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Brigham Young University

Theses/Dissertations

1974

Articles 1 - 12 of 12

Full-Text Articles in Physical Sciences and Mathematics

The Purification And Characterization Of Methylmalonyl Coa Mutase From Bovine Brain, Damon Martin Sep 1974

The Purification And Characterization Of Methylmalonyl Coa Mutase From Bovine Brain, Damon Martin

Theses and Dissertations

Methylmalonyl CoA mutase has been purified over 2300-fold from bovine brain using fractional precipitation, ion exchange resins, and gel filtration procedures. The crude extract had an equal mixture of mutase in the halo- and apoenzyme form. After the final purification step the ratio had changed to 86% holo-enzyme and 14% apoenzyme. The mutase enzyme had a pH optimum of 7. 0 in Tris-HCI buffer. The Km values for L-methylmalonyl CoA and succinyl CoA were 7.7 x 10^-4 M and 1.8 x 10^-4 M respectively. The equiIibrium constant in the direction of succinyl CoA formation was 19. Inhibition with N-ethylmalei-mide was …

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The Benthic Communities Of The Eastern Rocky Shore Areas Of Goshen Bay, Utah Lake, Thomas Whitney Toole Aug 1974

The Benthic Communities Of The Eastern Rocky Shore Areas Of Goshen Bay, Utah Lake, Thomas Whitney Toole

Theses and Dissertations

Information about the benthic macroinvertebrate populations along the eastern shore of Goshen Bay, Utah Lake, Utah, can be used, in part, to determine future management of the lake. In the project herein reported, cement artificial substrate samplers were used to sample two types of substrate: rubble and compacted calcareous tufa. Monthly samples were obtained from each type of substrate from March 1972 to May 1973. An amphipod, Hyalela azteca and a chironomid, Dicrotendipes fumidus were the dominant organisms in numbers and tiomass. Amphipod numbers were dependent upon the amount of algal standing crop. Elimination of this area could affect the …

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The Attack Of Hard And Soft Nucleophiles On 6-Methylsulfonyl-, 6-Methylsulfinyl-, And 6-Methylthioaminopteridines, William David Johnston Aug 1974

The Attack Of Hard And Soft Nucleophiles On 6-Methylsulfonyl-, 6-Methylsulfinyl-, And 6-Methylthioaminopteridines, William David Johnston

Theses and Dissertations

In an attempt to prepare 6-anilino and 6-benzylaminopteridines, 2,4,7-triamino-6-methylsulfonyl and 2,4,7-triamino-6-methylsulfinylpteridines were prepared and reacted with a number of benzylamines and aniline. These hard nucleophiles gave amine exchange products with no displacement at the 6 position. Aliphatic amines gave exchange in the 2,4-and 7-positions. The exchange occurring in the 7-position must be occurring by an AE mechanism. This is the first such exchange reported in a ring other than a 1,3-azine. Aniline gave no exchange product except in an acid catalyzed reaction, and then gave exchange in only the 2 and 4-positions. Numerous reactions on related substrates, are reported. Soft …

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Part I. Catalytic Hydrocarbon Reforming By Technetium Catalysts.|Npart Ii.|Pacetone Azine And 3,5,5-Trimethyl-2-Pyrazoline Adducts Of Palladium Chloride, James Lynn Palmer Aug 1974

Part I. Catalytic Hydrocarbon Reforming By Technetium Catalysts.|Npart Ii.|Pacetone Azine And 3,5,5-Trimethyl-2-Pyrazoline Adducts Of Palladium Chloride, James Lynn Palmer

Theses and Dissertations

Technetium catalyzes hydrocarbon reforming reactions of dehydrocyclization, isomerization, hydrogenolysis, and coke formation. A kinetic equation was derived and E_a and A_o evaluated for dehydrocyclization of n-heptane, isomerization of n-pentane, and dehydrogenation of methylcyclohexane and cyclohexane. The results were related to the metal, the form of the catalyst, catalyst support, and the deactivation of the catalyst. The effect of sulfur compounds was determined. No residual radioactivity in the product was observed. The ligands, acetone azine (AA) and 3,5,5-trimethyl-2- pyrazoline (Py), reacted with (C_6H_5CN)_2PdCl_2 to form adducts, L_2PdCl_2 and (LPdCl_2)_n. Their structures were characterized by spectroscopic methods and some molecular weights determined. …

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Metabolism Of 3-Isopropyl-4h-2,1,3-Benzothiadiazin-4-(3h)-One-2,2-Dioxide (Bentazon) In Agitated And Non-Agitated Sediment, David Cortez Gutierrez Aug 1974

Metabolism Of 3-Isopropyl-4h-2,1,3-Benzothiadiazin-4-(3h)-One-2,2-Dioxide (Bentazon) In Agitated And Non-Agitated Sediment, David Cortez Gutierrez

Theses and Dissertations

Bentazon, (3-isopropyl-1H-2,1,3-benzothiadiazin-4(3H)-l-2,2-dioxide) a new experimental herbicide, was studied under the effects of sterile and non-sterile conditions, 12 hours light: 12 hours dark and totally dark conditions, and agitated and non-agitated conditions in aquatic sediment. The effects of the different levels of BOD/COD values on the decomposition of Bentazon were studied. Photoperiod, sterility, and BOD/COD levels appeared to have no influence in the breakdown of Bentazon. Agitation-time interaction appeared to be the only factor that influenced the more rapid degradation of Bentazon. Bentazon was the major 14C-residue found in the water; it was followed by an unknown. The third major metabolite …

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Thermodynamic Stability Constants Of Silver Bromide Complexes In Water And Water-Acetone Mixtures Determined By Ion-Selective Electrode Measurements, Arthur Lee Cummings Aug 1974

Thermodynamic Stability Constants Of Silver Bromide Complexes In Water And Water-Acetone Mixtures Determined By Ion-Selective Electrode Measurements, Arthur Lee Cummings

Theses and Dissertations

Thermodynamic equilibrium constants for silver(I) bromide complexes were determined by ion-selective membrane electrode potential measurements in water and in mixtures of water and acetone of approximately 5, 10 and 15 percent acetone by weight. Values of the solubility product constant were determined in each solvent system by calibration of a silver bromide membrane electrode with silver nitrate solutions and with sodium bromide solutions. Stability constants of silver(I) bromide complexes were determined using a silver ion-selective, silver sulfide membrane electrode in unsaturated solutions in which the formal concentrations of silver(I) and of bromide ranged from approximately I x 10-8 to 7 …

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A Remote Aerosol Sampler To Be Used With Charged-Particle X-Ray Fluorescence Analysis, Steven Dee Rowley Aug 1974

A Remote Aerosol Sampler To Be Used With Charged-Particle X-Ray Fluorescence Analysis, Steven Dee Rowley

Theses and Dissertations

A remote aerosol sampler, capable of up to 3 weeks continuous sampling has been developed. It consists of an Anderson 2000 Inc. mini-sampler or personnel monitor requiring an air flow of 1.4 e/min, a flow meter, a vacuum meter, a bleed valve, a dry gas volume meter, and a pump. The pump is a Brailsford Model TD-4X2, and operates on a 24 volt D.C. power supply. The sampler consists of four impaction stages with a 0.4 μ Nuclepore backup filter. Particulates are removed from the plates in an ultrasonic cleaner with hexane solvent. The suspended particulates are collected on a …

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A Calorimetric Study Of Metal Binding In Carboxypeptidase, Carbonic Anhydrase And Concanavalin A, Gary E. Hatch Apr 1974

A Calorimetric Study Of Metal Binding In Carboxypeptidase, Carbonic Anhydrase And Concanavalin A, Gary E. Hatch

Theses and Dissertations

The purpose of this study was to perfect a new calorimetric method for identifying and counting ionizable chemical groups on proteins. To do this, calorimetric and electrometric titrations were performed (using HCl and NaOH as titrant) on native carboxypeptidase, carbonic anhydrase and concanavalin A plus their apo and organic ligand bound derivatives. Readily identifiable endpoints were seen in the calorimetric titrations and general agreement was found between ΔH values obtained in this study and literature ΔH values of model compounds undergoing the same reaction. Imidazole groups were those most easily counted. Many assumptions had to be made, however, in concluding …

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Trace Metal Analysis Of Hair By Charged Particle X-Ray Fluorescence, George M. Allison Apr 1974

Trace Metal Analysis Of Hair By Charged Particle X-Ray Fluorescence, George M. Allison

Theses and Dissertations

A method for the trace element analysis of hair by charged particle X-ray fluorescence is presented. The validity of the method is shown by the analysis of NBS SRM 1577--Bovine Liver, obtained from the National Bureau of Standards. Excellent correlation is obtained between results from the analysis by the X-ray method and those certified by NBS. Hair samples are ashed by a low temperature oxidation process and analyzed by the X-ray method. The results from the analysis by the X-ray method are compared to those obtained from the analysis of the same hair samples by atomic absorption. Good correlation is …

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Macrocyclic Polyether Sulfide Syntheses, The Preparation Of Thia-Crown-3, 4, 6, And 7 Compounds, Yau-Kwong Joseph Hui Apr 1974

Macrocyclic Polyether Sulfide Syntheses, The Preparation Of Thia-Crown-3, 4, 6, And 7 Compounds, Yau-Kwong Joseph Hui

Theses and Dissertations

Macrocyclic polyether sulfides have been prepared by reacting an oligoethylene glycol dichloride with a dithiol or sodium sulfide in ethanol. The following new compounds were prepared: 1-thia-(9-crown-3), 1,4-dithia-(9-crown-3), 1,4-dithia-(12-crown-4), 1,4,7-trithia-(12-crown-4), 1-thia-(18-crown-6), I,4-dithia-(18-crown-6), 1,7-dithia-(18-crown-6), 1,4,7-trithia-(18-crown-6), 1,7-dithia-(21-crown-7), 1,4,7-trithia-(21-crown-7). Four other previously reported macrocyclic polyether sulfides were also prepared. The symmetry of the nmr spectra of these compounds give added evidence for the proposed ring structures. The following subjects were presented and discussed: studies of cyclization by-products, dependence of cyclization yield on the size of the rings, high dilution principle and its application, medium-sized rings, effect of hetero-atoms on cyclization and melting point …

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The Solution Photochemistry Of Benzaldehyde In Benzene, Ethanol, And 1-Hexyne, Ronald Douglas Knudsen Apr 1974

The Solution Photochemistry Of Benzaldehyde In Benzene, Ethanol, And 1-Hexyne, Ronald Douglas Knudsen

Theses and Dissertations

The photoreactions of benzaldehyde in benzene, ethanol, and 1-hexyne have been studied. Irradiation of benzaldehyde in benzene produces benzoin (I), hydrobenzoin (II), and deoxybenzoin (III). Irradiation of benzoin (I) in this solvent results in benzaldehyde formation as well as small amounts of (II) and (III). The ethanol irradiation of benzaldehyde resulted, predominantly, in the formation of (II) with (I) formed in small amounts. The photolysis of benzaldehyde in 1-hexyne produces (I), (II), (III) cis-2-heptenophenone (VII), trans-2-heptenophenone (VIII), heptanophenone (IX), and 2-(n-butyl)- 1,4-diphenyl-1,4-butanedione (X). Mechanistic pathways for the formation of these photoproducts are discussed. Separation and characterization of cis- and trans-2- …

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The Mormon Role In Irrigation Beginnings And Diffusions In The Western States: An Historical Geography, Kelly C. Harper Jan 1974

The Mormon Role In Irrigation Beginnings And Diffusions In The Western States: An Historical Geography, Kelly C. Harper

Theses and Dissertations

Irrigation has played an important part in the development of the Western States. Its beginnings have often been associated with the Mormon settlement in Utah. However, irrigation had its inception in the West long before the Mormons came to the Great Basin in 1847. The spatial extent of irrigation before this date included limited acreage in nearly every Western State.

Before their arrival in the Great Basin the Mormons had become acquainted with irrigation methods. Knowledge of irrigation had diffused to them primarily from the Spanish in the Southwest. Thus, they were well prepared to begin their irrigation enterprises in …

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