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Articles 1 - 7 of 7
Full-Text Articles in Physical Sciences and Mathematics
Synthesis, Characterization, And Antiproliferative Activity Of Novel Chiral [Quinoxp*Aucl2]+ Complexes, Adedamola S. Arojojoye, R. Tyler Mertens, Samuel Ofori, Sean R. Parkin, Samuel G. Awuah
Synthesis, Characterization, And Antiproliferative Activity Of Novel Chiral [Quinoxp*Aucl2]+ Complexes, Adedamola S. Arojojoye, R. Tyler Mertens, Samuel Ofori, Sean R. Parkin, Samuel G. Awuah
Chemistry Faculty Publications
Herein is reported the synthesis of two Au(III) complexes bearing the (R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (R,R-QuinoxP*) or (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline (S,S-QuinoxP*) ligands. By reacting two stoichiometric equivalents of HAuCl4.3H2O to one equivalent of the corresponding QuinoxP* ligand, (R,R)-(–)-2,3-Bis(tert-butylmethylphosphino)quinoxalinedichlorogold(III) tetrachloroaurates(III) (1) and (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxalinedichlorogold(III) tetrachloroaurates(III) (2) were formed, respectively, in moderate yields. The structure of (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxalinedichlorogold(III) tetrachloroaurates(III) (2) was further confirmed by X-ray crystallography. The antiproliferative activities of the two compounds were evaluated in a panel of cell lines and exhibited promising results comparable to auranofin and cisplatin with …
The Relationship Between Visible Gold And Arsenopyrite At The Orenada Zone 4 Deposit, Val D'Or, Quebec, Cassandra Powell
The Relationship Between Visible Gold And Arsenopyrite At The Orenada Zone 4 Deposit, Val D'Or, Quebec, Cassandra Powell
Electronic Thesis and Dissertation Repository
The Orenada Zone 4 deposit is an Archean orogenic gold deposit situated southeast of Val d’Or, Québec in the southeastern Abitibi Greenstone Belt. It is located directly within the Cadillac-Larder-Lake Deformation Zone. Mineralization is hosted within a volcanoclastic horizon of the Cadillac Group where two distinct facies were defined. Both facies underwent a pervasive sericite-chlorite-carbonate±albite alteration assemblage that predates gold mineralization. Gold is associated with two generation of auriferous quartz-carbonate-tourmaline veins and within fractures of corroded arsenopyrite grains, located proximal to the vein walls. A LA-ICP-MS study determined that neither textural type of arsenopyrite displayed refractory gold. Therefore, gold was …
Fabrication, Characterization And Applications Of Chemically Modified Planar Metallic Electrodes From Copper Clad Sheets, Rana T. K. Alsaidi
Fabrication, Characterization And Applications Of Chemically Modified Planar Metallic Electrodes From Copper Clad Sheets, Rana T. K. Alsaidi
Theses
In this work, we developed a fabricating method for planar electrodes by milling and cutting copper-clad sheets. The main objectives of this thesis are to produce customized planar electrodes with different geometries with relatively higher reusability compared to the screen-printed electrodes available by commercial vendors. The fabricated electrodes from copper-clad sheets were electroplated with different metals using commercial electroplating baths to produce different metallic planar electrodes. Also, the fabrication of planar electrodes with cavities to be filled with modified carbon paste was done. The electroplated planar electrodes were characterized by the cyclic voltammetry technique. In addition to that, they were …
Gold Nanoparticles: Core Conversion Of Au144(Sch2ch2ph)60 To Au99(Sph-Ch3)42 Using Aromatic Thiolate Ligands And Crystallization Of Au99(Sph-Ch3)42, Elizabeth Turnage
Gold Nanoparticles: Core Conversion Of Au144(Sch2ch2ph)60 To Au99(Sph-Ch3)42 Using Aromatic Thiolate Ligands And Crystallization Of Au99(Sph-Ch3)42, Elizabeth Turnage
Honors Theses
The purpose of this thesis is to synthesize Au144(SCH2CH2Ph)60 using a two-step synthesis reaction, and then using this product to conduct a core conversion from Au144(SCH2CH2Ph)60 to Au99(SPh-CH3)42. The Au99(SPh-CH3)42 product will then be used to attempt to form crystals using five different crystal set-up methods. Au144(SCH2CH2Ph)60 is made with aliphatic thiolate ligands, and when it is placed in a mixture containing excess para-methyl benzenethiol, it undergoes a …
Wavelength Sensitivity Of Indium Tin Oxide On Surface Plasmon Resonance Angles, Antonio Ruiz, Carlos Villa Angulo, Ivan Olaf Hernandez-Fuentes
Wavelength Sensitivity Of Indium Tin Oxide On Surface Plasmon Resonance Angles, Antonio Ruiz, Carlos Villa Angulo, Ivan Olaf Hernandez-Fuentes
Turkish Journal of Electrical Engineering and Computer Sciences
Surface plasmon resonance (SPR) is a charge-density oscillation that occurs when a beam of p-polarized monochromatic light impinges with a greater angle than the critical angle in a dielectric-metal interface. Because of the high losses related to metals, the generated surface plasmon waves propagate with high attenuation in the visible and near-infrared spectral regions in most of the dielectric-metal interfaces. An alternative to reduce such losses is to use a transparent indium tin oxide (ITO) film. In this paper, we compared theoretical calculations and experimental measurements of the SPR angle $\theta_{SPR}$ on the interfaces of a borosilicate prism (Bp) and …
Copper And Gold In Vapors And Liquids As A Function Of Hcl At 700°C And 100 Mpa, Corrie A. Lucchesi
Copper And Gold In Vapors And Liquids As A Function Of Hcl At 700°C And 100 Mpa, Corrie A. Lucchesi
Graduate Research Theses & Dissertations
Porphyry ore deposits are major sources of copper (Cu) and gold (Au) and form when a magmatic volatile phase (MVP) exsolves from a porphyritic intermediate to felsic melt and transports metals to surrounding country rock where they precipitate in an ore zone. There is a consensus that the chloride concentration of the MVP has a direct relationship to the concentration of Cu and Au in the MVP, but the role of dissolved HCl on Cu and Au concentrations has not been addressed. It is hypothesized that increasing HCl concentrations in the MVP will result in higher concentrations of Cu and …
Investigation Of Underpotential Deposition Of Copper At Heated Gold Loop Screen-Printed Electrodes In A Variety Of Water Samples, Eun-Ju Lee
Legacy Theses & Dissertations (2009 - 2024)
To study the underpotential deposition (UPD) of copper, three different types of water samples (TraceSelect® Ultra-pure water, Indian pond water at University at Albany and tap water) are used at a heated gold loop screen-printed electrode (GLE), which is a new type of heated working electrode for voltammetry measurements that is able to directly detect the copper content in the water samples. The anodic stripping analysis of copper is performed with these gold loop electrodes at room temperature of 25 °C and electrode temperature of 80 °C at two different deposition potentials, -0.20 V and +0.10 V. Furthermore, the concentration …