Physical Sciences and Mathematics Commons^™

Copper Complexation And Speciation In The Western South And Equatorial Atlantic Ocean, John A. Consolvo

Chemistry & Biochemistry Theses & Dissertations

Presented here are the first data on copper complexation and speciation in the South Atlantic Ocean. Samples were collected at six vertical profile stations and along the surface (1m) transect during the 1996 IOC Baseline Contaminant Survey. Copper complexation measurements were made for the surface transect (1m) samples and three of the six vertical profile stations (1m - ~500m) using differential pulse anodic stripping voltammetry (DPASV) with a thin mercury film, rotating glassy carbon disk electrode (TMFRGCDE).

A strong organic copper complexing ligand (L₁; log K' _cuL1/cu2+ > 11. 8 ± 0 .4) was detected in 57% of all …

Fourier Transform Raman Spectroscopy For Process Control In The Petroleum Industry, Kent Lawson Wise

Chemistry & Biochemistry Theses & Dissertations

As early as 1950, Raman spectroscopy was proposed as a method to determine aromatics and olefins in hydrocarbon mixtures. Until recently, extensive use of Raman spectroscopy in the characterization of hydrocarbons has not been practical due to several limitations. One early limitation to Raman analysis was the absence of a high intensity and stable excitation source. This problem has been overcome with the advent of lasers. Another limitation was the presence of fluorescence in hydrocarbon fuels when excited by visible lasers. However, the development of Fourier-transform Raman spectrometers now allows Raman spectra to be collected using near-IR lasers (e.g …

Identity, Conflict And Cooperation In International River Basins, Jack V. Kalpakian

Graduate Program in International Studies Theses & Dissertations

This dissertation tests the hypothesis that water disputes cause serious conflict within and between states. It uses a structured case study approach to see whether there is a link between the independent and dependent variables. It also considers the effect of other variables on serious conflict. Specifically it addresses the effects of national identity and the othering process on conflict. The three case studies are built around rivers in the drier parts of the world. This biases the dissertation towards affirming the established mainstream hypothesis which states that water disputes cause serious conflict. In all three cases, historical animosities and …

Design Of Adaptive Sliding Mode Fuzzy Control For Robot Manipulator Based On Extended Kalman Filter, Abdelrahman Aledhaibi

Mechanical & Aerospace Engineering Theses & Dissertations

In this work, a new adaptive motion control scheme for robust performance control of robot manipulators is presented. The proposed scheme is designed by combining the fuzzy logic control with the sliding mode control based on extended Kalman filter. Fuzzy logic controllers have been used successfully in many applications and were shown to be superior to the classical controllers for some nonlinear systems. Sliding mode control is a powerful approach for controlling nonlinear and uncertain systems. It is a robust control method and can be applied in the presence of model uncertainties and parameter disturbances, provided that the bounds of …

Investigations On The Use Of Ion Mobility Spectrometry For Clinical Chemistry Applications, Henri Parson Patten

Theses and Dissertations in Biomedical Sciences

The major objective of this research is to examine ion mobility spectrometry as a rapid screening tool for specific application to clinical chemistry research and laboratory use. Methodology was developed for target analytes representing several classes of physiologically active substances, including anesthetics, illicit drugs, and their metabolites. The IMS characteristics of animal tissues and other compounds such as amino acids and proteins were determined. Quality assurance and control procedures were developed for specific quality data objectives. Criteria were established relating to use of IMS for assessing the precision and accuracy of data, qualitative screening, and semi-quantitative analyses.

It was found …

Buckets: Smart Objects For Digital Libraries, Michael L. Nelson

Computer Science Theses & Dissertations

Discussion of digital libraries (DLs) is often dominated by the merits of various archives, repositories, search engines, search interfaces and database systems. While these technologies are necessary for information management, information content and information retrieval systems should progress on independent paths and each should make limited assumptions about the status or capabilities of the other. Information content is more important than the systems used for its storage and retrieval. Digital information should have the same long-term survivability prospects as traditional hardcopy information and should not be impacted by evolving search engine technologies or vendor vagaries in database management systems.

Digital …

Advanced Atmospheric Water Vapor Dial Detection System, Tamer Refaat

Electrical & Computer Engineering Theses & Dissertations

Measurement of atmospheric water vapor is very important for understanding the Earth's climate and water cycle. The remote sensing Differential Absorption Lidar (DIAL) technique is a powerful method to perform such measurement from aircraft and space. This thesis describes a new advanced detection system, which incorporates major improvements regarding sensitivity and size. These improvements include a low noise advanced avalanche photodiode detector, a custom analog circuit, a 14-bit digitizer, a microcontroller for on board averaging and finally a fast computer interface.

This thesis describes the design and validation of this new water vapor DIAL detection system which was integrated onto …

Effects Of Elevated Atmospheric Co2 On Root Growth, Turnover And Decomposition In A Scrub Oak Ecosystem, John Joseph Dilustro

Biological Sciences Theses & Dissertations

Atmospheric carbon dioxide levels are increasing and predicted to double this century. The implications of this rise on vegetation structure and function are not well understood. Measurement of root growth response to elevated atmospheric carbon dioxide is critical to understanding soil carbon input. I investigated the effects of elevated carbon dioxide on fine root growth and decomposition using open top chambers with both ambient and elevated (700 PPM) CO₂ treatments in an oak-palmetto scrub ecosystem at Kennedy Space Center, Florida. Minirhizotron tubes were installed in each elevated and control chamber to allow observation of roots. Each tube was sampled …

Phenomenological Description Of Double-Pion Photoproduction, Andry M. Rakotovao

Physics Theses & Dissertations

Double pion photoproduction off proton targets is studied, in the framework of an Effective Lagrangian approach at tree level, based on the coupling of photons and pions to nucleons and resonances. We consider N, Δ(1232), N(1440), N(1520) and N(1535) as intermediate baryonic states and ρ-meson as the intermediate 2π resonance. The general form of the amplitude is presented and total cross sections of the γp → π⁺π− p, γp → π⁰π⁰p and γp → π ⁺π⁰n processes are evaluated up to Eγ …

Resolution Of Overlapping Spectra By Wavelength Modulation Spectroscopy, Audra Michiele Bullock

Electrical & Computer Engineering Theses & Dissertations

Wavelength modulation absorption spectroscopy is a highly sensitive, non-intrusive technique for probing gaseous species, which employs the well-known principles of modulation spectroscopy in a novel way. With this technique, parameters such as velocity, density, and temperature can be measured with a high degree of precision. The research presented here shows that wavelength modulation is a convenient means of increasing the sensitivity of an absorption spectroscopy measurement because it allows for harmonic detection. The focus of the dissertation is resolution of overlapping spectra by harmonic detection and the advantages gained by performing detection at the higher harmonics, e.g., sixth and eighth. …

Electroweak Structure Of Three-And Four-Body Nuclei, Laura Elisa Marcucci

Physics Theses & Dissertations

This work reports results for (i) the elastic electromagnetic form factors of the trinucleons; (ii) the nuclear response functions of interest in [e → e'] experiments, at excitation energies below the deuteron breakup threshold; (iii) the astrophysical S-factor for proton weak capture on ³He (the hep reaction). The initial and final state wave functions are calculated using the correlated hyperspherical harmonics method, from a realistic Hamiltonian consisting of the Argonne ^v18 two-nucleon and Urbana IX three-nucleon interactions. The nuclear electroweak charge and current operators include one- and many-body components. The predicted magnetic form factor of …

Diffusion Problems In Wound Healing And A Scattering Approach To Immune System Interactions, Julia Suzanne Arnold

Mathematics & Statistics Theses & Dissertations

A theoretical model for the existence of a Critical Size Defect (CSD) in certain animals is the focus of the majority of this dissertation. Adam [1] recently developed a one-dimensional model of this phenomenon, and chapters I–V address the exist the CSD in a two-dimensional model and a three-dimensional model. The two dimensional (or 1-d circular) model is the more appropriate for a study of CSD's. In that model we assume a circular wound of uniform depth and develop a time-independent form of the diffusion equation relevant to the study of the CSD phenomenon. It transpires that the range of …

A Semantic-Based Middleware For Multimedia Collaborative Applications, Agustin Jose Gonzalez

Computer Science Theses & Dissertations

The Internet growth and the performance increase of desktop computers have enabled large-scale distributed multimedia applications. They are expected to grow in demand and services and their traffic volume will dominate. Real-time delivery, scalability, heterogeneity are some requirements of these applications that have motivated a revision of the traditional Internet services, the operating systems structures, and the software systems for supporting application development. This work proposes a Java-based lightweight middleware for the development of large-scale multimedia applications. The middleware offers four services for multimedia applications. First, it provides two scalable lightweight protocols for floor control. One follows a centralized model …

Generalized Compton Amplitudes In Quantum Chromodynamics, Ignati Grigentch

Physics Theses & Dissertations

In this dissertation we describe results of our studies of generalized Compton amplitudes. We have calculated the one-loop corrections to the amplitude in the coordinate representation in terms of nonlocal string light-ray operators. We have also developed a consistent approach to the problem of constructing the gauge invariant Compton amplitude and obtained an expression for the explicitly gauge invariant amplitude which includes all the generalized target-mass corrections.

Precision Measurement Of The Spin Structure Of The Proton And The Deuteron, Frank R. Wesselmann

Physics Theses & Dissertations

Experiment E155 at the Stanford Linear Accelerator Center measured the spin structure functions g1 and g2 of the proton and deuteron using deep inelastic scattering of 50 GeV polarized electrons from dynamically polarized, solid ¹⁵NH₃ and ⁶LiD targets. Three independent spectrometers, covering a large kinematic region, 0.014 < x_Bjorken < 0.9 and 1 < Q² < 40 (GeV /c)^2, detected 200 million events. A fully self-consistent and statistically sound approach to calculating radiative corrections was developed, providing well-defined statistical errors for the E155 data set. Also, a comprehensive fit to the global data set was created which simultaneously …

An Object-Oriented Algorithmic Laboratory For Ordering Sparse Matrices, Gary Karl Kumfert

Computer Science Theses & Dissertations

We focus on two known NP-hard problems that have applications in sparse matrix computations: the envelope/wavefront reduction problem and the fill reduction problem. Envelope/wavefront reducing orderings have a wide range of applications including profile and frontal solvers, incomplete factorization preconditioning, graph reordering for cache performance, gene sequencing, and spatial databases. Fill reducing orderings are generally limited to—but an inextricable part of—sparse matrix factorization.

Our major contribution to this field is the design of new and improved heuristics for these NP-hard problems and their efficient implementation in a robust, cross-platform, object-oriented software package. In this body of research, we (1) examine …

An Examination Of A Multidimensional Model Of Customer Satisfaction With Internet Purchasing, Kathleen Vanscoyoc

Theses and Dissertations in Business Administration

The World Wide Web and Internet have transformed the competitive business environment and altered the customer-firm relationship by creating a new retailing format and service enterprise. It is rapidly growing as a competitive distribution medium in which customer satisfaction will be a major success factor in the development and maintenance of this new retailing format. Despite its growing importance as a new shopping medium, little empirical research has been conducted that examines the relationship between Internet shopping, customer satisfaction, company image, and future online purchasing. Research is needed to develop theoretical models that will systematically explain and predict behavior related …

Multicast Services For Multimedia Collaborative Applications, Emad Eldin Mohamed Mohamed

Computer Science Theses & Dissertations

This work aims at providing multicast services for multimedia collaborative applications over large inter-networks such as the Internet. Multimedia collaborative applications are typically of small group size, slow group membership dynamics, and awareness of participants' identities and locations. Moreover, they usually consist of several components such as audio, video, shared whiteboard, and single user application sharing engines that collectively help make the collaboration session successful. Each of these components has its demands from the communication layer that may differ from one component to another. This dissertation identifies the overall characteristics of multimedia collaborative applications and their individual components. It also …

Virtual Compton Scattering In The Nucleon Resonance Region, Luminita Anca Todor

Physics Theses & Dissertations

This thesis is a study of virtual Compton scattering reaction in which a virtual photon is elastically scattered off a proton γv p → γp. The p( e,e′p)γ reaction was measured in the nucleon resonance region for the first time in the experiment E93-050 in Hall A at Thomas Jefferson National Accelerator Facility. To lowest order in ^αQED, this reaction is a coherent superposition of radiation from the incident or scattered electron in elastic ep scattering (Bethe-Heitler) and exclusive production of a photon on the proton, by absorption of a virtual photon …

Extending Traditional Static Analysis Techniques To Support Development, Testing And Maintenance Of Component-Based Solutions, Robert David Cherinka

Computer Science Theses & Dissertations

Traditional static code analysis encompasses a mature set of techniques for helping understand and optimize programs, such as dead code elimination, program slicing, and partial evaluation (code specialization). It is well understood that compared to other program analysis techniques (e.g., dynamic analysis), static analysis techniques do a reasonable job for the cost associated with implementing them. Industry and government are moving away from more ‘traditional’ development approaches towards component-based approaches as ‘the norm.’ Component-based applications most often comprise a collection of distributed object-oriented components such as forms, code snippets, reports, modules, databases, objects, containers, and the like. These components are …

Experimental Investigation Of Long-Lived "Zeke" Rydberg States In Ultracold Argon, Gambhir Ranjit

Physics Theses & Dissertations

There is considerable interest in the dynamics of ultracold plasmas and ultracold Rydberg gases. Ultracold plasmas are typically formed by photo-excitation of ultracold atoms to an energy region near (both above and below) an ionization threshold. Excitation to bound, highly-excited Rydberg states can lead to formation of a plasma via several processes, including collisions between Rydberg atoms. Three-body recombination in an ultracold plasma can also result in the production of ultracold Rydberg atoms. Understanding the dynamics of ultracold Rydberg gases is therefore important for understanding the dynamics of ultracold plasmas. In this dissertation, we have investigated the formation and survival …

An Architectural Framework For Performance Analysis: Supporting The Design, Configuration, And Control Of Dis /Hla Simulations, David B. Cavitt

Computer Science Theses & Dissertations

Technology advances are providing greater capabilities for most distributed computing environments. However, the advances in capabilities are paralleled by progressively increasing amounts of system complexity. In many instances, this complexity can lead to a lack of understanding regarding bottlenecks in run-time performance of distributed applications. This is especially true in the domain of distributed simulations where a myriad of enabling technologies are used as building blocks to provide large-scale, geographically disperse, dynamic virtual worlds. Persons responsible for the design, configuration, and control of distributed simulations need to understand the impact of decisions made regarding the allocation and use of the …