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Multifunctional And Moisture Tolerant Zinc-Based Mono- And Bi-Metallic Metal-Organic Framework (Mof) Thin Films, Emmanuel Agbata
Multifunctional And Moisture Tolerant Zinc-Based Mono- And Bi-Metallic Metal-Organic Framework (Mof) Thin Films, Emmanuel Agbata
Theses and Dissertations
Many applications of metal-organic frameworks (MOFs) are highly dependent on their structures. The type and consistency of structure inform their properties. Zinc-based MOFs are applicable in different fields because of the low toxicity of zinc materials and are therefore also useful for catalysis. While MOF-5, a zinc-based MOF with carboxylate linkers is moisture intolerant, a variant of this is moisture tolerant. The introduction of a nitrogen-based linker in the zinc MOF which renders the structure moisture-tolerant. This material has not been explored as much, despite its multifunctional properties. Furthermore, the growth of Zn-based bimetallics of this MOF has not yet …