Physical Sciences and Mathematics Commons^™

Understanding The Impacts Of Freshwater Fluxes On The Biogeochemistry Of The Coastal Arctic: A Case Study Of Prudhoe Bay, Francesca Lingo

Dissertations and Theses

The Arctic region, undergoing significant environmental changes due to rapid warming, faces alterations in air temperatures, melting permafrost, declining sea ice, and changes in riverine inputs. These shifts have profound implications for Arctic coastal ecology and biogeochemical cycles. This study, focusing on Alaska's North Slope, explores the influence of freshwater fluxes on water optical properties, vital for accurate satellite remote sensing interpretations. Our approach combined field measurements, existing data, and satellite remote sensing retrievals to identify biogeochemical gradients and their seasonal and interannual variations. A novel finding was the unique CDOM composition in Prudhoe Bay, characterized by a lower molecular …

Fine Characterization Of Leafing Phenology In The Brazilian Atlantic Forest By Optical And Microwave Remote Sensing, James B. Bell

Dissertations and Theses

Tropical forests provide important ecosystem functions in the global biosphere, but they remain among the most poorly understood elements of land surface models, especially with regard to their seasonal dynamics. For instance, in seasonally dry forests, the pattern of the annual green-up in their canopies closely follows annual patterns of rainfall. The same, however, does not occur in wet forest canopies which are dominated by evergreen trees. In the latter, water is not scarce enough to limit leaf photosynthetic function. Canopy leafing phenology in these forests is therefore poorly characterized by optical remote sensing methods which are not sensitive to …

Sea Surface Temperatures And Vertical Wind Shear As Precursors To Tropical Cyclone Activity In The Caribbean And An Expanding Main Developing Region, Keneshia Hibbert

Dissertations and Theses

Sea surface temperatures and vertical wind shear are essential to tropical cyclone formation. TCs need warm SSTs and low shear for genesis. Increasing SSTs and VWS changes influence storm development. This work analyzes SST and VWS trends for the Caribbean, surrounding region, and the Atlantic hurricane main developing region from 1982 to 2020. Storm intensity increases significantly during this period. Annual and seasonal trends show regional SSTs in the MDR are warming annually (0.0219°C yr^-1) and per season (0.0280°C yr^-1). Simultaneously, VWS decreases during the late rainfall season at 0.0556m/s yr^-1 in the MDR and …

Evaluation Of Snow And Streamflow In The National Water Model With Analysis Using Machine Learning, Engela Sthapit

Dissertations and Theses

Snow has great influence on land-atmosphere interactions and snowmelt from the mountains is a vital water source for downstream communities dependent on snow fed lakes, rivers and streams. This study explored the snow and streamflow prediction capabilities of process-based numerical prediction and data-driven machine learning models.

The overall goal of this study was to understand the deficiencies in the NOAA’s National Water Model (NWM) to represent snow, subsequently streamflow, and recognize the areas where it could be improved for future model developments. The goal was also to evaluate if the recent advancements in machine learning techniques is useful for predicting …

Data Fusion And Synergy Of Active And Passive Remote Sensing; An Application For Freeze Thaw Detections, Zahra Sharifnezhadazizi

Dissertations and Theses

There has been a recent evolvement in the field of remote sensing after increase of number satellites and sensors data which could be fused to produce new data and products. These efforts are mainly focused on using of simultaneous observations from different platforms with different spatial and temporal resolutions. The research dissertation aims to enhance the synergy use of active and passive microwave observations and examine the results in detection land freeze and thaw (FT) predictions. Freeze thaw cycles particularly in high-latitude regions have a crucial role in many applications such as agriculture, biogeochemical transitions, hydrology and ecosystem studies. The …

Analysis Of Uncertainty In Hydrometeorological Ensemble Forecasts, Carolien N. Mossel

Dissertations and Theses

Ensemble hydrometeorological forecasting has great potential for improving flood predictions and use in water management systems, however, the amount of data used and created with an ensemble forecast requires a careful and intentional approach to understand how useful and skillful the forecast is. The NOAA National Water Model (NWM) was run using downscaled NOAA Global Ensemble Forecast System (GEFS) meteorological forcings for the 2016-2017 wet season (October-March) in California to create an 11-member hydrologic forecast ensemble. To evaluate the performance of these ensemble forecasts, we chose to study streamflow sites within Sonoma County, California, a rain-dominated region which includes the …

Long Term Nutrient And Chlorophyll A Dynamics Across Long Island Sound And Impacts On Dissolved Oxygen Conditions Within The Western Sound (1991-2019), Sherry Perreira

Dissertations and Theses

Nitrogen overload, eutrophication, and hypoxia have been challenging and persistent water quality problems in Long Island Sound (LIS) over the past decades with major impacts on commercial industries, ecology, and recreational activities in the region. Recognizing these problems, the EPA enforced three phases of the Clean Water Act (CWA) to reduce nitrogen loads in an effort to improve this important estuary. This study examines how nitrogen (NH₃, NO_x & TDN), chlorophyll a (CHLA), and dissolved oxygen (DO) concentrations changed in LIS over the past 30 years, in response to water quality regulations as well as changes in …

Adapting To Extreme Heat: Social, Atmospheric, And Infrastructure Impacts Of Air Conditioning In Megacities - The Case Of New York City, Harold Gamarro

Dissertations and Theses

Extreme heat events are becoming more frequent and intense in most large cities. Built-up surfaces also limit cooling mechanisms, leading to warmer conditions in cities, a phenomenon called the Urban Heat Island (UHI). This presents major challenges to reduce adverse health effects of hot weather, particularly in vulnerable populations like the elderly and low-income communities. Here we explore the overall impacts of increasing air conditioning (AC) system adoption in residences as an adaptive measure to reduce human health risks under heat waves, with New York City (NYC) as a case study. This study uses AC adoption data from the 2017 …

Ecosystem Health In Guánica Bay And La Parguera, Puerto Rico: Remote Sensing Of Ocean Color And Metal Analysis Of Coral Tissue And Surficial Sediments, Jahnelle Howe

Dissertations and Theses

Guánica Bay is an estuary located in southwest Puerto Rico, with a coral reef ecosystem at its periphery. This ecosystem is affected by sediments, nutrients, and contaminants from the watershed through the Bay and into the offshore water. This project evaluates Guánica Bay and La Parguera coastal areas through remote sensing and chemical analysis to assess coastal ecosystem health. The concentration of metals in two coral species and their associated surface sediments was were analyzed by X-ray fluorescence (XRF) and Direct Mercury Analyzer (DMA- 80). Ocean color remote sensing was used to estimate nutrient inputs and phytoplankton biomass through chlorophyll- …

Ftir Analysis Of Bacteria Biomass-Mineral Interactions In Soils, Finola Fung-Khee

Dissertations and Theses

Soil organic carbon (SOC) accounts for 70% of the carbon on Earth. It is therefore a key player in global carbon cycling and climate change (Smith et al., 2008). Soil organic matter (SOM) is an important component of organic matter in soils (SOC), and results from biogeochemical process involving net primary producers, soil biomass and soil mineralogy (Horwath and Kuzyakov, 2018). In this study, the interplay between soil bacterial biomass and reactive clay minerals in soils was investigated. The purpose of the research was to shed light into the stabilization of SOC in a bacterial biomass-soil/clay matrix. Soils characterized as …

Tropical Cyclone Hazards In Relation To Propagation Speed, Jiehao Huang

Dissertations and Theses

As the population and infrastructure along the US East Coast increase, it becomes increasingly important to study the characteristics of tropical cyclones that can impact the coast. A recent study shows that the propagation speed of tropical cyclones has slowed over the past 60 years, which can lead to greater accumulation of precipitation and greater storm surge impacts. The study presented herein is meant to examine and analyze the relationships that exist between the propagation speed of tropical cyclones, their surface wind strength, displacement angles, and cyclone averaged winds. This analysis is focused on tropical cyclones spanning from 1950-2015 in …

Snowmelt Detection On Alpine Glaciers Using Synthetic Aperture Radar Time Series, Corey Scher

Dissertations and Theses

Hindu Kush Himalayan (HKH) glaciers serve as some of the most sensitive indicators of changes in global climate. These glaciers shape the hydrologic dynamics of river systems supplying freshwater to over 2 billion people throughout Asia and regulate the geochemistry of sensitive aquatic alpine ecosystems. As snowmelt onsets sooner, lasts longer, and snowfields retreat due to increases in global temperature, the hydrologic dynamics of catchments draining HKH threaten to change the availability of surface freshwater resources for nearly one fifth of the global population, disturb sensitive aquatic habitat, and precipitate hazards associated with glacier wasting. Informed planning and decision-making around …

Electrical Conductivity And Resistivity Study Of Heterogeneous Sediment In Inwood Hill Park, Manhattan, Ny, Rea A. Khaleda

Dissertations and Theses

The area near the inlet of Spuyten Duyvil Creek in Inwood Hill Park in New York City exhibits complex hydrological processes. The inlet is a tidal flat, which contains brackish water; a mixture of saltwater and freshwater. The area was modified by man, built on a shell bed and contains heterogeneous sediment. One field adjacent to the inlet contains several small sinkholes. Electrical resistivity and ground conductivity techniques were used in order to get an understanding of the hydrological processes of this field. It was hypothesized that the formation of the sinkholes is due to the tidal forcing of the …

Pressure, Temperature, And Stress Conditions Of Southern Alpine Fault (New Zealand) Mylonites, Jake T. Reitman

Dissertations and Theses

The Alpine Fault, New Zealand, provides a unique window into the rheologic history of a seismically-active continental plate boundary. Due to lower exhumation rates along southern portions of the fault relative to the well-studied central Alpine Fault, deformation ages vary along strike by ~15 m.y.. Mylonites collected from two southern creeks near Haast, NZ, display a uniform recrystallized grain size of ~11 𝜇m in mylonitic quartz indicating differential stress values in the south of ~100 MPa, roughly twice the stress values observed in the central Alpine Fault. Constraints from Ti-in-quartz thermobarometry and Raman Spectroscopy of Carbonaceous Material (RSCM) indicate mylonitization …

Carbonatites As A Record Of The Carbon Isotope Composition Of Large Igneous Province Outgassing, Ellen Gales

Dissertations and Theses

Large igneous province (LIP) eruptions have been linked in some cases to major perturbations of Earth’s carbon cycle. However, few observations directly constrain the isotopic composition of carbon released by LIP magmas because carbon isotopes fractionate during degassing, which hampers understanding of the relative roles of mantle versus crustal carbon reservoirs. Carbonatite magmatism associated with LIPs provides a unique window into the isotopic systematics of LIP carbon because the majority of carbon in carbonatites crystalizes rather than degassing. Here, we present new δ¹³C data for the Guli carbonatites in the Siberian Traps. In addition, we compile ~260 published …

Hydroclimate Drivers And Atmospheric Dynamics Of Floods, Nasser Najibi

Dissertations and Theses

Our preliminary survey showed that most of the recent flood-related studies did not formally explain the physical mechanisms of long-duration and large-peak flood events that can evoke substantial damages to properties and infrastructure systems. These studies also fell short of fully assessing the interactions of coupled ocean-atmosphere and land dynamics which are capable of forcing substantial changes to the flood attributes by governing the exceeding surface flow regimes and moisture source-sink relationships at the spatiotemporal scales important for risk management. This dissertation advances the understanding of the variability in flood duration, peak, volume, and timing at the regional to the …

Convective Transport Of Tropical Marine Boundary Layer Species Into The Upper Troposphere And Relation To Species Lifetime: In Situ Measurements And Global Model Simulation, Sofia M. Chelpon

Dissertations and Theses

This study investigates the influence of tropical deep convection on distribution of trace gasses in the tropical upper troposphere (UT) using data from the Convective Transport of Active Species in the Tropics (CONTRAST) Experiment conducted over the tropical western Pacific during January and February of 2014. Fifty-five chemical species measured during the CONTRAST campaign are analyzed with lifetimes ranging from less than a day to several years. The vertical profiles of these species suggest that they fall into three main groups delineated by their lifetime: 1) very long-lived trace gases demonstrating a nearly constant vertical structure, 2) intermediate lifetime species …

Differentiation In Impact Melt Sheets As A Mechanism To Produce Evolved Magmas On Mars, Ari Koeppel

Dissertations and Theses

Asteroid bombardment contributed to extensive melting and resurfacing of ancient (> 3 Ga) Mars, thereby influencing the early evolution of the Martian crust. However, information about how impact melting has altered Mars’ crustal petrology is limited. Evidence from some of the largest impact structures on Earth, such as Sudbury and Manicouagan, suggests that some impact melt sheets experience chemical differentiation. If these processes occur on Mars, we expect to observe differentiated igneous materials in some exhumed rock samples. Some rocks observed in Gale crater are enriched in alkalis (up to 14 wt% Na₂O + K₂O) and …

Mechanisms Of Shear Zone Localization And Raman Thermobarometry In Spinel Peridotites From The Alpine Fault, New Zealand, Emily J. Lubicich

Dissertations and Theses

A suite of xenoliths from two localities on South Island, New Zealand, exhibit rare microstructures and provide information on deformation during the early stages of development of the Alpine Fault. The first set of samples has evidence of dislocation creep with subgrains, recrystallized grains, undulose extinction and a lattice preferred orientation. These samples also show evidence of post deformation static grain growth with polygonal grains, 120° triple junctions, and euhedral grains within larger grains of the same phase. Samples from the second locality also show evidence of dislocation creep but with minimal static grain growth. This set also has a …

Temporal Variability Of Fluorescent Dissolved Organic Matter At A Brackish, Tidal Marsh-Estuary Interface, Alana B. Menendez

Dissertations and Theses

Marshes are both terrestrial and aqueous, sitting as an intermediate between land and water. Studies over constrained numbers of tidal cycles have demonstrated that these marshes are net exporters of dissolved organic carbon (DOC) to adjoining estuaries, however, there is need for continuous monitoring to better understand the temporal variability of this flux: tidally, seasonally, and during episodic rain events. Through use of a YSI EXO2 sonde, an in situ optical sensor at the interface of the brackish, tidal Kirkpatrick Marsh and Rhode River sub-estuary in Edgewater, Maryland (located on the northwestern shore of the Chesapeake Bay), we were able …

Marsh-Exported Dissolved Organic Matter Fate In Estuaries, Laura Ann Logozzo

Dissertations and Theses

Dissolved organic matter (DOM) is a significant driver of estuarine productivity and nutrient cycling. The colored component of DOM, chromophoric dissolved organic matter (CDOM), impacts coastal optical properties, ocean color, and light attenuation. While marshes are largely considered sinks for carbon due to their high productivity and low soil carbon degradation rates, laterally they are sources of carbon as optically and chemically distinct DOM to surrounding aquatic ecosystems; these inputs are often essential in sustaining a net heterotrophic system. However, the photoreactivity and bioavailability of marsh-exported DOM is largely uncategorized, thus making it difficult to quantify its impacts on estuarine …

Analyzing Evapotranspiration In The Tropical Montane Cloud Forest At Sierra De Bahoruco, Dominican Republic, Emmanuel Rodriguez-Gonzalez

Dissertations and Theses

Lake Enriquillo is located in the southwestern extreme of Dominican Republic and has been experiencing a rapid expansion in surface area, along with other water bodies in the same region, since 2004 causing major flooding to the surrounding agricultural and cattle-raising lands, infrastructure and communities. Understanding why the lake is expanding at such rapid rate and accurately forecast how they will behave in the future is the main goal of The Hispaniola Lakes Project. The purpose of this project is to investigate the effects that hydrometeorological drivers are having on the forested areas located in Sierra de Bahoruco, which is …

Modern Foraminiferal Assemblages Of The Denmark Strait, Laura Larocca

Dissertations and Theses

Foraminifera occupy a geological range from the early Cambrian to the present day. Their well preserved shells, high relative abundance, and short response time to changing environmental conditions make foraminifera ideal proxies for environmental change. Benthic foraminifera are a valuable but poorly understood paleobiological proxy for the reconstruction of environmental conditions on continental shelves occupied by arctic and subarctic waters. This study identifies, examines, and quantifies calcareous benthic foraminiferal faunas from a sediment core taken from the Denmark Strait. Our analysis of three-thousand individuals from ten discrete samples aim to provide a better understanding of the modern patterns of foraminiferal …

Assessing The Utility Of Imaging Radar For Identifying White Sand Vegetation Structure, Jessica Rosenqvist

Dissertations and Theses

White sand vegetation communities are wide spread across South America; found in Peru, Venezuela, Brazilian Amazon and Guyana. They are distributed in patches ranging from <1 km2 to greater than tens of square kilometers and their origins and locations are still not well understood. The communities are related to a variety of factors (soil type, flooding, nutrient content and fire); hence a precise definition for the ecosystem is still not fully defined. Nevertheless, the result of these variations creates a unique environment for endemic plant and animal species to thrive. Furthermore, analysis of these areas has been very scattered and identification of local white sand areas (<1 km2) have not been accomplished. In addition, identification of these locations has currently only used optical satellite imagery (Landsat, MODIS). Hence, in this project, we have attempted to use synthetic aperture radar to create a classification system to locate the white sand vegetation systems. The goal is to be able to apply this method to identify white sand vegetation distribution across South America. The region of focus for this thesis has been in Aracá, a large white sand area located in Brazil in the State of Amazonas. Due to the lack of ground reference data, a classified map by Capurucho et al. (2013), generated using Landsat data, was used as a comparison and reference. JAXA’s ALOS-1 PALSAR (L-band), ESA’s Sentinel-1A (C-band) and NASA’s SRTM sensors were used for land classification. As microwave signals penetrate clouds and haze, the advantage of using sensors with this wavelength allows for an unobstructed coverage of the landscape all year round. Different combinations of polarizations and wavelengths were used during the analysis to try and separate the white sand vegetation from water and terra firme forest. The resulting classification images showed a 30% agreement with the classification map by Capurucho et al. It is important to note, that this number is in fact an agreement percentage as the map used was a classification image and coarse in resolution (due to the lack of reference data). Therefore, this value does not imply a bad classification. Future work will include time-series data, precise ground reference points and data from other sensors such as ALOS-2 PALSAR, to improve the classification accuracy.

Adsorption Of Antibiotics By Vermiculite, Mosa J. Ferdous

Dissertations and Theses

The occurrence of residual antibiotics in the environment has been a worldwide issue and warrants the development of inexpensive yet effective methods for antibiotics removal from contaminated water. In this thesis work, the adsorption of four antibiotics, namely chlorotetracycline (CTC), oxytetracycline (OTC), ofloxacin (OFL), and enrofloxacin (ENR), onto natural vermiculite has been studied using batch (static) and column (dynamic) adsorption techniques. The Langmuir and Freundlich isotherm models were initially used to explain the adsorption processes. The separation factor (RL) values derived from the Langmuir model and the 1/n values derived from Freundlich model in the present investigation were less than …

3d Structural And Stratigraphic Architecture Of The Northwest Santa Barbara Basin And Implications For Submarine Landslide Generation, Alexis Wright

Dissertations and Theses

Multiple submarine landslides have been previously documented on the north flank of the Santa Barbara Channel, and such failures are considered to be capable of generating local tsunamis hazards to the Santa Barbara region. 2D seismic-reflection datasets provide a general view of regional framework geology, including faulting and folding associated with north-south compression. However, better understanding of the relationships between faults, folds, stratigraphic architecture, and submarine landslides can be obtained with 3D seismic datasets. In this study we use an industry 3D seismic-reflection volume that encompasses the slope and shelfbreak surrounding the Gaviota submarine landslide (3.8 km2) to investigate structural …

Evidence For The Drainage Of A Superglacial Lake As The Source Of Seismic Waves Recorded At A Regional Distance, Erik J. Orantes

Dissertations and Theses

Surface melting during the summer leads to the formation of lakes on the Greenland Ice Sheet surface, known as supraglacial lakes. Some of these lakes drain through cracks in their beds and release the water into the ice sheet. Previous studies suggest that some of the water reaches the bedrock, enabling basal sliding, which could potentially increase glacial discharge (Sundal et al., 2009). Das et al. (2008) showed that supraglacial lake drainage can be accompanied by seismic activity, but little work has been done on the regional detection of such waves. The present study analyzes seismic data for the period …

Integrated Hydrologic Land Surface State Climate Indicators, Brian Lamb

Dissertations and Theses

No abstract provided.

Characterization Of Tropical Clouds Using Multi-Satellite Observations, Ricardo Anderson

Dissertations and Theses

Clouds an important component of the earth-climate system and play a critical role in affecting energy and water cycle of the planet. In particular, tropical convective clouds account for the majority of the precipitation that fall on the Earth's surface. Multiple active satellite missions in recent decade such as TRMM (Tropical Rainfall Measurement Mission), and CloudSat have provided fruitful new insight into the internal structures of these tropical convective clouds. In conjunction with cloud data from ISCCP (International Satellite Cloud Climatology Project), that is based passive remote sensing technology in the visible and infrared spectrum, this allows for a more …

Intra- And Inter-Seasonal Variability Of Supra-Glacial 1 Streams And Lakes Over The West Greenland Ice Sheet 2 From High-Resolution Satellite Optical Data, Michael Gregory Brown

Dissertations and Theses

The Greenland ice sheet (GrIS) is one of the largest glacial ice masses on Earth, second only to the Antarctic ice sheet. The surface hydrology of the GrIS plays a crucial role on the surface energy and mass balance budgets of the ice sheet as a whole. Surface water, known as supra-glacial water, is seasonally found in the ablation zone and feeds the en-glacial and sub-glacial hydrological environments of the ice sheet. The spatial distribution of surface streams is poorly understood and their temporal variability is (to our knowledge) unknown. One of the reasons for the lack of knowledge on …