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Full-Text Articles in Physical Sciences and Mathematics

Development And Application Of A Gg-Irms Reductive Pyrolysis Reactor Interface For The Δ34S Determination Of Sulfur In Individual Organic Compounds, N. Deborah Hewlett Oct 2005

Development And Application Of A Gg-Irms Reductive Pyrolysis Reactor Interface For The Δ34S Determination Of Sulfur In Individual Organic Compounds, N. Deborah Hewlett

Chemistry & Biochemistry Theses & Dissertations

The incorporation of sulfur into sedimentary organic matter is an important aspect of organic carbon preservation. A better understanding of the sulfur cycle and the formation of organo-sulfur compounds are necessary if we are to better understand the interaction of biogeochemical cycles of C, N, O, H. and S. Currently, the determination of 34S/32S in organic matter is limited to bulk organic samples. The sulfur isotopic analysis of individual organo-sulfur compounds within the sediments should allow for a more complete understanding of the sulfur cycle and the processes which lead to sulfur incorporation into organic matter. This …


Correlation And Causes Of Fifth Order Cycles Within The Upper Cretaceous Eagle Formation, Bighorn Basin Of Wyoming, Kimberly Ann Johnson Apr 2005

Correlation And Causes Of Fifth Order Cycles Within The Upper Cretaceous Eagle Formation, Bighorn Basin Of Wyoming, Kimberly Ann Johnson

OES Theses and Dissertations

Cyclic stratification was examined in the Upper Cretaceous (Santonian-Campanian) section (Eagle Formation) within the Bighorn Basin of Wyoming. Of particular concern was the 103 to 104 year band, which in marine settings has been attributed to orbital forcing (Milankovitch cyclicity). A series of 19 sections were measured through the Virgelle Member of the Eagle Formation. Most were measured on the “J”-shaped escarpment that constitutes the nose and north flank of the Thermopolis anticline. Several others were measured at sites up to 30 km to the northwest along paleo-shoreline. In the study, detailed thickness data of all sections and …


Iron In The Sargasso Sea (Bermuda Atlantic Time-Series Study Region) During Summer: Eolian Imprint, Spatiotemporal Variability, And Ecological Implications, Peter N. Sedwick, T. M. Church, A. R. Bowie, C. M. Marsay, S. J. Ussher, K. M. Achilles, P. J. Lethaby, R. J. Johnson, M. M. Sarin, D. J. Mcgillicuddy Jan 2005

Iron In The Sargasso Sea (Bermuda Atlantic Time-Series Study Region) During Summer: Eolian Imprint, Spatiotemporal Variability, And Ecological Implications, Peter N. Sedwick, T. M. Church, A. R. Bowie, C. M. Marsay, S. J. Ussher, K. M. Achilles, P. J. Lethaby, R. J. Johnson, M. M. Sarin, D. J. Mcgillicuddy

OES Faculty Publications

We report iron measurements for water column and aerosol samples collected in the Sargasso Sea during July-August 2003 (summer 2003) and April-May 2004 (spring 2004). Our data reveal a large seasonal change in the dissolved iron (dFe) concentration of surface waters in the Bermuda Atlantic Time-series Study region, from ∼1-2nM in summer 2003, when aerosol iron concentrations were high (mean 10 nmol/m-3), to ∼0.1-0.2nM in spring 2004, when aerosol iron concentrations were low (mean 0.64 nmol/m-3). During summer 2003, we observed an increase of ∼0.6nM in surface water dFe concentrations over 13 days, presumably due to …


Burial Of Terrestrial Organic Matter In Marine Sediments: A Re-Assessment, David J. Burdige Jan 2005

Burial Of Terrestrial Organic Matter In Marine Sediments: A Re-Assessment, David J. Burdige

OES Faculty Publications

Calculations based on recent observations indicate that approximately one third of the organic matter presently being buried in marine sediments may be of terrestrial origin, with the majority of this terrestrial organic matter (TOM) burial occurring in muddy, deltaic sediments. These calculations further suggest that the remineralization of terrestrial organic matter in the oceans is also much less efficient than that of marine organic matter. These two underappreciated observations have important implications in terms of our understanding of the controls on the global carbon cycle. From a paleoceanographic perspective, the results presented here also suggest that changes in TOM burial …


A Unique Seasonal Pattern In Phytoplankton Biomass In Low-Latitude Waters In The South China Sea, Chun-Mao Tseng, George T. F. Wong, I.-I. Lin, C.-R. Wu, K.-K. Liu Jan 2005

A Unique Seasonal Pattern In Phytoplankton Biomass In Low-Latitude Waters In The South China Sea, Chun-Mao Tseng, George T. F. Wong, I.-I. Lin, C.-R. Wu, K.-K. Liu

OES Faculty Publications

A distinctive seasonal pattern in phytoplankton biomass was observed at the South East Asian Time series Study (SEATS) station (18°N, 116°E) in the northern South China Sea (SCS). Surface chlorophyll-a, depth integrated chlorophyll-a and primary production were elevated to 0.3 mg/m3, ~35 mg/m2 and 300 mg-C/m2/d, respectively, in the winter but stayed low, at 0.1 mg/m3, ~15 mg/m2 and 110 mg-C/m2/d as commonly found in other low latitude waters, in the rest of the year. Concomitantly, soluble reactive phosphate and nitrate+nitrite in the mixed layer also became …


Hydrographic And Biological Changes In The Taiwan Strait During The 1997-1998 El Niño Winter, S. Shang, C. Zhang, H. Hong, Q. Liu, G. T. F. Wong, C. Hu, B. Huang Jan 2005

Hydrographic And Biological Changes In The Taiwan Strait During The 1997-1998 El Niño Winter, S. Shang, C. Zhang, H. Hong, Q. Liu, G. T. F. Wong, C. Hu, B. Huang

OES Faculty Publications

During the 1997–1998 El Niño event, the average sea surface temperature (SST) in the Taiwan Strait (TWS) in the winter was ~1.4°C higher than that of the winter climatological mean. The areal ratio of the warm water (≥2°C above the regional mean) to the cold water (≥2°C below the regional mean) in the TWS increased by 25% while the area of the eutrophic water (chlorophyll a >1 mg m-3) was halved. Field observations also indicate that the mixed layer in the TWS became more nutrient-poor during this winter. These observations are consistent with a diminished advection of the …


Variability Of Sea Ice Cover In The Chukchi Sea (Western Arctic Ocean) During The Holocene, Anne De Vernal, Claude Hillaire-Marcel, Dennis A. Darby Jan 2005

Variability Of Sea Ice Cover In The Chukchi Sea (Western Arctic Ocean) During The Holocene, Anne De Vernal, Claude Hillaire-Marcel, Dennis A. Darby

OES Faculty Publications

Dinocysts from cores collected in the Chukchi Sea from the shelf edge to the lower slope were used to reconstruct changes in sea surface conditions and sea ice cover using modern analogue techniques. Holocene sequences have been recovered in a down-slope core (B15: 2135 m, 75°44'N, sedimentation rate of ~1cm kyr-1) and in a shelf core (P1: 201 m, 73°41'N, sedimentation rate of ~22 cm kyr-1). The shelf record spanning about 8000 years suggests high-frequency centennial oscillations of sea surface conditions and a significant reduction of the sea ice at circa 6000 and 2500 calendar (cal) …