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Synthesis And Process Optimization Of Colloidal Unimolecular Polymer, Cup, Particle Formation, And Its Interfacial Surface Tension Behavior, Ashish Zore

Doctoral Dissertations

"Colloidal Unimolecular Polymer (CUP) particles are 3-9 nm size single-chain polymer nanoparticles that are made from amphiphilic acrylic co-polymers using the process of water reduction. The formation of CUP particles was driven by the polymer-polymer interactions being greater than polymer-solvent interactions as well as the charge-charge repulsion due to the increasing dielectric of the medium. CUPs provide a surfactant or additive-free nanoparticle system that was useful for studying the interfacial behavior of pure aqueous nanoparticles using a maximum bubble pressure tensiometer. The equilibrium surface tension shows a dependence on concentration and the charge density of the CUP particle. The equilibrium …