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Andrews University

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Lanthanide Spectroscopy

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Full-Text Articles in Physical Sciences and Mathematics

Crystal Field And Zeeman Splittings For Energy Levels Of Nd3+ In Hexagonal Aln, John B. Gruber, Gary W. Burdick, Ulrich Vetter, Brandon Mitchell, Volkmar Dierolf, Hans Hofsass Sep 2012

Crystal Field And Zeeman Splittings For Energy Levels Of Nd3+ In Hexagonal Aln, John B. Gruber, Gary W. Burdick, Ulrich Vetter, Brandon Mitchell, Volkmar Dierolf, Hans Hofsass

Faculty Publications

The crystal-field and Zeeman splittings of the energy levels of Nd3+(4f3) 2S+1LJ in hexagonal phase AlN have been investigated. The multiplet manifolds of Nd3+(4f3) analyzed include the ground state, 4I9/2, and excited states 4I11/2, 4I13/2, 4F3/2, 4F5/2, 2H(2)9/2, 4F7/2, 4S3/2, 4G5/2, and 2G7/2. Experimental energy levels were obtained from analyses of the 12 K cathodoluminescence spectra from Nd3+-implanted films of AlN, and from the 15 K photoluminescence excitation spectra and the site-selective combined excitation-emission spectra (CEES) recently reported for in situ Nd-doped hexagonal AlN grown by plasma-assisted molecular beam epitaxy (PA-MBE). CEES results identify a main site and two minority …


Analysis Of The Spectra Of Trivalent Erbium In Multiple Sites Of Hexagonal Aluminum Nitride, John B. Gruber, Ulrich Vetter, Gary W. Burdick, Zachery D. Fleishman, Larry D. Merkle, Takashi Taniguchi, Yuan Xiaoli, Takashi Sekiguchi, Daniel Jurgens, Hans Hofsass Sep 2012

Analysis Of The Spectra Of Trivalent Erbium In Multiple Sites Of Hexagonal Aluminum Nitride, John B. Gruber, Ulrich Vetter, Gary W. Burdick, Zachery D. Fleishman, Larry D. Merkle, Takashi Taniguchi, Yuan Xiaoli, Takashi Sekiguchi, Daniel Jurgens, Hans Hofsass

Faculty Publications

The 12 K cathodoluminescence spectra of Er3+ doped into single crystals of aluminum nitride (2H-AlN) in the hexagonal phase are reported between 320 nm and 775 nm. The emission spectra represent transitions from the lower Stark level of 2P(3/2) to the Stark levels of the 4I(15/2), 4I(13/2), 4I(11/2), 4I(9/2), 4F(9/2), and 4S(3/2) multiplet manifolds of Er3+(4f(11)). Emission spectra from 4S(3/2) to 4I(15/2) are also reported. All observed strong line emission are accounted for in terms of two principle sites, denoted site "a" and site "b", with a few line spectra attributed to additional sites. A parameterized Hamiltonian that includes the …