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Physical Sciences and Mathematics Commons

Open Access. Powered by Scholars. Published by Universities.®

Clemson University

2011

Carbon

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Full-Text Articles in Physical Sciences and Mathematics

Biological And Ecological Responses To Carbon-Based Nanomaterials, Tatsiana Ratnikova Aug 2011

Biological And Ecological Responses To Carbon-Based Nanomaterials, Tatsiana Ratnikova

All Dissertations

Nanotechnology has been undergoing tremendous development in recent decades, driven by realized perceived applications of nanomaterials in electronics, therapeutics, imaging, sensing, environmental remediation, and consumer products. Along with these developments there have been increased evidences that engineered nanomaterials are often associated with hazardous effects they invoke in biological and ecosystems through intentional designs or unintentional discharge. Consequently there is a crucial need for documenting and understanding the interactions between nanoparticles and biological and ecosystems. This dissertation is aimed at bridging such a knowledge gap by examining the biological and ecological responses to carbon nanoparticles, a major class of nanomaterials which …


Risks Posed To Drinking Water Aquifers Due To Leakage Of Dissolved Co2 In Improperly Abandoned Wellbores, Kirk Ellison Aug 2011

Risks Posed To Drinking Water Aquifers Due To Leakage Of Dissolved Co2 In Improperly Abandoned Wellbores, Kirk Ellison

All Theses

In order to ensure safe long-term storage of carbon dioxide in geologic formations, the risks posed by improperly abandoned wells must be understood and minimalized. In addition to supercritical and gaseous CO2, brine containing dissolved CO2 poses a leakage risk. CO2 dissolution in brine leads to denser brine and better long-term storage security, but its leakage risk is not zero. Under specific circumstances with formation overpressure or overlying aquifer drawdown, dissolved brine can flow up improperly abandoned wells where it can potentially enter and contaminate drinking water aquifers. The possibility that depressurization in the wellbore may cause CO2 exsolution from …