Physical Sciences and Mathematics Commons^™

Nitrogen-Doped And Phosphorus-Doped Epoxy-Sealed Carbon Fiber Ultramicroelectrodes As Electrochemical Sensors For Detection Of Hydrogen Peroxide, Emmanuel Peprah-Yamoah

Electronic Theses and Dissertations

Ultramicroelectrodes (UMEs) are useful as probes for evaluating electroactive species in confined spaces (e.g., inside living cells) and for measuring fast electrochemical reactions. However, UME applications often require modification of the electrode surface to improve selectivity and sensitivity towards target analytes. Previous research in our group demonstrated that a simple soft nitriding method introduces surface nitrogen (N)-containing groups on carbon fiber (CF), leading to improved electroreduction of hydrogen peroxide (H₂O₂) on CF-UMEs. However, sensitivity for H₂O₂ detection using N-CF-UMEs was low compared to that for other modified UMEs. As an alternative to N-CF-UMEs, …

Folic Acid – Carbon Dots – Doxorubicin Nanoparticles As Cancer Theranostic, Michael Tetteh

Electronic Theses and Dissertations

This work focused on engineering bi-functionalized nanoparticles (NPs) based on carbon dots (CDs) to improve early cancer detection and treatment. Therefore, using folic acid (FA) as a targeting agent, the CDs were prepared to deliver high concentrations (HC) of doxorubicin (DOX) and gemcitabine (GEM) covalently and non-covalently to cancer cells. The prepared FA-CDs-DOX/GEM-HC NPs were characterized using ultraviolet-visible spectroscopy, fluorescence spectroscopy, and Fourier transform infrared spectroscopy. Assessment of the drug loading capacity (DLC) and drug loading efficiency (DLE) indicated that the non-covalent NPs have low DLC but high DLE compared to the relatively low DLE and high DLC of covalent …

Fossil Mammals From Hickory Tree Cave, Sullivan County, Tennessee, Alexis Rivera

Electronic Theses and Dissertations

Hickory Tree Cave, also known as Big Spring Cave, is located in the southern Appalachians and is known for fossils that are considered to be Quaternary in age. Fossil mammals were identified and assigned to the lowest taxonomical level possible. Most remains are fragmented or digested and it seems likely that various taphonomic processes are responsible for the resulting assemblage. The site lacks the extreme boreal component of Pleistocene cave faunas in the region (e.g. Baker Bluff Cave), with most reported taxa inhabiting Appalachian deciduous forest environments in North America today. While the presence of tapir (Tapirus sp.) …

Opinion Mining Of Bird Preference In Wildlife Parks, Isiwat Adenopo

Electronic Theses and Dissertations

Opinion Mining is becoming the fastest growing area to extract useful and insightful information to support decision making. In the age of social media, user’s opinions and discussions have become a highly valuable source to look for users preferences, likes, and dislikes.

The industry of wildlife parks (or zoos) is a competitive domain that requires careful analysis of visitor’s opinions to understand and cater for their preferences when it comes to wildlife. In this thesis, an opinion mining approach was proposed and applied on textual posts on the social media platform, Twitter, to extract the popularity, polarity (sentiment), and emotions …

Warming Overcomes Dispersal-Limitation To Promote Non-Native Expansion In Lake Baikal, Larry L. Bowman Jr., Daniel J. Wieczynski, Lev Y. Yampolsky, David M. Post

ETSU Faculty Works

Non-native species and climate change pose serious threats to global biodiversity. However, the roles of climate, dispersal, and competition are difficult to disentangle in heterogeneous landscapes. We combine empirical data and theory to examine how these forces influence the spread of non-native species in Lake Baikal. We analyze the potential for Daphnia longispina to establish in Lake Baikal, potentially threatening an endemic, cryophillic copepod Epischurella baikalensis. We collected field samples to establish current community composition and compared them to model predictions informed by flow rates, present-day temperatures, and temperature projections. Our data and model agree that expansion is currently …

Evaluating Spatial-Temporal Patterns In Us Tornado Occurrence With Space Time Cube Analysis And Linear Kernel Density Estimation: 1950-2019, Darrell L. Wiser

Electronic Theses and Dissertations

This research estimated the spatial-temporal patterns of tornadoes in the continental United States from 1950-2019 using the National Weather Service Storm Prediction Center’s Severe Weather GIS (SVRGIS) database. This study employed Space-Time Cube Analysis and Linear Kernel Density (Kernel Density Linear Process, (KDLP)) rather than the standard Kernel Density Estimation (KDE) approach; to evaluate whether tornado hotspot locations and intensities shift over time.

The first phase of the study utilized KDLP to map changes in tornado hotspots and qualitatively assess decadal shifts in hotspot locations and intensities by occurrence and magnitude between decades using ArcGIS Pro and CrimeStat. Next an …

Reduced Fuel Emissions Through Connected Vehicles And Truck Platooning, Paul D. Brummitt

Electronic Theses and Dissertations

Vehicle-to-infrastructure (V2I) and vehicle-to-vehicle (V2V) communication enable the sharing, in real time, of vehicular locations and speeds with other vehicles, traffic signals, and traffic control centers. This shared information can help traffic to better traverse intersections, road segments, and congested neighborhoods, thereby reducing travel times, increasing driver safety, generating data for traffic planning, and reducing vehicular pollution. This study, which focuses on vehicular pollution, used an analysis of data from NREL, BTS, and the EPA to determine that the widespread use of V2V-based truck platooning—the convoying of trucks in close proximity to one another so as to reduce air drag …

An Evaluation Of Castor Californicus And Implications For The Evolution And Distribution Of The Genus Castor (Rodentia: Castoridae) In North America, Kelly Lubbers

Electronic Theses and Dissertations

The genus Castor is represented in Eurasia by Castor fiber, North America by C. canadensis, and has been in North America since the late Miocene. This study aims to assess whether morphology of Miocene-Pliocene C. californicus and extant C. canadensis are distinctly different. Specimens of Castor were compared using geometric morphometrics on cranial material and linear measurements of postcranial material. Species occurrence data were compared with past and future climate data to assess Castor distribution in North America through time. Results show that C. canadensis is highly variable in both cranial and postcranial morphology and C. californicus falls …

Community Structure Analysis Of Turtles With Application To The Early Pliocene Gray Fossil Site, Julian Conley

Electronic Theses and Dissertations

Turtles are important components of ecosystems around the world, with diverse ecological niches and adaptations. However, there are few detailed studies of how turtle community structure reflects local environments. This project applied techniques of community structure analysis to sites across the United States to infer past ecosystem and environmental conditions of the early Pliocene Gray Fossil Site (GFS) in northeastern Tennessee based on the ancient turtle community. Results indicate extant turtle community structure closely reflects environmental conditions, and that ancient turtle communities can be used to infer climate and habitat conditions of past ecosystems. Application to the GFS turtle community …

The Paleoecology Of High-Elevation Bison In The Greater Yellowstone Ecosystem And Implications For Modern Bison Conservation, Darian Bouvier

Electronic Theses and Dissertations

The national mammal of the United States, the American Bison (Bison bison) was once nearly extinct. Populations have recovered to the degree that thousands roam the Great Plains today. Due to their large numbers and body size, this species has an oversized impact on the ecological communities where it lives and is considered a keystone herbivore in modern North American grasslands. This study explores the detailed, seasonally resolved, paleoecology of seven bison from the Greater Yellowstone Ecosystem during the Late Holocene through stable isotope analyses and species niche modeling. Isotopic analyses of δ¹³C, δ¹⁵N, …

Bbt Acoustic Alternative Top Bracing Cadd Data Set-Norev-2022jun28, Bill Hemphill

STEM Guitar Project’s BBT Acoustic Kit

This electronic document file set consists of an overview presentation (PDF-formatted) file and companion video (MP4) and CADD files (DWG & DXF) for laser cutting the ETSU-developed alternate top bracing designs and marking templates for the STEM Guitar Project’s BBT (OM-sized) standard acoustic guitar kit. The three (3) alternative BBT top bracing designs in this release are
(a) a one-piece base for the standard kit's (Martin-style) bracing,
(b) 277 Ladder-style bracing, and
(c) an X-braced fan-style bracing similar to traditional European or so-called 'classical' acoustic guitars.

The CADD data set for each of the three (3) top bracing designs includes …

Bbt Side Mold Assy, Bill Hemphill

STEM Guitar Project’s BBT Acoustic Kit

This electronic document file set covers the design and fabrication information of the ETSU Guitar Building Project’s BBT (OM-sized) Side Mold Assy for use with the STEM Guitar Project’s standard acoustic guitar kit. The extended 'as built' data set contains an overview file and companion video, the 'parent' CADD drawing, CADD data for laser etching and cutting a drill &/or layout template, CADD drawings in AutoCAD .DWG and .DXF R12 formats of the centerline tool paths for creating the mold assembly pieces on an AXYZ CNC router, and support documentation for CAM applications including router bit specifications, feeds, speed, multi-pass …

Friedel-Crafts Alkylation Of Benzene With A Superacid Catalyst, Josh T. Cutright

Undergraduate Honors Theses

Long-chain alkylbenzenes are industrially synthesized precursors to commercial surfactants such as laundry detergent. The currently used catalysts in the processes of their synthesis are corrosive and harmful to the environment. These problems can be avoided utilizing heterogeneous highly acidic catalysts. Solid catalysts do not corrode equipment and are relatively simple to remove from the post-reaction mixture. Phosphotungstic acid (PTA) supported on silica gel could be a possible catalyst due to its high acidity with an estimated pKa ≈ -13. The catalyst PTA-SiO₂ was prepared via the sol-gel method to covalently embed it in a silica support. The catalyst was …

Nitrogen Doping Of Electrochemically Activate Carbon Screen-Printed Electrodes, Ethan Galloway

Undergraduate Honors Theses

Screen printed electrodes (SPEs), which are prepared by patterning conductive inks or pastes onto an insulating support (e.g., plastic film), are widely employed as sensing and biosensing platforms due to their ease of fabrication and relatively low cost. This is especially applicable to electrodes of this nature prepared with carbon-based inks (SPCEs). To date, the most successful and significant commercial application of SPEs has been as test strips for glucose meters. Despite the maturity of this technology, SPE research remains very active as improvements in sensitivity and selectivity, which often involve modifying the electrode surface, hold the key to advancing …

Development Of A Prototype Electron Detector For Use In Ucna+, Richard Mcdonald

Undergraduate Honors Theses

The UCNA Experiment at the Los Alamos Neutron Science Center (LANSCE) uses an electron spectrometer to observe angular correlations between the neutron spin and the momenta of β particles emitted during the process of β decay. These angular correlations give rise to an asymmetry determined by the ratio of two coupling constants, gA and gV . Combined with neutron lifetime measurements, these observations probe physics beyond the standard model through unitarity tests of the Cabbibo-Kobayashi-Maskawa Matrix. UCNA’s current spectrometer uses a multi-wire proportional chamber and a plastic scintillator coupled to four photomultiplier tubes (PMTs) by 2 meters of light guides …

Simulating Polistes Dominulus Nest-Building Heuristics With Deterministic And Markovian Properties, Benjamin Pottinger

Undergraduate Honors Theses

European Paper Wasps (Polistes dominula) are social insects that build round, symmetrical nests. Current models indicate that these wasps develop colonies by following simple heuristics based on nest stimuli. Computer simulations can model wasp behavior to imitate natural nest building. This research investigated various building heuristics through a novel Markov-based simulation. The simulation used a hexagonal grid to build cells based on the building rule supplied to the agent. Nest data was compared with natural data and through visual inspection. Larger nests were found to be less compact for the rules simulated.

Stumbling Into Virtual Worlds. How Resolution Affects Users’ Immersion In Virtual Reality And Implications For Virtual Reality In Therapeutic Applications, Brianna Martinson

Undergraduate Honors Theses

Studies of how users experience Virtual Reality (VR) have thus far failed to address the extent to which rendering resolution and rendering frame rate affect users’ sense of immersion in VR, including applications of VR involving simulators, treatments for psychological and mental disorders, explorations of new and nonexistent structures, and ways to better understand the human body in medical applications.

This study investigated if rendering resolution affected users’ sense of immersion in VR. This was conducted by comparing the responses of two groups, relative to two measures of participant immersion: (a) participant’s sense of presence and (b) participant’s sense of …

Extraction And Partial Purification Of An Antibiotic-Like Compound From The Soil Bacterium Rhodococcus Strain Kchxc3, Elizabeth Bond

Undergraduate Honors Theses

Rhodococcus bacteria have many secondary metabolic pathways that may produce novel natural products. The bacterium Rhodococcus strain KCHXC3 was isolated from a soil sample collected near Kingsport, Tennessee and was found to produce an inhibitory compound active against a broad array of bacterial species, including the Gram negative pathogen Shigella sonnei. The aim of this research is to extract and purify the compound for future structure elucidation. A mixture of compounds from 3 month old agar plates inoculated with strain KCHXC3 was extracted using ethyl acetate. The crude extract was then partially purified utilizing a Sephadex LH-20 column, followed …

John Horton Conway: The Man And His Knot Theory, Dillon Ketron

Electronic Theses and Dissertations

John Horton Conway was a British mathematician in the twentieth century. He made notable achievements in fields such as algebra, number theory, and knot theory. He was a renowned professor at Cambridge University and later Princeton. His contributions to algebra include his discovery of the Conway group, a group in twenty-four dimensions, and the Conway Constellation. He contributed to number theory with his development of the surreal numbers. His Game of Life earned him long-lasting fame. He contributed to knot theory with his developments of the Conway polynomial, Conway sphere, and Conway notation.

Finding A Representative Distribution For The Tail Index Alpha, Α, For Stock Return Data From The New York Stock Exchange, Jett Burns

Electronic Theses and Dissertations

Statistical inference is a tool for creating models that can accurately display real-world events. Special importance is given to the financial methods that model risk and large price movements. A parameter that describes tail heaviness, and risk overall, is α. This research finds a representative distribution that models α. The absolute value of standardized stock returns from the Center for Research on Security Prices are used in this research. The inference is performed using R. Approximations for α are found using the ptsuite package. The GAMLSS package employs maximum likelihood estimation to estimate distribution parameters using the CRSP data. The …

Risk Gameplay Analysis Using Stochastic Beam Search, Jacob Gillenwater

Electronic Theses and Dissertations

Hasbro’s RISK, first published in 1959, is a complex multiplayer strategy game that has received little attention from the scientific community. Training artificial intelligence (AI) agents using stochastic beam search gives insight into effective strategy when playing RISK. A comprehensive analysis of the systems of play challenges preconceptions about good strategy in some areas of the game while reinforcing those preconceptions in others. This study applies stochastic beam search to discover optimal strategies in RISK. Results of the search show both support for and challenges to traditionally held positions about RISK gameplay. While stochastic beam search competently investigates gameplay on …

Water Quality Assessment Of Karst Spring Water As A Private Water Supply Source In Northeast Tennessee, Lukman Fashina

Electronic Theses and Dissertations

Karst springs are an essential source of private water supply for about 10% of households in Tennessee. However, these springs, which can be easily polluted, are unregulated. This study, therefore, assesses water quality spatial patterns and water quality rating of roadside springs in northeast Tennessee.

Karst spring water samples collected from 50 springs were assessed using EPA Standard methods for pathogens, nutrients, radon, and physicochemical parameters. Springs generally met federal and state standards for physicochemical parameters, 90% of samples contained E. coli, and all samples contained fecal coliform. High E. coli was spatially clustered causing a fecal contamination hot …

Hybrid Machine And Deep Learning-Based Cyberattack Detection And Classification In Smart Grid Networks, Adedayo Aribisala

Electronic Theses and Dissertations

Power grids have rapidly evolved into Smart grids and are heavily dependent on Supervisory Control and Data Acquisition (SCADA) systems for monitoring and control. However, this evolution increases the susceptibility of the remote (VMs, VPNs) and physical interfaces (sensors, PMUs LAN, WAN, sub-stations power lines, and smart meters) to sophisticated cyberattacks. The continuous supply of power is critical to power generation plants, power grids, industrial grids, and nuclear grids; the halt to global power could have a devastating effect on the economy's critical infrastructures and human life.

Machine Learning and Deep Learning-based cyberattack detection modeling have yielded promising results when …

Development Of Classroom Tools For A Risc-V Embedded System, Lucas Phillips

Undergraduate Honors Theses

RISC-V is an open-source instruction set that has been gaining popularity in recent years, and, with support from large chip manufacturers like Intel and the benefits of its open-source nature, RISC-V devices are likely to continue gaining momentum. Many courses in a computer science program involve development on an embedded device. Usually, this device is of the ARM architecture, like a Raspberry Pi. With the increasing use of RISC-V, it may be beneficial to use a RISC-V embedded device in one of these classroom environments. This research intends to assist development on the SiFive HiFive1 RevB, which is a RISC-V …

Pliocene Wood From The Gray Fossil Site, Owen Madsen

Undergraduate Honors Theses

The Gray Fossil Site in northeastern Tennessee preserves materials from a 5-million-year-old ecosystem, including wood from nearby trees. This study consists of three parts: conservation of wood remains, identification of taxonomic groups represented by the fossil wood, and measuring the organic content of fossil wood from the Gray Fossil Site. When excavated, wood specimens from the site are saturated due to a high local water table. After testing seven different techniques to dry wood specimens, wrapping a specimen in string and allowing it to dry slowly was the method least likely to cause warping and cracking. Microscopic examination of wood …

Intraday Algorithmic Trading Using Momentum And Long Short-Term Memory Network Strategies, Andrew R. Whitinger Ii

Undergraduate Honors Theses

Intraday stock trading is an infamously difficult and risky strategy. Momentum and reversal strategies and long short-term memory (LSTM) neural networks have been shown to be effective for selecting stocks to buy and sell over time periods of multiple days. To explore whether these strategies can be effective for intraday trading, their implementations were simulated using intraday price data for stocks in the S&P 500 index, collected at 1-second intervals between February 11, 2021 and March 9, 2021 inclusive. The study tested 160 variations of momentum and reversal strategies for profitability in long, short, and market-neutral portfolios, totaling 480 portfolios. …

Detecting The Intensity Of Denial-Of-Service Cyber Attacks Using Supervised Machine Learning, Abigail Hubbard

Undergraduate Honors Theses

Denial-of-Service (DoS) attacks are aimed at shutting a machine or network down to block users from accessing it. These attacks can be difficult to detect and can cost millions in damages or lost earnings. Since the first DoS attack occurred in 1999, the way DoS attacks have been launched has become more complicated, making them more elusive and harder to detect. The first step to detect and mitigate a DoS attack is for a system to identify the malicious traffic.

In this experiment, we aim to identify the malicious traffic within ten seconds. To do this the project was divided …

A Machine Learning Approach For Reconnaissance Detection To Enhance Network Security, Rachel Bakaletz

Electronic Theses and Dissertations

Before cyber-crime can happen, attackers must research the targeted organization to collect vital information about the target and pave the way for the subsequent attack phases. This cyber-attack phase is called reconnaissance or enumeration. This malicious phase allows attackers to discover information about a target to be leveraged and used in an exploit. Information such as the version of the operating system and installed applications, open ports can be detected using various tools during the reconnaissance phase. By knowing such information cyber attackers can exploit vulnerabilities that are often unique to a specific version.

In this work, we develop an …

Community Structure Analysis Of Mammals Found At The Gray Fossil Site, Tn, Sarah Clark

Electronic Theses and Dissertations

The early Pliocene Gray Fossil Site (GFS) is a biodiverse site with a unique faunal assemblage that represents one of few sites of its age in eastern North America. A community structure analysis of the mammals at GFS was done to characterize species and better understand the paleoenvironment. Data and was gathered from twenty modern communities and five late Neogene sites to compare with GFS. Species from these 26 sites were categorized by body size, locomotor mode, cheek tooth crown height, and diet to characterize niches occupied. Descriptive statistics contrasted proportions of species within categories across communities. Discriminant function analyses …

Android-Based Mobile App Design For Covid-19 Tracking, Paula Faidley

Tennessee Posters at the Capitol

With the evolution of smartphones and rise in their popularity, mobile applications have become a booming concept. Mobile applications connect users with things they value most. With the growing need of mobile applications, mobile app design is quickly becoming a sought-after skill. By learning the intricate process of mobile app design, individuals can learn new and innovative ways to express their creativity while providing useful products. During times such as the recent pandemic, mobile applications are especially useful because people would often times feel alone from spending a majority of the year in quarantine while being overwhelmed with all of …