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Clemson University

Theses/Dissertations

2012

Sorption

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Sorption And Enantiomerization Of Current Use Chiral Pesticides, April Hall Dec 2012

Sorption And Enantiomerization Of Current Use Chiral Pesticides, April Hall

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Chiral pesticides are prevalent in the environment today and are known to react selectively with chiral environmental components such as microbes, enzymes, and other naturally occurring chiral materials. In addition, chiral sorption is a process that has been occasionally investigated in the study of homochirality (the exclusive presence of one enantiomer in living organisms), but almost overlooked in environmental science. For chiral sorption to occur, the sorbent and sorbate must be chiral entities. In the environment, there are abundant natural surfaces that are chiral, including clay minerals and organic matter present in soil, sediment and aqueous solution. A knowledge of …