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Full-Text Articles in Physical Sciences and Mathematics
Determination Of Interphase Line Tension In Langmuir Films, Jacob R. Wintersmith '06, Lu Zou, Andrew J. Bernoff, James C. Alexander, J. Adin Mann Jr.
Determination Of Interphase Line Tension In Langmuir Films, Jacob R. Wintersmith '06, Lu Zou, Andrew J. Bernoff, James C. Alexander, J. Adin Mann Jr.
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A Langmuir film is a molecularly thin film on the surface of a fluid; we study the evolution of a Langmuir film with two coexisting fluid phases driven by an interphase line tension and damped by the viscous drag of the underlying subfluid. Experimentally, we study a 4′-8-alkyl[1,1′-biphenyl]-4-carbonitrile (8CB) Langmuir film via digitally imaged Brewster angle microscopy in a four-roll mill setup which applies a transient strain and images the response. When a compact domain is stretched by the imposed strain, it first assumes a bola shape with two tear-drop shaped reservoirs connected by a thin …
Hole Dynamics In Polymer Langmuir Films, James C. Alexander, Andrew J. Bernoff, Elizabeth K. Mann, J. Adin Mann Jr., Lu Zou
Hole Dynamics In Polymer Langmuir Films, James C. Alexander, Andrew J. Bernoff, Elizabeth K. Mann, J. Adin Mann Jr., Lu Zou
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This article develops a model for the closing of a gaseous hole in a liquid domain within a two-dimensional fluid layer coupled to a Stokesian subfluid substrate, and compares this model to experiments following hole dynamics in a polymer Langmuir monolayer. Closure of such a hole in a fluid layer is driven by the line tension at the hole boundary and the difference in surface pressure within the hole and far outside it. The observed rate of hole closing is close to that predicted by our model using estimates of the line tension obtained by other means, assuming that the …