Physical Sciences and Mathematics Commons^™

Strong-Coupled Piezoelectric Polaron, Wayne E. Tefft

Physics Faculty Research & Creative Works

A semiclassical, variational calculation for the strong-coupled piezoelectric polaron gives the following results for the ground-state energy and polaron radius, respectively: U0=-0.47(m*/m) (κ²/ε)²eV, and R=3.5(ε/κ²) (m/m*)â ã where m* is the band effective mass, κ is the electromechanical coupling constant, and ε is the strain-free dielectric constant. The theory is expected to be valid when |U0| is larger than thermal energies and R is considerably larger than unit-cell dimensions. A calculation of the polaron effective mass, having a more limited region of validity, gives mp~m*[1+2|U0|/m*vs²], where vs is the velocity of sound. …

Survival Probability In Dissociative Attachment, Joseph C.Y. Chen, Jerry Peacher

Physics Faculty Research & Creative Works

The survival probability in dissociative attachment is investigated with special attention to the (e, H₂ ) system. It is shown that the simple expression for the dissociative-attachment cross section, as given by the product of a capture cross section and a survival probability, is equivalent to the s -wave approximation for the g → g dissociative attachment. This expression, however, does not constitute an approximation for the g → u dissociative attachment, since the parity of the initial rotational states of H₂ is always opposite to that of the relative angular momentum states of H and H- …

Rapid Calculation Of Electron Scattering Factors, Jerry Peacher, John G. Wills

Physics Faculty Research & Creative Works

The phase amplitude method is used to reduce the radial Schrödinger equation to two separate differential equations, one for the phase and one for the amplitude. These functions are both smooth as opposed to the rapidly oscillating solution of the radial Schrödinger equation for electron energies in the kilovolt range. The partial-wave phase shifts were obtained rapidly by integrating the differential equations for the phase and amplitude numerically. Hartree-Fock and Thomas-Fermi-Dirac fields were used in the calculation. Results for argon and uranium are given in order to compare with previous results. It was found that the WKBJ approximation to the …

Tolerance Regions For A Joint Exponential Distribution, Lee J. Bain

Mathematics and Statistics Faculty Research & Creative Works

The evaluation of the reliability of a system of components, when the components are assumed to follow a joint exponential distribution, is considered. The approach used is to develop tolerance regions for the joint exponential distribution or to estimate the probability content of the appropriate specification region. Copyright © 1968 by The Institute of Electrical and Electronics Engineers, Inc.

The Role Of The Doctor Of Engineering Degree In Graduate Education, Wouter Bosch, Robert E. Carlile

Chemistry Faculty Research & Creative Works

No abstract provided.

Analysis Of Trace Elements In River And Spring Waters, Faridoon Andeshire Namdarian

Masters Theses

"Methods for the analysis of trace elements in natural fresh waters were investigated.

Preconcentration of the water samples by reducing the volume and by using cation adsorption resins was studied. It was concluded that cation absorption was the more promising procedure.

The methods used for analysis were absorption spectrophotometry, neutron activation analysis, and atomic absorption spectrophotometry. Atomic absorption spectrophotometry was considered the most suitable method for the analysis of trace elements in waters.

Calcium, copper, lead, zinc, and cadmium were determined in a number of Missouri springs and stream water samples"--Abstract, page ii.

Handlos And Baron Model: Short Contact Times, J. Patel, Robert M. Wellek

Chemical and Biochemical Engineering Faculty Research & Creative Works

No abstract provided.

The Anodic Dissolution Of Cadmium, James W. Johnson, E. Deng, S. C. Lai, William Joseph James

Chemical and Biochemical Engineering Faculty Research & Creative Works

The anodic dissolution of cadmium has been studied in aqueous solutions containing Cl−, Br−, I−, Ac−, SO₄=, and NO3− ions. The normal valence (+2) was found in all solutions with the exception of NO₃−. The apparent valence (calculated) of cadmium ions in nitrate solutions varied from 1.2 to 2.0 and was found to be a function of NO₃− concentration, current density, and temperature. An anodic dissolution mechanism has been proposed involving local corrosion and disintegration of the anode which is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.

Radial Pressure Gradient In Turbulent Pipe Flow, Gary Kent Patterson, Walter J. Ewbank, Virgil A. Sandborn

Chemical and Biochemical Engineering Faculty Research & Creative Works

Measurements made with a Prandtl static pressure probe have demonstrated that a radial pressure gradient does exist in turbulent pipe flow with approximately the magnitude predicted by Sandborn from hot-wire anemometry measurements.

The Mechanism Of The Electrooxidation Of Acetylene On Gold, James W. Johnson, J. L. Reed, William Joseph James

Chemical and Biochemical Engineering Faculty Research & Creative Works

Acetylene has been oxidized anodically in aqueous solutions at 80 °C on gold electrodes. It was found that the partial oxidation to CO₂ was accompanied by a polymer formation. Effects of potential, acetylene partial pressure, pH, and temperature on the rate (current) were measured. A discontinuity in the Tafel curves was noted that indicated a change in the reaction mechanism with potential. The discontinuity was also pH dependent. A mechanism involving the discharge of H₂O and/or OH− has been proposed that is consistent with the experimental results. © 1967, The Electrochemical Society, Inc. All rights reserved.

The Effect Of Concentration On The Viscosities Of Solutions Of Linear Flexible High Polymers, Lung Yu Chou, Jacques L. Zakin

Chemical and Biochemical Engineering Faculty Research & Creative Works

Viscosity-concentration results in the moderately concentrated range for four samples of polyisobutylene (molecular weights of 1.3 x 104 to 1.0 x 106) in cyclohexane (concentrations up to 4.7 g./dl.) and in benzene (concentrations up to 7.0 g./dl.) at 24°C. (a theta solvent) showed molecular weight and goodness of solvent dependencies similar to those reported earlier for three other polymers. For polyisobutylene, polystyrene, and a copolymer of styrene and methyl methaerylate in good solvents, viscosity-concentration data plotted as ηsp. C[η] vs. k′[η]C fit a single curve. The linear region of this curve suggests that the Huggins equation is useful to C[η] …

Effect Of Environmental Hydrogen Pressure On The Hydrogen Yield From X‐Irradiated Polyethylenes, Otto H. Hill, R. Pat Lightfoot

Physics Faculty Research & Creative Works

An experimental assembly incorporating a capacitance‐type, differential pressure transducer, which provides resolutions of 3 x 10−4 torr at pressures extending to 30 torr, has been employed to monitor the effect of hydrogen environmental pressure on the hydrogen yield from x‐irradiated polyethylene's. Contrary to the observations of previous investigators, the hydrogen yield is found to be independent of hydrogen environmental pressures extending over the critical range up to at least 30 torr. It is demonstrated that neglecting the temperature and density gradients inherent in closed‐volume irradiation assemblies employing cryogenic traps to separate liberated gases into condensable and non condensable fractions may …

Studies In Coprecipitation Of Trace Amounts Of Elements, Gerald Delano Schucker

Masters Theses

"A new approach to preconcentration of trace amounts of elements has been demonstrated whereby traces of metals tied up as chelates are coprecipitated on a column of solid organic material. Complete coprecipitation was found to occur within very narrow pH ranges, thereby allowing separation as well as concentration of the elements by careful adjustment of acidity and concentration of chelating agent. The separation is based on the difference in stability constants of the metal chelates. Preliminary studies with different physical forms of the carrier precipitate, indicate adsorptive processes could play a significant role in the mechanism of the column-coprecipitation process. …

A Calorimetric Study Of The Effects Of Surface Energy In A Type Ii Superconductor, Robert Rex Rice

Doctoral Dissertations

"A calorimetric study of the effects of the interphase surface free energy has been conducted on ellipsoidal samples of first and second kind superconductors. The measurements were performed using a specially designed magnetization calorimeter by two different techniques. The measurements were made on lead, tin, lead-4at%thallium, and tin-6at% indium. The results confirm the existence and experted sign of the surface energy in a well annealed lead-4at%thallium sample, and indicate that the interphase surface energy in lead and tin is too small to be directly detected by this method. The measured latent heats of transition of lead and tin agree well …

Kilocycle Range Dislocation Damping In Dilute Magnesium Alloy Single Crystals, Robert Ray Nothdurft

Doctoral Dissertations

"The kilocycle range dislocation damping and Young's modulus of single crystals of magnesium and single crystals of magnesium containing small additions of lithium, zinc, or aluminum have been studied as a function of strain amplitude, temperature, and time during annealing and following a high strain amplitude vibration. The data are compared to the Granato-Lücke theory of dislocation damping, the Granato-Hikata-Lücke theory for the recovery of damping following plastic deformation, and the Yamafuji-Bauer theory for the recovery of damping following a high strain amplitude vibration. Reasonable qualitative agreement is obtained between the Granato-Lücke theory and the observed dependence of the damping …

Ferroelectric Properties Of Pbzro₃-Bifeo₃ Solid Solutions, Robert Gerson, Pen-Chu Chou, William Joseph James

Physics Faculty Research & Creative Works

Solid solutions of BiFeO and PbZrO₃ were investigated for crystallographic and dielectric properties. A new pseudocubic perovskite phase was found, which has been tentatively indexed as orthorhombic with the same unit cell as PbZrO₃ but with dielectric properties characteristic of a ferroelectric substance. The Curie point in this series of solid solutions has a minimum of about 155°C at a composition of about (PbZrO₃)_0.80 (BiFeO₃)_0.20, which at room temperature lies on the boundary between the orthorhombic antiferroelectric and the pseudocubic ferroelectric phases. This composition has a relative dielectric constant of 800 …

Anodic Dissolution Of Zinc In Potassium Nitrate, Martin E. Straumanis, J. L. Reed, William Joseph James

Materials Science and Engineering Faculty Research & Creative Works

The apparent valence of pure zinc dissolving anodically in 3% KNO₃ was determined as a function of current density, temperature, and ultrasonic agitation. The apparent valence of zinc dissolving anodically at 24°C diminishes from 2.01 ± 0.01 at low current densities to 1.86 at about 50 ma and remains fairly constant up to about 80 ma cm−2. This valence is affected to some extent by the preparation, e.g., polishing of the electrode, but is independent of its structure (mono- or polycrystal). Ultrasonic vibrations do not influence the apparent valence at high current densities. In all cases a black film …

A Theoretical Investigation Of Elastic And Voigt Transient Spherical Waves, And Plane Three-Element Viscoelastic Waves, Edward Hornsey

Doctoral Dissertations

"A mathematical model of explosive generated waves in rock is needed in many areas of engineering endeavor. Investigations to date have been unsuccessful in obtaining a model that satisfactorily represents real wave phenomena at all radial distances and in all of the important characteristics.

In this investigation, spherical waves in elastic and Voigt media were investigated. Series solutions for plane waves in a three-element viscoelastic medium were obtained. A dual exponential pressure pulse, P(t) = P_o (e^-αt-e^-ßt) was assumed because it can exhibit significant features of real pressure pulses while avoiding instantaneous rise time, which …

Study Of Resonance Effects In Allenic And Related Systems, Robert Andrew Steinkamp

Doctoral Dissertations

"In order to investigate the possibility of resonance effects through a non-coplanar substituted acetylene, synthesis of bis-(2,5,8-trimethyl-l-naphthyl)-acetylene was attempted. Condensation of acetylene with 2,5,8-trimethyl-l-tetralone to yield an acetylenic glycol followed by dehydration and dehydrogenation was expected to yield the desired non-coplanar acetylene. Comparison of its ultraviolet spectrum with that of di-l-naphthyl-acetylene would have suggested the true nature of the acetylene pi cloud. The acetylene condensation was unsuccessful, however.

Substituted allenes, which contain one sp hybridized carbon atom, were then successfully synthesized for a similar analysis of potential resonance effects. A series of para-substituted 4-phenyl-2-methylbutadienoic acids were synthesized and their pKa's …

Magnetic Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, James Ivan Latham

Doctoral Dissertations

"The magnetic susceptibility and spontaneous magnetic moment of the perovskitic, polycrystalline solid solutions of BiFeO₃ with PbTiO₃, PbZrO₃, and [50PbZrO₃·50PbTiO₃] were determined using the Faraday method. Pure BiFeO₃ has a G-type antiferromagnetic structure. Although the perovskite BiFeO₃ exhibits a sharp peak in the susceptibility at the Néel temperature, it does not possess a spontaneous magnetic moment. The solid solutions investigated possessed a spontaneous magnetic moment throughout the multiple cell rhombohedral region of the BiFeO₃-PbTiO₃-PbZrO₃ ternary phase diagram, which extends from pure BiFeO₃ to …

High Frequency Ferroelectric Properties Of The Bifeo₃-Pbtio₃-Pbzro₃ Ternary System, Robert Travis Smith

Doctoral Dissertations

"High temperature dielectric measurements have been performed on the ferroelectric and antiferroelectric perovskitic polycrystalline solid solutions in the BiFeO₃-PbTiO₃-PbZrO₃ ternary system. The data were taken in the UHF frequency range with the use of a slotted line and specially constructed sample holder capable of operation at temperatures in excess of 800°C.

The Curie points have been found to occur at progressively higher temperatures with the increase of BiFeO₃ content in the solutions except in phase transition regions where minima can occur. The dielectric constants at the Curie temperatures have been found to decrease with …

The Technique Of Lineaments And Linears Analysis And Its Application In The Minerogenic Province Of Southeast Missouri, Hassan A. Etr

Doctoral Dissertations

"Current terminology in the field of lineaments and linears (lineations) analysis was reviewed and quantitative definitions of the common terms offered. A general classification of lineations is herein proposed. Characteristics of drainage and airphoto lineations were reviewed and the procedure used in their analysis discussed.

An area about 1880 square miles was analyzed for lineations based on drainage networks and the resulting patterns showed preferred orientation. These drainage lineations were later compared with the airphoto lineations of the same area and a limited degree of similarity was observed.

The airphoto lineations of an area approximately 7000 sq. mi. covering the …

Basic Iron (Iii) Alkanoate Complexes, Young Hee Kim

Masters Theses

"Much information appears in the literature concerning the preparation, properties and structure of the basic iron (III) acetates...This study was initiated to prepare a number of the basic trinuclear iron (III) alkanoate complexes and to investigate the possibility of a common structure for all of these as suggested by the work of Orgel. The structural investigation was done on the basis of stoichiometric relationships, infrared spectra and magnetic moments"--Abstract, pages ii-iii.

A Study Of The Genesis Of The Pyritic Gneiss In The Grenville Series, St. Lawrence And Jefferson Counties, New York, Dennis O'Leary

Masters Theses

"The pyrite-pyrrhotite belt is a northeast-southwest trending area about 35 miles long and three to four miles wide located in Jefferson and western St. Lawrence counties, New York, within the metamorphosed Grenville Lowland just northwest of the Adirondack massif.

Outcropping within this belt are a number of thin discontinuous quartz-biotite-oligoclase gneisses with an unusually high graphite, chlorite, and pyrite content, known as "rusty gneisses." Sulfides are concentrated in these gneisses into zones of up to 50% or more pyrite. The pyrite is granular or crystalline and is invariably accompanied by large amounts of chlorite and graphite and local minor segregations …

A Study Of The Complexes Of Diketocyclobutenediol, Stewart Michael Condren

Masters Theses

"In this study of the complexes of diketocyclobutenediol, squaric acid, the following original compounds were prepared: zirconyl squarate, indium (III) squarate; titanium (III) squarate, ruthenium (III) squarate, tungsten (VI) squarate, vanadium (III) squarate, and niobium (V) squarate, where squarate refers to the dianion of diketocyclobutenediol. Metal analyses were made on all of these except the ruthenium. However, only three of these metal analyses, namely those for titanium (III) squarate, indium (III) squarate, and zirconyl squarate, warrented [sic] further investigation. Carbon and hydrogen analyses were then made for these three compounds. From the percentage compositions, possible structures were proposed.

The tungsten, …

The Separation Of Optical Isomers By Gas Chromatography, Donald Ellis Carpenter

Masters Theses

"The purpose of this investigation was to study the separation of optical isomers by gas chromatography. An optically inactive solid support was coated with an optically active substrate. Racemic compounds were used as samples. The optically active packing materials tried were d-tartaric acid, d-diethyl tartrate, sucrose, d-camphoric acid, d-camphor-10-sulfonic acid, α -methyl-D-glucoside and L-(α)-glutamic acid.

Racemic compounds that were tried included 2-butanol, 3-methyl- 2-butanol, 2-methyl-1-butanol, 2-octanol, 2-bromooctane, 2-methoxy-octane, methyl-2-bromobutyrate, and 3-methylhexane.

It was found that racemic compounds could be separated by using an optically active material for packing in the gas chromatographic columns. Racemic 2-butanol, 3-methyl-2-butanol, and 2-methyl-1- butanol were …

Infrared Spectra And Magnetic Properties Of Fluorine Substituted Copper (Ii) Alkanoates, Jose G. Rodriguez

Masters Theses

"The purpose of this study was to prepare some selected copper(II) fluorcalkanoates, investigate their magnetic susceptibilities, study the infrared spectra of these salts and compare these properties to those of the unfluorinated copper(II) alkanoates….

The experimental data obtained indicate that the copper(II) trifluoroacetate, perfluoropropanoate and perfluorosuccinate does not form a binuclear cage structure. Copper(II) 3-(trifluoromethyl) butanoate with a magnetic moment of 1.4 should possess a binuclear case structure similar to copper( II) acetate monohydrate. The structure for copper( II) perfluoroglutarate monohydrate with a magnetic moment of 1.63 B.M. should have a structure somewhere between the two aforementioned structures"--Abstract, page ii.

Preparation And Spectra Of Some New Alkyl Ammonium Salts Of The Tetrachlorocuprate (Ii) Ion., Paul Douglas Griffin

Masters Theses

"Several compounds containing the complex tetrachlorocuprate(II) anion, CuCl₄⁼, and various alkyl or aryl cations were prepared. These include bis(methylammonium)tetrachlorocuprate(II), bis(isopropylammoniumtetrachlorocuprate(II), 1,3-propanediammoniumtetrachlorocuprate(II), bis(furfuryl-ammonium)tetrachlorocuprate(II), and a series of ethylene ammonium salts. Some unsuccessful and difficult preparations are described. Spectra were taken in acetone, 4-butyrolactone, and methanoleaf An explanation of the effects of various solvents on the absorption spectrum and structure of the complex ion is given"--Abstract, page ii.

A Petrofabric Study Of The Iron Ore Of Benson Mines, Star Lake, New York, Remo Antonio Masiello

Masters Theses

"The petrofabrics of the host gneiss silicates and Ovate ore grains were studied in thin sections of oriented specimens collected from widely scattered positions in the iron ore deposit at Benson Mines, New York.

Ten oriented specimens selected for petrofabrics study were comprised primarily of feldspar, quartz, garnet and ores, with lesser quantities of biotite and sillimanite. Petrofabric diagrams were prepared for the orientation fabrics of magnetite and biotite in eight of the ten specimens, but sillimanite and quartz were sufficiently abundant for fabric determination in only three specimens. Duplicate thin section and perpendicular sections were utilized to check the …

A Study Of An Electric Method To Excite And Detect Acoustic Waves In Solids, John H. Stevens

Masters Theses

"This experiment has demonstrated that it is possible to generate pulses of acoustic waves in an aluminum single crystal by the direct use of the tensile stress associated with an electric field at the surface of a conductor, and it is possible to detect these waves with a biased, capacitive pickup transducer"--Abstract, page ii.