Physical Sciences and Mathematics Commons^™

Approximation Of The Generalized Singular Value Expansion, Matthew Jacob Roberts

Dissertations, Master's Theses and Master's Reports

Let $X$, $Y$, and $Z$ be real separable Hilbert spaces, let $T:X \to Y$ be a compact operator, and let $L:D(L) \to Z$ be a closed and densely defined linear operator. Then the generalized singular value expansion (GSVE) is an expansion that expresses $T$ and $L$ in terms of a common orthonormal basis. Under certain hypotheses on discretization, the GSVE of an approximate operator pair $(T_j,L_j)$, where $T_j:X_j \to Y_j$ and $L_j:X_j \to Z_j$, converges to the GSVE of $(T,L)$. Error estimates establish a rate of convergence that is consistent with numerical experiments in the case of discretization using piecewise …

Credit Risk Analysis Using Machine Learning And Neural Networks, Dhruv Dhanesh Thanawala

Dissertations, Master's Theses and Master's Reports

A key activity within the banking industry is to extend credit to customers, hence,

credit risk analysis is critical for nancial risk management. There are various methods

used to perform credit risk analysis. In this project, we analyze German and

Australian nancial data from UC Irvine Machine Learning repository, reproducing

results previously published in literature. Further, using the same dataset and various

machine learning algorithms, we attempt to create better models by tuning available

parameters, however, our results are at best comparable to published results.

In this report, we have explained the algorithms and mathematical framework that

goes behind developing …

Optimization And Control Of Arrays Of Wave Energy Converters, Jianyang Lyu

Dissertations, Master's Theses and Master's Reports

Wave Energy Converter Array is a practical approach to harvest ocean wave energy. To leverage the potential of the WEC array in terms of energy extraction, it is essential to have a properly designed array configuration and control system. This thesis explores the optimal configuration of Wave Energy Converters (WECs) arrays and their optimal control. The optimization of the WEC array allows both dimensions of individual WECs as well as the array layout to varying. In the first optimization problem, cylindrical buoys are assumed in the array where their radii and drafts are optimization parameters. Genetic Algorithms are used for …

A Critical Review Of Current Approaches And Practices In Computing Ethics Education, Sophia Farquhar

Dissertations, Master's Theses and Master's Reports

Recent scandals caused by the results of negligent, malicious, or shortsighted software development practices highlight the need for software developers to consider the ethical implications of their work. Computing ethics has historically been a marginalized area within computing disciplines, so educators in these disciplines do not have a common background for teaching the topic. Computing ethics education, although often a required part of coursework, can vary widely in the method of implementation from university to university.

In this report I summarize the insights I gained from interviewing four educators from three different institutions on their pedagogical approaches to computing ethics. …

High Order Bound-Preserving Discontinuous Galerkin Methods And Their Applications In Petroleum Engineering, Ziyao Xu

Dissertations, Master's Theses and Master's Reports

This report contains researches in the theory of high-order bound-preserving (BP) discontinuous Galerkin (DG) method and their applications in petroleum engineering. It contains both theoretical analysis and numerical experiments. The compressible miscible displacements and wormhole propagation problem, arising in petroleum engineering, is used to describe the evolution of the pressure and concentrations of different components of fluid in porous media. The important physical features of concentration and porosity include their boundedness between 0 and 1, as well as the monotone increasing for porosity in wormhole propagation model. How to keep these properties in the simulation is crucial to the robustness …

Bayesian Analysis For The Intraclass Model And For The Quantile Semiparametric Mixed-Effects Double Regression Models, Duo Zhang

Dissertations, Master's Theses and Master's Reports

This dissertation consists of three distinct but related research projects. The first two projects focus on objective Bayesian hypothesis testing and estimation for the intraclass correlation coefficient in linear models. The third project deals with Bayesian quantile inference for the semiparametric mixed-effects double regression models. In the first project, we derive the Bayes factors based on the divergence-based priors for testing the intraclass correlation coefficient (ICC). The hypothesis testing of the ICC is used to test the uncorrelatedness in multilevel modeling, and it has not well been studied from an objective Bayesian perspective. Simulation results show that the two sorts …

Application Of A Distributed Hydrologic Model For The Analysis Of Land Use Change In Kedougou, Senegal, Francisco Perez

Dissertations, Master's Theses and Master's Reports

West Africa has experienced extensive land use/land cover (LULC) change since the Sahel drought of the 1970s and 80s. Demographic changes, rapid urbanization, and other anthropogenic impacts on land cover in West Africa have potentially altered hydrological regimes. This work was undertaken while I served as a Peace Corps Volunteer in the Kedougou region of Senegal, an area that has experienced significant and rapid infrastructural improvements and urbanization since the early 2000s. The Gambia River flows near Kedougou, where flooding is an extensive problem, making access and livelihood practices difficult during the rainy season. Changes in climate and land use …

Near-Infrared Fluorescent Probes For Sensitive Determination Of Lysosomal & Mitochondrial Ph In Live Cells, Wafa Mazi

Dissertations, Master's Theses and Master's Reports

Varied intracellular pH levels are critical for various physiological processes such as enzymatic activity, cell proliferation and apoptosis, ion transport, and muscle contraction. Cellular compartments, like lysosomes, must retain an acidic environment (pH ~ 4.5) to activate hydrolytic enzymes necessary for the breakdown of large biomolecules. Another cellular organelle, the mitochondria, provides the cell with energy and must retain an alkalis environment (pH ~ 8.0) for proper function. Substantial lysosomal and mitochondrial pH deviation is associated with cellular dysfunction and disease. Therefore, the precise detection of lysosomal and mitochondrial pH is essential to provide a better understanding of cellular physiological …

Characterizing Freshwater Phytoplankton Dynamics With Electro-Optical Remote Sensing, Michael Sayers

Dissertations, Master's Theses and Master's Reports

Freshwater lakes are an important component contributing to ecosystem health and biodiversity on local, regional, and global scales. And while lakes only represent <5% of the global surface area, they are often very productive systems which contribute significantly to carbon cycling dynamics and freshwater fish production on a number of spatial scales. Due to the remote location and sheer size of some of these lakes it has proven difficult to adequately document changes in water quality. Significant challenges exist to adequately monitor water quality, and in particular phytoplankton dynamics, over large spatial and temporal scales using traditional in situ methods. Satellite electro-optical remote sensing offers a potential tool to provide better characterization of phytoplankton dynamics for a variety of freshwater systems. This work resulted in an approach to quantify global summer phytoplankton abundance using a newly developed remote sensing derived chlorophyll-a product. This product was also used in conjunction with a newly created carbon fixation model to assess global freshwater phytoplankton production which provided new insights into the role freshwater systems play in the …

Synthesis Of Oligodeoxynucleotides Containing Sensitive Electrophiles, Shahien Shahsavari

Dissertations, Master's Theses and Master's Reports

Oligodeoxynucleotides (ODNs) containing electrophilic groups are useful in many studies including antisense drug development and DNA/protein interaction. Due to the use of strong nucleophiles for cleavage and deprotection, traditional ODN synthesis methods are not suitable for their preparation. To solve this problem, a new ODN synthesis technology using the 1,3- dithiane-2-yl-methoxycarbonyl (Dmoc) function as protecting groups and linker has been developed. Furthermore, Dmoc-derivatives were developed to demonstrate the feasibility of the technology. The Dmoc and Dmoc derivative functions are stable under all ODN synthesis conditions using the phosphoramidite chemistry. Upon oxidation of the sulfides in them, because of the drastically …

Magnetic Characterization Of Iron Formations From Drill Cores Near Iron Mountain, Michigan, Adren Rigdon

Dissertations, Master's Theses and Master's Reports

The magnetic properties of the ~1.88 Ga Vulcan Iron Formation and Felch Formation were investigated from samples taken from three drill cores through the Felch Trough, north of Iron Mountain, MI. The conducted analyses included measurements of natural remanent magnetization, magnetic hysteresis, first order reversal curves, magnetic anisotropy, scanning electron microscopy, and electron dispersive spectroscopy. The data is compared to the results of a previous magnetic characterization study conducted on surface outcrop samples on two members of the Vulcan formation, the Curry and Traders members, near Iron Mountain, MI. Two distinct members of the Vulcan Formation were identified in the …

Keweenaw Fault Geometry And Slip Kinematics - Bête Grise Bay, Keweenaw Peninsula, Michigan, Colin Tyrrell

Dissertations, Master's Theses and Master's Reports

The Keweenaw Fault (KF) has been interpreted as a rift-bounding normal fault along the southern margin of the Midcontinent Rift System; later inverted into a reverse fault by a tectonic compression event. The fault trends NNE to NE for most of its trace but curves clockwise to ESE along the Bête Grise Bay area in Michigan’s Keweenaw Peninsula. U.S. Geological Survey maps depict the KF along Bête Grise Bay as a continuous thrust that follows a sinuous contact between Portage Lake Volcanics (PLV) and Jacobsville Sandstone (JS). New fieldwork reveals a left-stepping en echelon system of ESE-trending faults connected by …

Seismic Signals And Sources At Fuego Volcano, Guatemala During January 2012, Kyle Brill

Dissertations, Master's Theses and Master's Reports

Forecasting volcanic activity is challenging. The task is uniquely difficult at open vent volcanoes which present persistent low-level eruptions over long periods of time. Volcán de Fuego in Guatemala began its current eruptive episode in 1999. Fuego exhibited “background” levels of activity during January of 2012 when we installed a temporary monitoring network to produce a detailed baseline description of the volcano’s behavior. We accomplish this using data from two low-frequency microphone arrays, nine broadband (50 Hz to 30 second flat response) seismic stations, and visual time-lapse imagery collected over a period of ten days. We begin with a detailed …

Discontinuous Galerkin Methods For Convection-Diffusion Equations And Applications In Petroleum Engineering, Nattaporn Chuenjarern

Dissertations, Master's Theses and Master's Reports

This dissertation contains research in discontinuous Galerkin (DG) methods applying to convection-diffusion equations. It contains both theoretical analysis and applications. Initially, we develop a conservative local discontinuous Galerkin (LDG) method for the coupled system of compressible miscible displacement problem in two space dimensions. The main difficulty is how to deal with the discontinuity of approximations of velocity, u, in the convection term across the cell interfaces. To overcome the problems, we apply the idea of LDG with IMEX time marching using the diffusion term to control the convection term. Optimal error estimates in L^infinity(0, T; L^{2 …}

Towards Sustainable Production Of Chemicals And Fuels From The Fast Pyrolysis Of Waste Polyolefin Plastics, Ulises Gracida Alvarez

Dissertations, Master's Theses and Master's Reports

The increasing amount of plastic waste (PW) generation has become an important concern due to the leveled-off recycling rates. Therefore, governmental agencies around the world, including state governments in the United States, have proposed initiatives to minimize the amount of PW that is landfilled and encourage recycling or energy recovery. Circular economy is a strategy that attempts on reusing PW to produce new polymers while avoiding its disposal and the use of virgin material. Chemical recycling raises an interesting technology prospect due to the potential reduction of pollutant emissions and the establishment of a circular economy through the production of …

Method Considerations For Compound Identification In Complex Mixtures Using Electrospray Ionization Ultrahigh Resolution Mass Spectrometry, Tyler Leverton

Dissertations, Master's Theses and Master's Reports

Biomass burning aerosols are highly complex organic mixtures of thousands of components with consequences for global climate. Complex mixture component identification requires accurate mass measurement capability to separate components on a milli-Dalton scale, frequently using ultrahigh resolution mass spectrometry with electrospray ionization. Certain sample preparations and the ionization process may introduce artifacts that obscure the composition of the sample. Two method considerations were explored using isotopically labeled ¹⁵NH₄OH and MeOH-d₃ to track artifact formation in biomass burning samples. Informatics techniques and a custom molecular formula assignment software were used to identify the isotopic atoms in artifact …

Statistical Methods For Joint Analysis Of Multiple Phenotypes And Their Applications For Phewas, Xueling Li

Dissertations, Master's Theses and Master's Reports

Genome-wide association studies (GWAS) have successfully detected tens of thousands of robust SNP-trait associations. Earlier researches have primarily focused on association studies of genetic variants and some well-defined functions or phenotypic traits. Emerging evidence suggests that pleiotropy, the phenomenon of one genetic variant affects multiple phenotypes, is widespread, especially in complex human diseases. Therefore, individual phenotype analyses may lose statistical power to identify the underlying genetic mechanism. Contrasting with single phenotype analyses, joint analysis of multiple phenotypes exploits the correlations between phenotypes and aggregates multiple weak marginal effects and is therefore likely to provide new insights into the functional consequences …

Optical Vortex And Poincaré Analysis For Biophysical Dynamics, Anindya Majumdar

Dissertations, Master's Theses and Master's Reports

Coherent light - such as that from a laser - on interaction with biological tissues, undergoes scattering. This scattered light undergoes interference and the resultant field has randomly added phases and amplitudes. This random interference pattern is known as speckles, and has been the subject of multiple applications, including imaging techniques. These speckle fields inherently contain optical vortices, or phase singularities. These are locations where the intensity (or amplitude) of the interference pattern is zero, and the phase is undefined.

In the research presented in this dissertation, dynamic speckle patterns were obtained through computer simulations as well as laboratory setups …

Some Results On Partial Difference Sets And Partial Geometries, Eric J. Neubert Jr

Dissertations, Master's Theses and Master's Reports

This thesis shows results on 3 different problems involving partial difference sets (PDS) in abelian groups, and uses PDS to study partial geometries with an abelian Singer group. First, the last two undetermined cases of PDS on abelian groups with k ≤ 100, both of order 216, were shown not to exist. Second, new parameter bounds for k and ∆ were found for PDS on abelian groups of order p^n , p an odd prime, n odd. A parameter search on p^5 in particular was conducted, and only 5 possible such cases remain for p < 250. Lastly, the existence of rigid type partial geometries with an abelian Singer group are examined; existence is left undetermined for 11 cases with α ≤ 200. This final study led to the determination of nonexistence for an infinite class of cases which impose a negative Latin type PDS.

Data Set Generation Using Deep Learning Algorithms And Visual Feature Tracking, Kusuma Pallapotu

Dissertations, Master's Theses and Master's Reports

Object detection and classification plays a major role in today's modern technology. The implementations of these concepts range from consumer products to self driving cars. These concepts largely reply on the data sets used for training these models. There is a considerable amount of effort in generating these data sets for every specific application of these algorithms.

In this report, a method for generating image data sets with the use of visual feature tracking and deep learning algorithms for application in autonomous vehicles has been proposed. The aim is to reduce the time and effort dedicated towards the generation of …

Molecular Characterization Of Free Tropospheric Organic Aerosol And The Development Of Computational Tools For Molecular Formula Assignment, Simeon Schum

Dissertations, Master's Theses and Master's Reports

Organic aerosol affects human health and climate. These effects are largely determined by the composition of the organic aerosol, which is a complex mixture of species. Understanding the complexity of organic aerosol is critical to determining its effect on human health and climate. In this study, long range transported organic aerosol collected at the Pico Mountain Observatory was analyzed using ultrahigh resolution mass spectrometry. Organic aerosol transported in the free troposphere had an overall lower extent of oxidation than aerosol transported in the boundary layer. It was hypothesized that the lower oxidation was related to a more viscous phase state …

Location, Orbit And Energy Of A Meteoroid Impacting The Moon During The Lunar Eclipse Of January 21, 2019 & Testing The Weak Equivalence Principle With Cosmological Gamma Ray Bursts, Matipon Tangmatitham

Dissertations, Master's Theses and Master's Reports

Location, orbit and energy of a meteoroid impacting the moon during the Lunar Eclipse of January 21, 2019

During the total lunar eclipse of January 21, 2019 at least two meteoroids impacted the moon producing visible flash lights on the near side. One of the impacts occurred on the darkest side of the visible lunar face and was witnessed by many astrophotographers. In this paper we present estimations of the location, impact parameters (velocity and incoming direction), orbit and energy of the meteoroid, as obtained from images and videos collected by amateur astronomers in Colombia, the Dominican Republic, Morocco, USA, …

Linking Historical, Field, And Satellite Data To Determine The Relationship Between Gas Emissions And Vegetation Change In The Puhimau Geothermal Area East Rift Zone Kilauea, Hawaii, Christie Torres Rosa

Dissertations, Master's Theses and Master's Reports

The Puhimau geothermal area, located near the summit of the Kilauea volcano, Hawaii, has been suggested to represent a ‘window’ into the East Rift Zone. The quantification of CO₂ and H₂S soil gas emissions improves our understanding of its gas emission mode- including total emission and spatial distribution and contribute to a more accurate estimation of total CO₂ and H₂S in the thermal area – and how these gas emissions relate to observed vegetation health from satellite data. The total emission of CO₂ and H₂S was interpolated by the sequential Gaussian …

Aerosol-Cloud Interactions In Turbulent Clouds: A Combined Cloud Chamber And Theoretical Study, Kamal Kant Chandrakar

Dissertations, Master's Theses and Master's Reports

The influence of aerosol concentration on the cloud droplet size distribution is investigated in a laboratory chamber that enables turbulent cloud formation through moist convection. In chapter 2, moist Rayleigh-Bénard convection with water saturated boundaries is explored using a one-dimensional-turbulence model. This study provides some background about supersaturation statistics in moist convection. Chapters 3 - 7 discuss the experimental and theoretical investigation of aerosol-cloud interactions and cloud droplet size-distributions in turbulent conditions. The experiments are performed in a way so that steady-state microphysics are achieved, with aerosol input balanced by cloud droplet growth and fallout. As aerosol concentration is increased …

Towards The Discovery Of Oligonucleotide Cross-Linking Agents, Bhaskar Halami

Dissertations, Master's Theses and Master's Reports

Oligonucleotide cross-linking agents are expected to become a new class of antisense drugs. They function by first hybridizing with a complementary mRNA and then form a covalent bond to permanently link the mRNA to the oligonucleotide agent. Because of covalent cross-linking, this new class of antisense drugs are expected to have much higher potency than existing ones.

Some oligonucleotide cross-linking agents have appeared in the literature, but they have various drawbacks, which include slow cross-linking rate and reversible cross-linking. To address these problems, we designed a series of new cross-linking oligonucleotides with a range of different reactivities. These oligonucleotides were …

Statistical Methods For Mixed Frequency Data Sampling Models, Yun Liu

Dissertations, Master's Theses and Master's Reports

The MIDAS models are developed to handle different sampling frequencies in one regression model, preserving information in the higher sampling frequency. Time averaging has been the traditional parametric approach to handle mixed sampling frequencies. However, it ignores information potentially embedded in high frequency. MIDAS regression models provide a concise way to utilize additional information in HF variables. While a parametric MIDAS model provides a parsimonious way to summarize information in HF data, nonparametric models would maintain more flexibility at the expense of the computational complexity. Moreover, one parametric form may not necessarily be appropriate for all cross-sectional subjects. This thesis …

The Solvation Energy Of Ions In A Stockmayer Fluid, Cameron John Shock

Dissertations, Master's Theses and Master's Reports

The solvation of ions in polar solvents has been a long studied system since the early twentieth century. A common technique to calculate the energy associated with ion solvation is the Born Solvation energy equation. This equation assumes an ion is placed in an incompressible, homogeneous dielectric, which is not necessarily representative of a real system. In this work the Stockmayer Fluid Model is used in a molecular dynamics simulation through the software LAMMPS to check the quantitative correctness of the Born equation. It is also shown how solvation energies of ions placed in polymerized and non-polymerized solvents differ. It …

Application Of Agent-Based Modeling To Complex Systems, Robert J. Zupko Ii

Dissertations, Master's Theses and Master's Reports

This dissertation examines the application of agent-based modeling (ABM) to complex systems with the intent of developing a means of overcoming limitations present in existing tools. This is done though the development of two ABMs intended to address complex systems present in the fields of sustainability studies and chemistry.

After introductory information, Chapters 2 - 4 of this dissertation address the limitations of tools intended to project the environmental, economic, and social impacts of woody biomass based biofuels. Chapter 2 begins by discussing the limitations in tools to study timber harvest decision making and its impact upon the landscape, and …

Energy Transfer Between Eu2+ And Mn2+ For Na(Sr,Ba)Po4 And Ba2mg(Bo3)2, Kevin Bertschinger

Dissertations, Master's Theses and Master's Reports

There is no debate of the affect that solid-state lighting has had on the world we live in. Throughout the centuries, lighting has continued to improve from kerosene lanterns to white light emitting diodes. Even though lighting today is sufficient there is still much room to improve color rendering index and efficiency. An active area of research to improve today's lighting technology is by doping inorganic phosphors with luminescent ion centers. There have been numerous reports of inorganic phosphors showing a variety of emission color and luminescence. In this thesis we discuss two new inorganic phosphors codoped with Eu^{2+ …}

Understanding The Very High Energy Γ-Ray Emission From A Fast Spinning Neutron Star Environment, Chad A. Brisbois

Dissertations, Master's Theses and Master's Reports

Pulsars, and their associated pulsar wind nebulae, are factories producing high energy electrons and positrons in our galaxy. The Dragonfly nebula is a Vela-like pulsar wind nebula in the Cygnus region powered by the spin down of PSR J2021+3651. The TeV γ-ray source 2HWC J2019+367 was originally discovered in 2007 by the Milagro Observatory and has been associated with this pulsar. This dissertation presents the first detailed morphological and spectral study of the TeV emission up to the highest photon energies of 2HWC J2019+367. This analysis has identified two sources, the extended source HAWC J2019+368 and the point source HAWC …