Physical Sciences and Mathematics Commons^™

Photochemical Oxidation Studies Of Porphyrin Ruthenium Complexes, Eric Vanover

Masters Theses & Specialist Projects

In nature, transition metal containing enzymes display many biologically important, attractive and efficient catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in nature, namely, the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of this research and have successfully been utilized, as catalysts, in major oxidation reactions, such as the hydroxylation of alkanes. The present work focuses on photocatalytic studies of aerobic oxidation reactions with well characterized ruthenium porphyrin complexes.

The photocatalytic studies of aerobic oxidation reactions of hydrocarbons The photocatalytic studies of aerobic oxidation reactions of hydrocarbons catalyzed by …

Potential Role Of Inorganic Polyphosphate In The Cycling Of Phosphorus Within The Hypoxic Water Column Of Effingham Inlet, British Columbia, Julia M. Diaz, Ellery D. Ingall, Samuel D. Snow, Claudia R. Benitez-Nelson, Martial Taillefert, Jay A. Brandes

Faculty Publications

[1] The upper basin of Effingham Inlet possesses permanently anoxic bottom waters, with a water column redox transition zone typically occurring at least 40 m above the sediment‐water interface. During our sampling campaign in April and July 2007, this redox transition zone was associated with sharp peaks in a variety of parameters, including soluble reactive phosphorus (SRP) and total particulate phosphorus (TPP). Based on sequential extraction results, TPP maxima exhibited preferential accumulation of an operationally defined class of loosely adsorbed organic phosphorus (P), which may contain a substantial fraction of polyphosphate (poly‐P). This poly‐P may furthermore be involved in the …

Analysis Of The Early-Time Optical Spectra Of Sn 2011fe In M101, J. T. Parrent, D. A. Howell, B. Friesen, R. C. Thomas

Dartmouth Scholarship

The nearby Type Ia supernova SN 2011fe in M101 (cz=241 km s^-1) provides a unique opportunity to study the early evolution of a "normal" Type Ia supernova, its compositional structure, and its elusive progenitor system. We present 18 high signal-to-noise spectra of SN 2011fe during its first month beginning 1.2 days post-explosion and with an average cadence of 1.8 days. This gives a clear picture of how various line-forming species are distributed within the outer layers of the ejecta, including that of unburned material (C+O). We follow the evolution of C II absorption features until they diminish near maximum light, …

Late-Time Optical Emission From Core-Collapse Supernovae, Dan Milisavljevic, Robert A. Fesen, Roger A. Chevalier, Robert P. Kirshner

Dartmouth Scholarship

Ground-based optical spectra and Hubble Space Telescope images of 10 core-collapse supernovae (CCSNe) obtained several years to decades after outburst are analyzed with the aim of understanding the general properties of their late-time emissions. New observations of SN 1957D, 1970G, 1980K, and 1993J are included as part of the study. Blueshifted line emissions in oxygen and/or hydrogen with conspicuous line substructure are a common and long-lasting phenomenon in the late-time spectra. Followed through multiple epochs, changes in the relative strengths and velocity widths of the emission lines are consistent with expectations for emissions produced by interaction between SN ejecta and …

Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies, Brett Vanveller, Derek J. Schipper, Timothy M. Swager

Brett VanVeller

The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold enforces proximity of the alcohol and arene reacting partners and confers significant rigidity to the resulting π-system, expanding the tool set of iptycenes for materials applications.

Spitzer Imaging And Spectral Mapping Of The Oxygen-Rich Supernova Remnant G292.0+1.8, Parviz Ghavamian, Knox S. Long, William P. Blair, Sangwook Park, Robert Fesen

Dartmouth Scholarship

We present mid-infrared continuum and emission line images of the Galactic oxygen-rich supernova remnant (SNR) G292.0+1.8, acquired using the MIPS and IRS instruments on the Spitzer Space Telescope. The MIPS 24 μm and 70 μm images of G292.0+1.8 are dominated by continuum emission from a network of filaments encircling the SNR. The morphology of the SNR, as seen in the mid-infrared, resembles that seen in X-rays with the Chandra X-Ray Observatory. Most of the mid-infrared emission in the MIPS images is produced by circumstellar dust heated in the non-radiative shocks around G292.0+1.8, confirming the results of earlier mid-IR …

Stable Isotope Composition Of Hydrothermally Altered Rocks And Hydrothermal Minerals At The Los Azufres Geothermal Field, Mexico, Ignacio S Torres Alvarado, Muharrem Satir, Daniel Perez Zarate, Peter Birkle

Turkish Journal of Earth Sciences

The Los Azufres geothermal field is the second most important geothermal field for electricity production in Mexico, with a total installed capacity of 188 MW. Hydrothermal alteration studies have been an important tool for geothermal exploration and development of the field, but little attention has been given to the geochemical and isotopic characterization of hydrothermal minerals. \delta^1^8O, \delta^2H, and \delta^1^3C systematics at Los Azufres geothermal field were investigated using whole rock samples, as well as hydrothermal minerals separates, obtained from different depths in the wells Az-26 and Az-52. Most \delta^1^8O values reproduce well the present in-situ field temperatures and isotopic …

Effects Of Activated Carbon Surface Chemistry Modification On The Adsorption Of Mercury From Aqueous Solution, Emily K. Faulconer

Publications

Mercury (Hg), a naturally occurring element, is toxic and can lead to negative health impacts for humans and ecosystems. Activated carbon adsorption is effective in treating Hg-laden aqueous effluent for safe discharge. Two modifications of commercially available activated carbon were investigated: iron impregnation to allow for magnetic sorbent recapture and wet chemical oxidation to enhance aqueous Hg capture. The modified carbons were characterized by nitrogen adsorption-desorption, XRD, pHpzc, vibrating sample magnetometry, elemental analysis, and total acidity titration. The 3:1 C:Fe magnetic powdered activated carbon (MPAC) retained a high surface area of 790 m2 /g and was 95% magnetically recoverable, with …