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Full-Text Articles in Physical Sciences and Mathematics

Strain-Driven Growth Of Gaas(111) Quantum Dots With Low Fine Structure Splitting, Paul J. Simmonds Dec 2014

Strain-Driven Growth Of Gaas(111) Quantum Dots With Low Fine Structure Splitting, Paul J. Simmonds

Physics Faculty Publications and Presentations

Symmetric quantum dots (QDs) on (111)-oriented surfaces are promising candidates for generating polarization-entangled photons due to their low excitonic fine structure splitting(FSS). However, (111) QDs are difficult to grow. The conventional use of compressive strain to drive QD self-assembly fails to form 3D nanostructures on (111) surfaces. Instead, we demonstrate that (111) QDs self-assemble under tensile strain by growing GaAs QDs on an InP(111)A substrate. Tensile GaAs self-assembly produces a low density of QDs with a symmetric triangular morphology. Coherent, tensile QDs are observed without dislocations, and the QDs luminescence at room temperature. Single QD measurements reveal low FSS with …


Mapping Thunder Sources By Inverting Acoustic And Electromagnetic Observations, J. F. Anderson, J. B. Johnson, R. O. Arechiga, R. J. Thomas Dec 2014

Mapping Thunder Sources By Inverting Acoustic And Electromagnetic Observations, J. F. Anderson, J. B. Johnson, R. O. Arechiga, R. J. Thomas

Geosciences Faculty Publications and Presentations

We present a new method of locating current flow in lightning strikes by inversion of thunder recordings constrained by Lightning Mapping Array observations. First, radio frequency (RF) pulses are connected to reconstruct conductive channels created by leaders. Then, acoustic signals that would be produced by current flow through each channel are forward modeled. The recorded thunder is considered to consist of a weighted superposition of these acoustic signals. We calculate the posterior distribution of acoustic source energy for each channel with a Markov Chain Monte Carlo inversion that fits power envelopes of modeled and recorded thunder; these results show which …


Urban Seismology For Groundwater Characterization In A Developing Country: Challenges And Rewards, John H. Bradford, Kyle Lindsay, Steve Silliman, Nicaise Yalo, Moussa Boukari Dec 2014

Urban Seismology For Groundwater Characterization In A Developing Country: Challenges And Rewards, John H. Bradford, Kyle Lindsay, Steve Silliman, Nicaise Yalo, Moussa Boukari

Geosciences Faculty Publications and Presentations

The coastal city of Cotonou in the developing country of Bénin, West Africa, is a large population center that is facing a serious threat to the sustainability of its freshwater supply. The city relies on the Godomey aquifer for domestic water, but the aquifer is undergoing saltwater intrusion. This problem is likely to worsen without significant steps to improve management of the water supply. Aquifer continuity and saltwater flow paths are poorly understood, but that information is critical to ensure sustainable access to freshwater in this growing urban center. In January 2012, a two-year geophysical investigation was begun with the …


Quantifying The Basal Conditions Of A Mountain Glacier Using A Targeted Full-Waveform Inversion: Bench Glacier, Alaska, Usa, E. Babcock, J. Bradford Dec 2014

Quantifying The Basal Conditions Of A Mountain Glacier Using A Targeted Full-Waveform Inversion: Bench Glacier, Alaska, Usa, E. Babcock, J. Bradford

Geosciences Faculty Publications and Presentations

Glacier dynamics are inextricably linked to the basal conditions of glaciers. Seismic reflection methods can image the glacier bed under certain conditions. However, where a seismically thin layer of material is present at the bed, traditional analyses may fail to fully characterize bed properties. We use a targeted full-waveform inversion algorithm to quantify the basal-layer parameters of a mountain glacier: thickness (d), P-wave velocity (α) and density (ρ). We simultaneously invert for the seismic quality factor (Q) of the bulk glacier ice. The inversion seeks to minimize the difference between the data …


Turbidity-Based Sediment Monitoring In Northern Thailand: Hysteresis, Variability, And Uncertainty, Shawn G. Benner, Spencer H. Wood Nov 2014

Turbidity-Based Sediment Monitoring In Northern Thailand: Hysteresis, Variability, And Uncertainty, Shawn G. Benner, Spencer H. Wood

Geosciences Faculty Publications and Presentations

Annual total suspended solid (TSS) loads in the Mae Sa River in northern Thailand, determined with an automated, turbidity-based monitoring approach, were approximately 62,000, 33,000, and 14,000 Mg during the three years of observation. These loads were equivalent to basin yields of 839 (603-1170), 445 (217-462), and 192 (108-222) Mg km-2 for the 74.16-km2 catchment during 2006, 2007, and 2008, respectively. The yearly uncertainty ranges indicate our loads may be underestimated by 38-43% or overestimated by 28-33%. In determining the annual loads, discharge (Q) and turbidity (T) values were compared against 333 hand-sampled total suspended solid concentrations (TSS) …


Evolution Of Acyl-Substrate Recognition By A Family Of Acyl-Homoserine Lactone Synthases, Quin H. Christensen, Ryan M. Brecht, Dastagiri Dudekula, E. Peter Greenberg, Rajesh Nagarajan Nov 2014

Evolution Of Acyl-Substrate Recognition By A Family Of Acyl-Homoserine Lactone Synthases, Quin H. Christensen, Ryan M. Brecht, Dastagiri Dudekula, E. Peter Greenberg, Rajesh Nagarajan

Chemistry and Biochemistry Faculty Publications and Presentations

Members of the LuxI protein family catalyze synthesis of acyl-homoserine lactone (acyl-HSL) quorum sensing signals from S-adenosyl-L-methionine and an acyl thioester. Some LuxI family members prefer acyl-CoA, and others prefer acyl-acyl carrier protein (ACP) as the acyl-thioester substrate. We sought to understand the evolutionary history and mechanisms mediating this substrate preference. Our phylogenetic and motif analysis of the LuxI acyl-HSL synthase family indicates that the acyl-CoA-utilizing enzymes evolved from an acyl-ACP-utilizing ancestor. To further understand how acyl-ACPs and acyl-CoAs are recognized by acyl-HSL synthases we studied BmaI1, an octanoyl-ACP-dependent LuxI family member from Burkholderia mallei, and BjaI, an …


Warm Water Benthic Foraminifera Document The Pennsylvanian-Permian Warming And Cooling Events – The Record From The Western Pangea Tropical Shelves, Vladimir Davydov Nov 2014

Warm Water Benthic Foraminifera Document The Pennsylvanian-Permian Warming And Cooling Events – The Record From The Western Pangea Tropical Shelves, Vladimir Davydov

Geosciences Faculty Publications and Presentations

Shallow warm water benthic foraminifera (SWWBF), including all larger fusulinids (symbiont-bearing benthic foraminifera), are among the best indicators of paleoclimate and paleogeography in the Carboniferous and Permian. The distribution of benthic foraminifera in space and time constrain important tectonic, paleogeographic and climatic events at a global scale. The North American shelves during Pennsylvanian and Permian time - though geographically within the tropical belt - are characterized by temperate environments with significantly lower foraminifera diversification and rare occurrences of warm water Tethyan forms, that are in general appear in the region as a migration entities. Such environments allow documentation of warming …


Comparing Near-Regional And Local Measurements Of Infrasound From Mount Erebus, Antarctica: Implications For Monitoring, A. L. Dabrowa, D. N. Green, J. B. Johnson, J. C. Phillips, A. C. Rust Nov 2014

Comparing Near-Regional And Local Measurements Of Infrasound From Mount Erebus, Antarctica: Implications For Monitoring, A. L. Dabrowa, D. N. Green, J. B. Johnson, J. C. Phillips, A. C. Rust

Geosciences Faculty Publications and Presentations

Local (100s of meters from vent) monitoring of volcanic infrasound is a common tool at volcanoes characterized by frequent low-magnitude eruptions, but it is generally not safe or practical to have sensors so close to the vent during more intense eruptions. To investigate the potential and limitations of monitoring at near-regional ranges (10s of km) we studied infrasound detection and propagation at Mount Erebus, Antarctica. This site has both a good local monitoring network and an additional International Monitoring System infrasound array, IS55, located 25 km away. We compared data recorded at IS55 with a set of 117 known Strombolian …


Application Of The Monopole Source To Quantify Explosive Flux During Vulcanian Explosions At Sakurajima Volcano (Japan), Jeffrey B. Johnson, Alex J. C. Miller Nov 2014

Application Of The Monopole Source To Quantify Explosive Flux During Vulcanian Explosions At Sakurajima Volcano (Japan), Jeffrey B. Johnson, Alex J. C. Miller

Geosciences Faculty Publications and Presentations

A primary goal in volcano seismology is to characterize source motions internal to a volcano in terms of their representative forces. In a similar manner, much volcano infrasound research strives to recover eruptive force time histories corresponding to material accelerations occurring at Earth’s free surface. These motions may correspond to explosive emission of gas and pyroclasts (e.g., Banister, 1984), rapid ground distensions of a volcanic dome (e.g., Johnson and Lees, 2010), and/or gravity driven rock fall or pyroclastic flows (e.g., Yamasato, 1997). When free surface motion is unsteady it imposes stresses upon the surrounding atmosphere, which are propagated as acoustic …


Introduction To An Open Community Infrasound Dataset From The Actively Erupting Sakurajima Volcano, Japan, David Fee, Akihiko Yokoo, Jeffrey B. Johnson Nov 2014

Introduction To An Open Community Infrasound Dataset From The Actively Erupting Sakurajima Volcano, Japan, David Fee, Akihiko Yokoo, Jeffrey B. Johnson

Geosciences Faculty Publications and Presentations

Active volcanoes are significant sources of seismic and acoustic radiation. Extensive work has shown that infrasound is an effective tool to study and monitor active volcanoes. Infrasound is now a regular tool utilized by volcano observatories to aid in volcano monitoring and hazard mitigation. Infrasound‐based studies are able to provide important information on eruption dynamics and to develop quantitative models of volcanic eruptions. In addition, volcanoes provide excellent acoustic sources for atmospheric propagation studies and can be used to infer atmospheric dynamics and structure (see Johnson and Ripepe, 2011; Fee and Matoza, 2013 for recent reviews on volcano infrasound). The …


Eocene-Oligocene Latitudinal Climate Gradients In North America Inferred From Stable Isotope Ratios In Perissodactyl Tooth Enamel, Alessandro Zanazzi, Emily Judd, Andrew Fletcher, Harold Bryant, Matthew J. Kohn Oct 2014

Eocene-Oligocene Latitudinal Climate Gradients In North America Inferred From Stable Isotope Ratios In Perissodactyl Tooth Enamel, Alessandro Zanazzi, Emily Judd, Andrew Fletcher, Harold Bryant, Matthew J. Kohn

Geosciences Faculty Publications and Presentations

The Eocene-Oligocene transition (~ 34 Ma) was one of the most pronounced episodes of climate change of the Cenozoic. In order to investigate this episode of global climate cooling in North America, we analyzed the carbon and oxygen stable isotope composition of the carbonate component of 19 perissodactyl (horse and rhino) tooth enamel samples from the Eocene-Oligocene rocks of the Cypress Hills Formation (southwestern Saskatchewan, Canada); we then compared the results with previously published data from the US Great Plains (Nebraska, South Dakota, and Wyoming).

Average (± 1σ) perissodactyl enamel δ13C values (vs. V-PDB) in the Eocene (-8.8 …


Explosive Dome Eruptions Modulated By Periodic Gas-Driven Inflation, Jeffrey B. Johnson, J. J. Lyons, B. J. Andrews, J. M. Lees Oct 2014

Explosive Dome Eruptions Modulated By Periodic Gas-Driven Inflation, Jeffrey B. Johnson, J. J. Lyons, B. J. Andrews, J. M. Lees

Geosciences Faculty Publications and Presentations

Volcan Santiaguito (Guatemala) “breathes” with extraordinary regularity as the edifice's conduit system accumulates free gas, which periodically vents to the atmosphere. Periodic pressurization controls explosion timing, which nearly always occurs at peak inflation, as detected with tiltmeters. Tilt cycles in January 2012 reveal regular 26 ± 6 min inflation/deflation cycles corresponding to at least ~101 kg/s of gas fluxing the system. Very long period (VLP) earthquakes presage explosions and occur during cycles when inflation rates are most rapid. VLPs locate ~300 m below the vent and indicate mobilization of volatiles, which ascend at ~50 m/s. Rapid gas ascent feeds …


Kinetic Competition During The Transcription Cycle Results In Stochastic Rna Processing, Antoine Coulon, Matthew L. Ferguson, Valeria De Turris, Murali Palangat, Carson C. Chow, Daniel R. Larson Oct 2014

Kinetic Competition During The Transcription Cycle Results In Stochastic Rna Processing, Antoine Coulon, Matthew L. Ferguson, Valeria De Turris, Murali Palangat, Carson C. Chow, Daniel R. Larson

Physics Faculty Publications and Presentations

Synthesis of mRNA in eukaryotes involves the coordinated action of many enzymatic processes, including initiation, elongation, splicing, and cleavage. Kinetic competition between these processes has been proposed to determine RNA fate, yet such coupling has never been observed in vivo on single transcripts. In this study, we use dual-color single-molecule RNA imaging in living human cells to construct a complete kinetic profile of transcription and splicing of the β-globin gene. We find that kinetic competition results in multiple competing pathways for pre-mRNA splicing. Splicing of the terminal intron occurs stochastically both before and after transcript release, indicating there is not …


The Spatial Cross-Correlation Method For Dispersive Surface Waves, Andrew P. Lamb, Kasper Van Wijk, Lee M. Liberty, T. Dylan Mikesell Oct 2014

The Spatial Cross-Correlation Method For Dispersive Surface Waves, Andrew P. Lamb, Kasper Van Wijk, Lee M. Liberty, T. Dylan Mikesell

Geosciences Faculty Publications and Presentations

Dispersive surface waves are routinely used to estimate the subsurface shear-wave velocity distribution, at all length scales. In the well-known Spatial Autocorrelation method, dispersion information is gained from the correlation of seismic noise signals recorded on the vertical (or radial) components. We demonstrate practical advantages of including the cross-correlation between radial and vertical components of the wavefield in a spatial cross-correlation method. The addition of cross-correlation information increases the resolution and robustness of the phase velocity dispersion information, as demonstrated in numerical simulations and a near-surface field study with active seismic sources, where our method confirms the presence of a …


Luminescence Dating Without Sand Lenses: An Application Of Osl To Coarse-Grained Alluvial Fan Deposits Of The Lost River Range, Idaho, Usa, M. K. Kenworthy, T. M. Rittenour, J. L. Pierce, N. A. Sutfin, W. D. Sharp Oct 2014

Luminescence Dating Without Sand Lenses: An Application Of Osl To Coarse-Grained Alluvial Fan Deposits Of The Lost River Range, Idaho, Usa, M. K. Kenworthy, T. M. Rittenour, J. L. Pierce, N. A. Sutfin, W. D. Sharp

Geosciences Faculty Publications and Presentations

Optically stimulated luminescence (OSL) dating is increasingly used to estimate the age of fluvial deposits. A significant limitation, however, has been that conventional techniques of sampling and dose rate estimation are suitable only for thick (>60 cm) layers consisting of sand size or finer grains. Application of OSL dating to deposits lacking such layers remains a significant challenge. Alluvial fans along the western front of the Lost River Range in east-central Idaho, USA are one example. Deposits are typically pebble to cobble sheetflood gravels with a sandy matrix but thin to absent sand lenses. As a result, the majority …


Calculating The Velocity Of A Fast-Moving Snow Avalanche Using An Infrasound Array, Scott Havens, Hans-Peter Marshall, Jeffrey B. Johnson, Bill Nicholson Sep 2014

Calculating The Velocity Of A Fast-Moving Snow Avalanche Using An Infrasound Array, Scott Havens, Hans-Peter Marshall, Jeffrey B. Johnson, Bill Nicholson

Geosciences Faculty Publications and Presentations

On 19 January 2012, a large D3 avalanche (approximately 103 t) was recorded with an infrasound array ideally situated for observing the avalanche velocity. The avalanche crossed Highway 21 in Central Idaho during the largest avalanche cycle in the 15 years of recorded history and deposited approximately 8 m of snow on the roadway. Possible source locations along the avalanche path were estimated at 0.5 s intervals and were used to calculate the avalanche velocity during the 64 s event. Approximately 10 s prior to the main avalanche signal, a small infrasound signal originated from the direction of the …


Medicinal History Of North American Veratrum, Christopher M. Chandler, Owen M. Mcdougal Sep 2014

Medicinal History Of North American Veratrum, Christopher M. Chandler, Owen M. Mcdougal

Chemistry and Biochemistry Faculty Publications and Presentations

Plants belonging to the genus Veratrum have been used throughout history for their medicinal properties. During the nineteenth and twentieth centuries, phytochemical investigations revealed a host of steroidal alkaloids in Veratrum species, some of which are potent bioactives. This review discusses Veratrum species that grow in North America with a focus on the medicinal history of these plants and the steroidal alkaloids they contain. While significant reviews have been devoted to singularly describing the plant species within the genus Veratrum (botany), the staggering breadth of alkaloids isolated from these and related plants (phytochemistry), and the intricacies of how the various …


Postglacial Early Permian (Late Sakmarian– Early Artinskian) Shallow-Marine Carbonate Deposition Along A 2000 Km Transect From Timor To West Australia, Vladimir I. Davydov Sep 2014

Postglacial Early Permian (Late Sakmarian– Early Artinskian) Shallow-Marine Carbonate Deposition Along A 2000 Km Transect From Timor To West Australia, Vladimir I. Davydov

Geosciences Faculty Publications and Presentations

Late Sakmarian to early Artinskian (Early Permian) carbonate deposition was widespread in the marine intracratonic rift basins that extended into the interior of Eastern Gondwana from Timor in the north to the northern Perth Basin in the south. These basins spanned about 20° of paleolatitude (approximately 35°S to 55°S). This study describes the type section of the Maubisse Limestone in Timor-Leste, and compares this unit with carbonate sections in the Canning Basin (Nura Nura Member of the Poole Sandstone), the Southern Carnarvon Basin (Callytharra Formation) and the northern Perth Basin (Fossil Cliff Member of the Holmwood Shale). The carbonate units …


Sliding Rocks On Racetrack Playa, Death Valley National Park: First Observation Of Rocks In Motion, Richard D. Norris, James M. Norris, Ralph D. Lorenz, Jib Ray, Brian Jackson Aug 2014

Sliding Rocks On Racetrack Playa, Death Valley National Park: First Observation Of Rocks In Motion, Richard D. Norris, James M. Norris, Ralph D. Lorenz, Jib Ray, Brian Jackson

Physics Faculty Publications and Presentations

The engraved trails of rocks on the nearly flat, dry mud surface of Racetrack Playa, Death Valley National Park, have excited speculation about the movement mechanism since the 1940s. Rock movement has been variously attributed to high winds, liquid water, ice, or ice flotation, but has not been previously observed in action. We recorded the first direct scientific observation of rock movements using GPS-instrumented rocks and photography, in conjunction with a weather station and time-lapse cameras. The largest observed rock movement involved >60 rocks on December 20, 2013 and some instrumented rocks moved up to 224 m between December 2013 …


Discovery Of Shallow-Marine Biofacies Conodonts In A Bioherm Within The Carboniferous-Permian Transition In The Omalon Massif, Ne Russia Near The North Paleo-Pole: Correlation With A Warming Spike In The Southern Hemisphere, Vladimir I. Davydov, Alexander S. Biakov Aug 2014

Discovery Of Shallow-Marine Biofacies Conodonts In A Bioherm Within The Carboniferous-Permian Transition In The Omalon Massif, Ne Russia Near The North Paleo-Pole: Correlation With A Warming Spike In The Southern Hemisphere, Vladimir I. Davydov, Alexander S. Biakov

Geosciences Faculty Publications and Presentations

The conodont genera Hindeodus and Streptognathodus are reported for the first time within the Carboniferous-Permian transition in the northern high latitudes of the Paren’ River, Omolon Massif, NE Russia. Several fossil groups, including brachiopods, bivalves, scaphopods and microgastropods were found to be prolific in the invertebrate-dominated bioherms. These bioherms occur within predominantly siliciclastic sequences with extremely poor fauna, whereas in the studied bioherms the diversity of the bivalves and brachiopods exceeded observed diversity elsewhere in coeval facies in NE Russia. The bioherms are biostratigraphically constrained as uppermost Pennsylvanian to lowermost Cisuralian based on ammonoids. The very unusual peak of bivalve …


How Do They Know It Is A Parallelogram? Analysing Geometric Discourse At Van Hiele Level 3, Sasha Wang, Margaret Kinzel Jul 2014

How Do They Know It Is A Parallelogram? Analysing Geometric Discourse At Van Hiele Level 3, Sasha Wang, Margaret Kinzel

Mathematics Faculty Publications and Presentations

In this article, we introduce Sfard's discursive framework and use it to investigate prospective teachers' geometric discourse in the context of quadrilaterals. In particular, we focus on describing and analysing two participants' use of mathematical words and substantiation routines related to parallelograms and their properties at van Hiele level 3 thinking. Our findings suggest that a single van Hiele level of thinking encompasses a range of complexity of reasoning and differences in discourse and thus a deeper investigation of students' mathematical thinking within assigned van Hiele levels is warranted.


Radical Constructivism And Social Justice: Educational Implications, Dewey I. Dykstra Jr. Jul 2014

Radical Constructivism And Social Justice: Educational Implications, Dewey I. Dykstra Jr.

Physics Faculty Publications and Presentations

Upshot • Gash describes some very interesting and exemplary work using RC-influenced research and practices. I worry that his third stage of a three-stage emergence of constructivist epistemology in the study of cognitive development is consistent with a distinction between focus on individual cognitive development and focus on knowledge not in the mind but in the group, inconsistent with RC. An alternative is given and the issue of an RC perspective on social justice is discussed.


Automorphisms Of Cornoa Algebras, And Group Cohomology, Samuel Coskey, Ilijas Farah Jul 2014

Automorphisms Of Cornoa Algebras, And Group Cohomology, Samuel Coskey, Ilijas Farah

Mathematics Faculty Publications and Presentations

In 2007 Phillips and Weaver showed that, assuming the Continuum Hypothesis, there exists an outer automorphism of the Calkin algebra. (The Calkin algebra is the algebra of bounded operators on a separable complex Hilbert space, modulo the compact operators.) In this paper we establish that the analogous conclusion holds for a broad family of quotient algebras. Specifically, we will show that assuming the Continuum Hypothesis, if A is a separable algebra which is either simple or stable, then the corona of A has nontrivial automorphisms. We also discuss a connection with cohomology theory, namely, that our proof can be viewed …


Independent Evaluation Of The Snodas Snow Depth Product Using Regional Scale Lidar-Derived Measurements, A. R. Hedrick, H. P. Marshall, A. Winstral, K. Elder, S. Yueh, D. Cline Jun 2014

Independent Evaluation Of The Snodas Snow Depth Product Using Regional Scale Lidar-Derived Measurements, A. R. Hedrick, H. P. Marshall, A. Winstral, K. Elder, S. Yueh, D. Cline

Geosciences Faculty Publications and Presentations

Repeated Light Detection and Ranging (LiDAR) surveys are quickly becoming the de facto method for measuring spatial variability of montane snowpacks at high resolution. This study examines the potential of a 750 km2 LiDAR-derived dataset of snow depths, collected during the 2007 northern Colorado Cold Lands Processes Experiment (CLPX-2), as a validation source for an operational hydrologic snow model. The SNOw Data Assimilation System (SNODAS) model framework, operated by the US National Weather Service, combines a physically-based energy-and-mass-balance snow model with satellite, airborne and automated ground-based observations to provide daily estimates of snowpack properties at nominally 1 km resolution …


Design Of A Flexible Component Gathering Algorithm For Converting Cell-Based Models To Graph Representations For Use In Evolutionary Search, Marianna Budnikova, Jeffrey W. Habig, Daniel Lobo, Nicolas Cornia, Michael Levin, Tim Andersen Jun 2014

Design Of A Flexible Component Gathering Algorithm For Converting Cell-Based Models To Graph Representations For Use In Evolutionary Search, Marianna Budnikova, Jeffrey W. Habig, Daniel Lobo, Nicolas Cornia, Michael Levin, Tim Andersen

Computer Science Faculty Publications and Presentations

Background

The ability of science to produce experimental data has outpaced the ability to effectively visualize and integrate the data into a conceptual framework that can further higher order understanding. Multidimensional and shape-based observational data of regenerative biology presents a particularly daunting challenge in this regard. Large amounts of data are available in regenerative biology, but little progress has been made in understanding how organisms such as planaria robustly achieve and maintain body form. An example of this kind of data can be found in a new repository (PlanformDB) that encodes descriptions of planaria experiments and morphological outcomes using a …


Trends In Extreme U.S. Temperatures, Jaechoul Lee, Shanghong Li, Robert Lund Jun 2014

Trends In Extreme U.S. Temperatures, Jaechoul Lee, Shanghong Li, Robert Lund

Mathematics Faculty Publications and Presentations

This paper develops trend estimation techniques for monthly maximum and minimum temperature time series observed in the 48 conterminous United States over the last century. While most scientists concur that this region has warmed on aggregate, there is no a priori reason to believe that temporal trends in extremes and averages will exhibit the same patterns. Indeed, under minor regularity conditions, the sample partial sum and maximum of stationary time series are asymptotically independent (statistically). Previous authors have suggested that minimum temperatures are warming faster than maximum temperatures in the United States; such an aspect can be investigated via the …


U-Pb Zircon Geochronology Of Roxbury Conglomerate, Boston Basin, Massachusetts: Tectono-Stratigraphic Implications For Avalonia In And Beyond Se New England, Margaret D. Thompson, Jahandar Ramezani, James L. Crowley Jun 2014

U-Pb Zircon Geochronology Of Roxbury Conglomerate, Boston Basin, Massachusetts: Tectono-Stratigraphic Implications For Avalonia In And Beyond Se New England, Margaret D. Thompson, Jahandar Ramezani, James L. Crowley

Geosciences Faculty Publications and Presentations

High-precision CA-TIMS 206Pb/238U zircon dates from sandstone and Brighton igneous rocks associated with Roxbury Conglomerate in the Boston Basin, eastern Massachusetts provide constraints on the age and tectonic significance of these deposits. Detrital zircon suites from Roxbury-related sandstones representing, in ascending order, the Franklin Park Member (proposed name), the Brookline Member and the Squantum Member establish closely comparable maximum depositional ages of 595.14 ± 0.90, 598.87 ± 0.71 and 596.39 ± 0.79 Ma, respectively. The youngest of these is the best maximum age estimate of the conglomerate. Brighton dacite near the base of the Brookline Member and …


Cytotoxicity Of Zno Nanoparticles Can Be Tailored By Modifying Their Surface Structure: A Green Chemistry Approach For Safer Nanomaterials, Alex Punnoose, Kelsey Dodge, John W. Rasmussen, Jordan Chess, Denise Wingett, Catherine Anders May 2014

Cytotoxicity Of Zno Nanoparticles Can Be Tailored By Modifying Their Surface Structure: A Green Chemistry Approach For Safer Nanomaterials, Alex Punnoose, Kelsey Dodge, John W. Rasmussen, Jordan Chess, Denise Wingett, Catherine Anders

Physics Faculty Publications and Presentations

ZnO nanoparticles (NP) are extensively used in numerous nanotechnology applications; however, they also happen to be one of the most toxic nanomaterials. This raises significant environmental and health concerns and calls for the need to develop new synthetic approaches to produce safer ZnO NP, while preserving their attractive optical, electronic, and structural properties. In this work, we demonstrate that the cytotoxicity of ZnO NP can be tailored by modifying their surface-bound chemical groups, while maintaining the core ZnO structure and related properties. Two equally sized (9.26 ± 0.11 nm) ZnO NP samples were synthesized from the same zinc acetate precursor …


Defect Induced Ferromagnetism In Undoped Zno Nanoparticles, K. Rainey, J. Chess, J. Eixenberger, D. A. Tenne, C. B. Hanna, A. Punnoose May 2014

Defect Induced Ferromagnetism In Undoped Zno Nanoparticles, K. Rainey, J. Chess, J. Eixenberger, D. A. Tenne, C. B. Hanna, A. Punnoose

Physics Faculty Publications and Presentations

Undoped ZnO nanoparticles (NPs) with size ∼12 nm were produced using forced hydrolysis methods using diethylene glycol (DEG) [called ZnO-I] or denatured ethanol [called ZnO-II] as the reaction solvent; both using Zn acetate dehydrate as precursor. Both samples showed weak ferromagnetic behavior at 300 K with saturation magnetization Ms = 0.077 ± 0.002 memu/g and 0.088 ± 0.013 memu/g for ZnO-I and ZnO-II samples, respectively. Fourier transform infrared(FTIR) spectra showed that ZnO-I nanocrystals had DEG fragments linked to their surface. Photoluminescence (PL) data showed a broad emission near 500 nm for ZnO-II which is absent in the ZnO-I samples, …


Dopant Spin States And Magnetism Of Sn1−XFeXO2 Nanoparticles, A. Punnoose, Kelsey Dodge, J. J. Beltrán, K. M. Reddy, Nevil Franco, Jordan Chess, Josh Eixenberger May 2014

Dopant Spin States And Magnetism Of Sn1−XFeXO2 Nanoparticles, A. Punnoose, Kelsey Dodge, J. J. Beltrán, K. M. Reddy, Nevil Franco, Jordan Chess, Josh Eixenberger

Physics Faculty Publications and Presentations

This work reports detailed investigations of a series of ∼2.6 nm sized, Sn1−xFexO2 crystallites with x = 0–0.10 using Mossbauer spectroscopy, x-ray photoelectron spectroscopy (XPS), electron paramagnetic resonance spectroscopy (EPR), and magnetometry to determine the oxidation state of Fe dopants and their role in the observed magnetic properties. The magnetic moment per Fe ion μ was the largest ∼6.48 × 10−3 μB for the sample with the lowest (0.001%) Fe doping, and it showed a rapid downward trend with increasing Fe doping. Majority of the Fe ions are in 3+ oxidation state occupying octahedral …