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Full-Text Articles in Physical Sciences and Mathematics
Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna
Identification And Quantitation Of Volatile Amines In Chesapeake Bay Sediments, Neeraja Y. Krishna
Chemistry & Biochemistry Theses & Dissertations
Sediments from different parts of the Chesapeake Bay were analyzed to determine the presence of volatile amines. A HF-HCl extraction method was used to extract both exchangeable and fixed amines from the sediments and a purge-and-trap technique was used to concentrate the amines. Following derivatization with heptafluorobutyric anhydride (HFBA), the HFBA-amines were analyzed by gas chromatography with electron capture detection and with mass spectrometric detection. One primary amine, i-amylamine with a concentration ranging from 0. 78 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty seven samples collected on three different dates in 1993. Another primary amine, 2-methylbutylamine with a concentration ranging from 0.18 nmoles/g dry weight to < 0.05 nmoles/g dry weight was found in a total of twenty three samples collected on three different dates in 1993. A secondary amine, diethylamine was detected but could not be quantified in a total of seven samples collected in September 1993. The concentrations of these amines varied with location in the Bay, depth in the sediment, and time of year the sediments were collected. The origin of i-amylamine and 2-methylbutylamine might be from the biological decarboxylation of amino acids leucine and isoleucine, respectively. The origin of diethylamine is unknown.
Description, Distribution, And Abundance Of The Blue Crab, Callinectes Sapidus (Rathbun), Spawning Stock Of The Lower Chesapeake Bay, Patrick John Geer
Description, Distribution, And Abundance Of The Blue Crab, Callinectes Sapidus (Rathbun), Spawning Stock Of The Lower Chesapeake Bay, Patrick John Geer
OES Theses and Dissertations
The lower Chesapeake Bay spawning stock of the blue crab, Callinectes sapidus, (Rathbun), is examined for seven years (1986 - 1992) in an attempt to better understand stock behavior. Three methods of post-stratification are used to describe the distribution and movement of the population over time. The three methods, density strata, geographic zones, and depth strata, did well in explaining movements of the population, indicating a trend of increased concentration of blue crabs near the eastern Bay late in the spawning season - October. The data suggest a bimodal period of spawning and a trimodal period of abundance. The …
Age, Growth, And Mortality Of Atlantic Croaker, Micropogonias Undulatus, In The Chesapeake Bay Region, With A Discussion Of Apparent Geographic Changes In Population Dynamics, Luiz R. Barbieri, Mark E. Chittenden Jr., Cynthia M. Jones
Age, Growth, And Mortality Of Atlantic Croaker, Micropogonias Undulatus, In The Chesapeake Bay Region, With A Discussion Of Apparent Geographic Changes In Population Dynamics, Luiz R. Barbieri, Mark E. Chittenden Jr., Cynthia M. Jones
OES Faculty Publications
Atlantic croaker, Micropogonias undulatus, collected from commercial catches in Chesapeake Bay and in Virginia and North Carolina coastal waters during 1988-1991 (n=1,967) were aged from transverse otolith sections. Ages 1-8 were recorded, but eight-year-old fish were rare. Marginal increment analysis showed that for ages 1-7, annuli are formed once a year during the period April-May. Otolith age readings were precise: >99% agreement within and between readers. Observed lengths-at-age were highly variable and growth rate decreased after the first year. Despite the high variability in sizes-at-age, observed lengths for ages 1-7 fit the von Bertalanffy growth model (r2=0.99; n=753) well. …
Seasonal Relationships Between Phytoplankton Composition, Abundance, And Primary Productivity In Three Tidal Rivers Of The Lower Chesapeake Bay, Harold G. Marshall, Kneeland K. Nesius
Seasonal Relationships Between Phytoplankton Composition, Abundance, And Primary Productivity In Three Tidal Rivers Of The Lower Chesapeake Bay, Harold G. Marshall, Kneeland K. Nesius
Biological Sciences Faculty Publications
The seasonal abundance and successional patterns of phytoplankton, including autotrophic picoplankton, are compared to spring, summer, and fall primary production maxima that occurred in three tidal rivers. The tidal freshwaters were dominated by diatoms, chlorophytes, and cyanobacteria during a late spring through early fall period of maximum growth. In contrast, downstream assemblages were dominated by estuarine diatoms, dinoflagellates, and cryptomonads which developed spring pulses and a protracted summer-fall maximum. Autotrophic picoplankton produced a major summer pulse at all river stations with reduced abundance during other seasons. The mean annual productivity rates for the tidal James, Rappahannock, and York rivers were …
Spatial And Temporal Occurrence Of Spanish Mackerel Scomberomorus Maculatus In Chesapeake Bay, Mark E. Chittenden Jr., Luiz R. Barbieri, Cynthia M. Jones
Spatial And Temporal Occurrence Of Spanish Mackerel Scomberomorus Maculatus In Chesapeake Bay, Mark E. Chittenden Jr., Luiz R. Barbieri, Cynthia M. Jones
OES Faculty Publications
No abstract provided.