerosol toxin yield depends upon a variety of chemical and physical variables. The formaldehyde hemiacetals derived from these solvents were reported as major electronic cigarette aerosol components by us in 2015. In the study described herein, the formaldehyde hemiacetals were found at higher levels than those of free formaldehyde via an orthogonal sample collection protocol. In addition, the common aldehyde collection methods for electronic cigarettes, such as impingers and sorbent tubes containing DNPH, significantly underestimate the levels of …
Benzene Formation In Electronic Cigarettes, James F. Pankow, Kilsun Kim, Kevin J. Mcwhirter, Wentai Luo, Jorge O. Escobedo, Robert M. Strongin, Anna K. Duell, David H. Peyton
Benzene Formation In Electronic Cigarettes, James F. Pankow, Kilsun Kim, Kevin J. Mcwhirter, Wentai Luo, Jorge O. Escobedo, Robert M. Strongin, Anna K. Duell, David H. Peyton
Chemistry Faculty Publications and Presentations
The heating of the fluids used in electronic cigarettes (“e-cigarettes”) used to create “vaping” aerosols is capable of causing a wide range of degradation reaction products. We investigated formation of benzene (an important human carcinogen) from e-cigarette fluids containing propylene glycol (PG), glycerol (GL), benzoic acid, the flavor chemical benzaldehyde, and nicotine.
Solvent Chemistry In The Electronic Cigarette Reaction Vessel, Robert Paul Jensen, Robert M. Strongin, David H. Peyton
Solvent Chemistry In The Electronic Cigarette Reaction Vessel, Robert Paul Jensen, Robert M. Strongin, David H. Peyton
Chemistry Faculty Publications and Presentations
Knowledge of the mechanism of formation, levels and toxicological profiles of the chemical products in the aerosols (i.e., vapor plus particulate phases) of e-cigarettes is needed in order to better inform basic research as well as the general public, regulators, and industry. To date, studies of e-cigarette emissions have mainly focused on chromatographic techniques for quantifying and comparing the levels of selected e-cigarette aerosol components to those found in traditional cigarettes. E-cigarettes heat and aerosolize the solvents propylene glycol (PG) and glycerol (GLY), thereby affording unique product profiles as compared to traditional cigarettes. The chemical literature strongly suggests that there …