Physical Sciences and Mathematics Commons^™

Pakistan, India And The Indus River Basin, Muquadas Ilyas

Dissertations and Theses

Water is a fundamental need of all living things. The right to clean water is classified as a human right under United Nations Resolution 64/292.As such it is the responsibility of governments to ensure its citizens are not deprived of this essential resource. In doing so, effective water management is crucial to provide clean water that is accessible to everyone regardless of any challenges such as geographical constraints or political disputes. This thesis explores the water management efforts of Pakistan and India. These countries are facing a water crisis, whereby numerous citizens have died due to dehydration and diseases contracted …

Understanding The Impacts Of Freshwater Fluxes On The Biogeochemistry Of The Coastal Arctic: A Case Study Of Prudhoe Bay, Francesca Lingo

Dissertations and Theses

The Arctic region, undergoing significant environmental changes due to rapid warming, faces alterations in air temperatures, melting permafrost, declining sea ice, and changes in riverine inputs. These shifts have profound implications for Arctic coastal ecology and biogeochemical cycles. This study, focusing on Alaska's North Slope, explores the influence of freshwater fluxes on water optical properties, vital for accurate satellite remote sensing interpretations. Our approach combined field measurements, existing data, and satellite remote sensing retrievals to identify biogeochemical gradients and their seasonal and interannual variations. A novel finding was the unique CDOM composition in Prudhoe Bay, characterized by a lower molecular …

Fine Characterization Of Leafing Phenology In The Brazilian Atlantic Forest By Optical And Microwave Remote Sensing, James B. Bell

Dissertations and Theses

Tropical forests provide important ecosystem functions in the global biosphere, but they remain among the most poorly understood elements of land surface models, especially with regard to their seasonal dynamics. For instance, in seasonally dry forests, the pattern of the annual green-up in their canopies closely follows annual patterns of rainfall. The same, however, does not occur in wet forest canopies which are dominated by evergreen trees. In the latter, water is not scarce enough to limit leaf photosynthetic function. Canopy leafing phenology in these forests is therefore poorly characterized by optical remote sensing methods which are not sensitive to …

Advancing The Accuracy Of Watershed Analysis Across Diverse Hydrometeorological And Geologic Regimes Via Classification And Analysis Of Gpm-Imerg Products, Jake M. Longenecker

Dissertations and Theses

The analysis and protection of watersheds, along with spring water resources, depend on the accurate identification of catchments. Building on previous research that correlated spring hydrographs with high-resolution, satellite-based Global Precipitation Measurement – Integrated Multi-satellitE Retrievals for GPM (GPM-IMERG) data, I improve the speed and accuracy of catchment identification and hydrodynamic characterization via an enhanced Empirically Constrained Hydrologic Operation (ECHO) algorithm. This research (1) establishes optimal parameter inputs for the algorithm to enable reliable identification of source point-locations, (2) removes human in-the-loop processing, and thus reduce potential operator bias, and (3) explores the potential for using a limited dataset of …

Towards Simulation Of Complex Ocean Flows: Analysis And Algorithm For Computation Of Coupled Partial Differential Equations, Wenbin Dong

Dissertations and Theses

The hybrid CFD models which usually consist of 2 sub-models, develop our capability to simulate many emerging problems with multiphysics and multiscale flows, especially for the coastal ocean flows interacted with local phenomena of interest. For most cases, the sub-models are connected with direct interpolation which is easy and workable. It becomes urgently needed to investigate the inner mechanism of such model integration as this simple method does not work well if the two sub-models are different in governing equations, numerical methods, and computational grids. Also, it can not treat complex flow structures as well as the balance in mass …

A Temporal Examination Of The Connections Between Convective Available Potential Energy And Convective System Development, Chad A. Small

Dissertations and Theses

In 1983, the World Climate Research Programme launched its first project: the International Satellite Cloud Climatology Project (ISCCP). While the ISCCP has succeeded in many of its cataloging and analytical goals, one of its flagship products, the Convection Tracking (CT) Database does not contain certain environmental parameters that are essential in understanding how, and when, convection is initiated or intensified. The development of mesoscale convection – notably, convective systems (CS) – is also largely dependent on parameters like convective available potential energy (CAPE) which the ISCCP CT Database does not record. By tying information on CAPE to CS, discoveries in …

Sea Surface Temperatures And Vertical Wind Shear As Precursors To Tropical Cyclone Activity In The Caribbean And An Expanding Main Developing Region, Keneshia Hibbert

Dissertations and Theses

Sea surface temperatures and vertical wind shear are essential to tropical cyclone formation. TCs need warm SSTs and low shear for genesis. Increasing SSTs and VWS changes influence storm development. This work analyzes SST and VWS trends for the Caribbean, surrounding region, and the Atlantic hurricane main developing region from 1982 to 2020. Storm intensity increases significantly during this period. Annual and seasonal trends show regional SSTs in the MDR are warming annually (0.0219°C yr^-1) and per season (0.0280°C yr^-1). Simultaneously, VWS decreases during the late rainfall season at 0.0556m/s yr^-1 in the MDR and …

Evaluation Of Snow And Streamflow In The National Water Model With Analysis Using Machine Learning, Engela Sthapit

Dissertations and Theses

Snow has great influence on land-atmosphere interactions and snowmelt from the mountains is a vital water source for downstream communities dependent on snow fed lakes, rivers and streams. This study explored the snow and streamflow prediction capabilities of process-based numerical prediction and data-driven machine learning models.

The overall goal of this study was to understand the deficiencies in the NOAA’s National Water Model (NWM) to represent snow, subsequently streamflow, and recognize the areas where it could be improved for future model developments. The goal was also to evaluate if the recent advancements in machine learning techniques is useful for predicting …

Data Fusion And Synergy Of Active And Passive Remote Sensing; An Application For Freeze Thaw Detections, Zahra Sharifnezhadazizi

Dissertations and Theses

There has been a recent evolvement in the field of remote sensing after increase of number satellites and sensors data which could be fused to produce new data and products. These efforts are mainly focused on using of simultaneous observations from different platforms with different spatial and temporal resolutions. The research dissertation aims to enhance the synergy use of active and passive microwave observations and examine the results in detection land freeze and thaw (FT) predictions. Freeze thaw cycles particularly in high-latitude regions have a crucial role in many applications such as agriculture, biogeochemical transitions, hydrology and ecosystem studies. The …

Analysis Of Blue Fountain Pen Ink By Uv-Vis Spectroscopy, Atr-Ftir Spectroscopy, And Thin Layer Chromatography Enhanced With Rgb Spot Evaluation To Construct A Database For Comparison And Identification., Elliot D. Quinteros

Dissertations and Theses

Pen ink can be a crucial piece of physical evidence in the area of Forensic Science. For example, evidence such as notes, letters, printed documents, checks, currency, ransom notes, and books may contain ink. Analysis of ink is typically done for identification or differentiation purposes. To improve existing methods, it was proposed to create a database with many samples and experimental information. The methods used and evaluated were thin-layer chromatography (TLC) enhanced with RGB spot evaluation, UV-Vis spectroscopy, and ATR-FTIR spectroscopy. All three methods were used to analyze 89 fountain pen ink samples. All three methods were able to discriminate …

Understanding The Relationship Between Urban Areas And The Boundary Layer Using Remote Sensing Methods, Gabriel A. Rios

Dissertations and Theses

The atmospheric boundary layer is crucial to the exchange in energy between the Earth's surface and the atmosphere. Within this layer, the majority of human activities are carried out, which makes understanding the boundary layer especially important for many of our interests. A key component of this energy exchange is found at the surface, was surface properties are the interface through which momentum, heat, moisture, and other fluxes are transferred between media. Not only does the surface act as an interface, but as an actor that influences the exchange efficiency and rates. This concept is the crux of atmospheric boundary …

Nonlinear Light - Matter Interactions Of Ultrafast High Intensity Laser Pulses, Henry Meyer

Dissertations and Theses

This thesis focuses on the key nonlinear optical effects that arise from the interactions of intense ultrafast laser pulses with various states of matter. These interactions involve electronic and molecular states and yield new information on the underlying fundamental processes that govern the molecular world. Modern day lasers offer ultrashort pulses, high intensities, and complex polarizations and wavefronts. These extreme conditions have profound effect on the optical properties and behaviors of electronic and molecular states within a material. The changes in these mechanisms effect generation of nonlinear optics, such supercontinuum (SC), stimulated Raman (SRS), self-focusing and filamentation, conical emission (CE), …

A Real-Time 3d Object Detection, Recognition And Presentation System On A Mobile Device For Assistive Navigation, Jin Chen

Dissertations and Theses

This thesis proposes an integrated solution for 3D object detection, recognition, and presentation to increase accessibility for various user groups in indoor areas through a mobile application. The system has three major components: a 3D object detection module, an object tracking and update module, and a voice and AR-enhanced interface. The 3D object detection module consists of pre-trained 2D object detectors and 3D bounding box estimation methods to detect the 3D poses and sizes of the objects in each camera frame. This module can easily adapt to various 2D object detectors (e.g., YOLO, SSD, Mask RCNN) based on the requested …

A Citizen-Science Approach For Urban Flood Risk Analysis Using Data Science And Machine Learning, Candace Agonafir

Dissertations and Theses

Street flooding is problematic in urban areas, where impervious surfaces, such as concrete, brick, and asphalt prevail, impeding the infiltration of water into the ground. During rain events, water ponds and rise to levels that cause considerable economic damage and physical harm. The main goal of this dissertation is to develop novel approaches toward the comprehension of urban flood risk using data science techniques on crowd-sourced data. This is accomplished by developing a series of data-driven models to identify flood factors of significance and localized areas of flood vulnerability in New York City (NYC). First, the infrastructural (catch basin clogs, …

Investigating The Effect Of Electrolyte Concentration And Charging Protocol On Materials Utilization In Rechargeable Zinc Manganese Dioxide Batteries, Snehal H. Kolhekar

Dissertations and Theses

Achieving a highly cyclable, high energy density battery with MnO₂ cathodes encounters many obstacles. Chief among these is the inability of the widely-used γ-MnO₂ polymorph to retain its structural integrity when cycled to near full one-electron discharge capacity, which is about 280mAh/g for commercially available electrolytic manganese dioxide (EMD). In this one-electron range, discharge occurs by proton insertion producing Mn⁺³ which then reverts to γ-MnO₂ on charging. In the first part of the thesis, we investigate the root cause of failure of MnO₂ cathodes under deep cycling in the one-electron discharge range and establish a …

Analysis Of Uncertainty In Hydrometeorological Ensemble Forecasts, Carolien N. Mossel

Dissertations and Theses

Ensemble hydrometeorological forecasting has great potential for improving flood predictions and use in water management systems, however, the amount of data used and created with an ensemble forecast requires a careful and intentional approach to understand how useful and skillful the forecast is. The NOAA National Water Model (NWM) was run using downscaled NOAA Global Ensemble Forecast System (GEFS) meteorological forcings for the 2016-2017 wet season (October-March) in California to create an 11-member hydrologic forecast ensemble. To evaluate the performance of these ensemble forecasts, we chose to study streamflow sites within Sonoma County, California, a rain-dominated region which includes the …

Comparison Of Calculated Normal Mode Molecular Vibrations With Experimental Gas-Phase Infrared Spectroscopy, Anila Renis Sutar

Dissertations and Theses

Computational vibrational spectroscopy serves as an important tool in the interpretation of experimental infrared (IR) spectra. Analysis of computational results provides a perspective over broader wavelength ranges and at higher precision. Although there are issues regarding accuracy, this can be approximated by using a scaling factor. High-resolution gas-phase FTIR spectroscopy at a resolution of 0.125 cm^-1 can partially resolve rovibrational transitions in the P, Q, and R bands and therefore identify fundamental frequencies with approximately 1 cm^-1 precision.

This research has compared high-resolution gas-phase FTIR absorption peaks to calculated vibrational frequencies. In the calculation of normal mode frequencies, …

A New Mathematical Theory For The Dynamics Of Large Tumor Populations, A Potential Mechanism For Cancer Dormancy & Recurrence And Experimental Observation Of Melanoma Progression In Zebrafish, Adeyinka A. Lesi

Dissertations and Theses

Cancer, a family of over a hundred disease varieties, results in 600,000 deaths in the U.S. alone. Yet, improvements in imaging technology to detect disease earlier, pharmaceutical developments to shrink or eliminate tumors, and modeling of biological interactions to guide treatment have prevented millions of deaths. Cancer patients with initially similar disease can experience vastly different outcomes, including sustained recovery, refractory disease or, remarkably, recurrence years after apparently successful treatment. The current understanding of such recurrences is that they depend on the random occurrence of critical mutations. Clearly, these biological changes appear to be sufficient for recurrence, but are they …

Goes-R Supervised Machine Learning, Ronald Adomako

Dissertations and Theses

The GOES-R series is a product line of four satellite, with two currently on-orbit (GOES-16 “East” and GOES-17 “West”). GOES-17 is susceptible to a Loop-Heat-Pipe (LHP) phenomenon where during Fall and Spring seasons, there are times of day where some of the infrared bands records inaccurate readings from the Advanced Baseline Imager (ABI). This occurs from joint astronomical behavior and position of the GOES-17. This calibration issue occurs when the LHP instrument fails to radiate the heat of the sun out of ABI. Predictive Calibration (pCal) is an algorithm developed by instrument vendors for the National Oceanic Atmospheric Agency (NOAA) …

Understanding The Effect Of Climate And Hydrometeorological Extremes On Natural And Human-Induced Hydrosystems, Jeongwoo Hwang

Dissertations and Theses

The contemporary hydrosystems of the United States involve a complex combination of natural and modified basins in the presence of changing climate and anthropogenic impacts. An enhanced understanding of the interdependence between climate forcings, human-induced interventions, and water balance in both natural and modified basins are essential for developing reliable and resilient hydrosystems and for better water resources management. In response, this dissertation focuses on investigating the hydroclimatology of natural and modified basins across the contiguous United States. It has three research objectives: (1) to explain flow alterations due to anthropogenic activities, especially dam operations, in modified basins and understand …

Long Term Nutrient And Chlorophyll A Dynamics Across Long Island Sound And Impacts On Dissolved Oxygen Conditions Within The Western Sound (1991-2019), Sherry Perreira

Dissertations and Theses

Nitrogen overload, eutrophication, and hypoxia have been challenging and persistent water quality problems in Long Island Sound (LIS) over the past decades with major impacts on commercial industries, ecology, and recreational activities in the region. Recognizing these problems, the EPA enforced three phases of the Clean Water Act (CWA) to reduce nitrogen loads in an effort to improve this important estuary. This study examines how nitrogen (NH₃, NO_x & TDN), chlorophyll a (CHLA), and dissolved oxygen (DO) concentrations changed in LIS over the past 30 years, in response to water quality regulations as well as changes in …

On The Improvements Of Boundary-Layer Representation For High Resolution Weather Forecasting In Costal-Urban Environments, David Melecio-Vazquez

Dissertations and Theses

As large urban centers around the world become more densely populated, the global conversion from natural to man-made land surfaces will only increase. These land-use changes affect the urban surface energy budget which in turn changes the structure of the planetary boundary layer (PBL) above. With current high-performance computing systems, meteorological and built environment information can be better utilized to quantify the anthropogenic effects of these modifications. Although these systems have improved forecasting near-surface weather conditions, a comprehensive approach to represent urban impacts on the PBL is still limited. Improved PBL representation can lead to better weather and climate forecasts, …

Polarization Sensitive Imaging Techniques Using Quantum Entangled Qubits, Vitaly Sukharenko

Dissertations and Theses

The aim of this research is to study imaging techniques using quantum entangled qubits. These techniques extract information about the quantum state of two entangled qubits and corelate the degree of entanglement to each pixel. Imaging information of the underlying structure or material is decoded using the reconstruction of the quantum density matrix along with the calculated entanglement and concurrence levels between the two qubits. Reconstruction of a quantum state and quantum state tomography are of increasing importance in quantum information science. Quantum state tomography is used to describe entanglement of trapped ions [1] and photons [2]. Number of experiments …

Adsorption Kinetics And Phase Behavior Of Particles Adsorbed At An Interface, Shaghayegh Darjani

Dissertations and Theses

The ability to predict the adsorption dynamic, phase behavior, and surface pressure of a monolayer of adsorbed particles in two-dimensional systems are key aspects of many current research areas. Examples include phase transitions in amphiphilic monolayers, emulsion stability due to particle adsorption at interfaces, and melting at an interface.

In this thesis, a new approach for deriving the equation of state for a two-dimensional lattice gas is proposed, based on arguments similar to those used in the derivation of the Langmuir-Szyszkowski equation of state for localized adsorption. This work aims to predict the adsorption kinetics and phase behavior of a …

Adapting To Extreme Heat: Social, Atmospheric, And Infrastructure Impacts Of Air Conditioning In Megacities - The Case Of New York City, Harold Gamarro

Dissertations and Theses

Extreme heat events are becoming more frequent and intense in most large cities. Built-up surfaces also limit cooling mechanisms, leading to warmer conditions in cities, a phenomenon called the Urban Heat Island (UHI). This presents major challenges to reduce adverse health effects of hot weather, particularly in vulnerable populations like the elderly and low-income communities. Here we explore the overall impacts of increasing air conditioning (AC) system adoption in residences as an adaptive measure to reduce human health risks under heat waves, with New York City (NYC) as a case study. This study uses AC adoption data from the 2017 …

Ecosystem Health In Guánica Bay And La Parguera, Puerto Rico: Remote Sensing Of Ocean Color And Metal Analysis Of Coral Tissue And Surficial Sediments, Jahnelle Howe

Dissertations and Theses

Guánica Bay is an estuary located in southwest Puerto Rico, with a coral reef ecosystem at its periphery. This ecosystem is affected by sediments, nutrients, and contaminants from the watershed through the Bay and into the offshore water. This project evaluates Guánica Bay and La Parguera coastal areas through remote sensing and chemical analysis to assess coastal ecosystem health. The concentration of metals in two coral species and their associated surface sediments was were analyzed by X-ray fluorescence (XRF) and Direct Mercury Analyzer (DMA- 80). Ocean color remote sensing was used to estimate nutrient inputs and phytoplankton biomass through chlorophyll- …

Mechanisms Of Value-Biased Prioritization In Fast Sensorimotor Decision Making, Kivilcim Afacan-Seref

Dissertations and Theses

In dynamic environments, split-second sensorimotor decisions must be prioritized according to potential payoffs to maximize overall rewards. The impact of relative value on deliberative perceptual judgments has been examined extensively, but relatively little is known about value-biasing mechanisms in the common situation where physical evidence is strong but the time to act is severely limited. This research examines the behavioral and electrophysiological indices of how value biases split-second perceptual decisions and the possible mechanisms underlying the process. In prominent decision models, a noisy but statistically stationary representation of sensory evidence is integrated over time to an action-triggering bound, and value-biases …

Edge Device Speaker Verification, Thomas P. Duffy

Dissertations and Theses

The continued shrinking of processors and other physical hardware in concert with development of embeddable machine learning frameworks has enabled new use cases placing machine learning directly in the “wild”. The problem of speaker verification, for a long time, has been deployed to perform inference on systems with significant computations resources. More recently, these systems have been built for smaller, cheaper devices which can be placed in people's homes or other edge locations. Here, we aim to demonstrate that a reasonably accurate, generalizable, text-independent speaker verification system can be built, trained, and, ultimately, deployed onto a microcontroller with as a …

Ftir Analysis Of Bacteria Biomass-Mineral Interactions In Soils, Finola Fung-Khee

Dissertations and Theses

Soil organic carbon (SOC) accounts for 70% of the carbon on Earth. It is therefore a key player in global carbon cycling and climate change (Smith et al., 2008). Soil organic matter (SOM) is an important component of organic matter in soils (SOC), and results from biogeochemical process involving net primary producers, soil biomass and soil mineralogy (Horwath and Kuzyakov, 2018). In this study, the interplay between soil bacterial biomass and reactive clay minerals in soils was investigated. The purpose of the research was to shed light into the stabilization of SOC in a bacterial biomass-soil/clay matrix. Soils characterized as …

Macro - And Microstructure Evaluation And Field Applications Of Concrete With Recycled Glass Pozzolan, Marija Krstic

Dissertations and Theses

Concrete is the most used material in the world, second only to water. Conventional concrete is produced with Portland cement (PC). The production of cement is an energy intensive operation that has raised significant environmental concerns, since one ton of cement generates an equal ton of CO₂. In the USA about 90 million tons of cement are used annually, with 3 million tons used in New York. Most contemporary concrete applications for buildings and infrastructure use high-performance concrete (HPC) mixtures which are produced by replacing a percentage of cement with supplementary cementitious materials (SCMs), consisting mainly of fly-ash …