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Articles 1 - 14 of 14

Full-Text Articles in Physical Sciences and Mathematics

Gravity Wave Characteristics From Oh Airglow Imager Over Maui, Alan Liu, Xian Lu, Zhenhua Li, Gary Swenson, Steven Franke Aug 2013

Gravity Wave Characteristics From Oh Airglow Imager Over Maui, Alan Liu, Xian Lu, Zhenhua Li, Gary Swenson, Steven Franke

Zhenhua Li

No abstract provided.


Differential Geometry Based Solvation Model Ii: Lagrangian Formulation, Zhan Chen, Nathan A. Baker, Guo-Wei Wei Dec 2011

Differential Geometry Based Solvation Model Ii: Lagrangian Formulation, Zhan Chen, Nathan A. Baker, Guo-Wei Wei

Zhan Chen

Solvation is an elementary process in nature and is of paramount importance to more sophisticated chemical, biological and biomolecular processes. The understanding of solvation is an essential prerequisite for the quantitative description and analysis of biomolecular systems. This work presents a Lagrangian formulation of our differential geometry based solvation models. The Lagrangian representation of biomolecular surfaces has a few utilities/advantages. First, it provides an essential basis for biomolecular visualization, surface electrostatic potential map and visual perception of biomolecules. Additionally, it is consistent with the conventional setting of implicit solvent theories and thus, many existing theoretical algorithms and computational software packages …


Gravity Wave Characteristics From Oh Airglow Imager Over Maui, Alan Z. Liu, Xian Lu, Zhenhua Li, Gary R. Swenson, Steven Franke Nov 2011

Gravity Wave Characteristics From Oh Airglow Imager Over Maui, Alan Z. Liu, Xian Lu, Zhenhua Li, Gary R. Swenson, Steven Franke

Alan Z Liu

No abstract provided.


Seasonal Variability Of The Diurnal Tide In The Mesosphere And Lower Thermosphere Over Maui, Hawaii (20.7˚N, 156.3˚W), Xian Lu, Alan Z. Liu, Jens Oberheide, Qian Wu, Tao Li, Zhenhua Li, Gary R. Swenson, Steven J. Franke Sep 2011

Seasonal Variability Of The Diurnal Tide In The Mesosphere And Lower Thermosphere Over Maui, Hawaii (20.7˚N, 156.3˚W), Xian Lu, Alan Z. Liu, Jens Oberheide, Qian Wu, Tao Li, Zhenhua Li, Gary R. Swenson, Steven J. Franke

Zhenhua Li

No abstract provided.


Seasonal Variability Of The Diurnal Tide In The Mesosphere And Lower Thermosphere Over Maui, Hawaii (20.7˚N, 156.3˚W), Xian Lu, Alan Z. Liu, Jens Oberheide, Qian Wu, Tao Li, Zhenhua Li, Gary R. Swenson, Steven J. Franke Sep 2011

Seasonal Variability Of The Diurnal Tide In The Mesosphere And Lower Thermosphere Over Maui, Hawaii (20.7˚N, 156.3˚W), Xian Lu, Alan Z. Liu, Jens Oberheide, Qian Wu, Tao Li, Zhenhua Li, Gary R. Swenson, Steven J. Franke

Alan Z Liu

No abstract provided.


Disassembly Of Preformed Amyloid Ss Fibrils By Small Organofluorine Molecules, Abha Sood, Abid Shaikh, Catharine Sauer, Samson Hailemichael, Michelle Foster, Béla Török, Marianna Török Jan 2011

Disassembly Of Preformed Amyloid Ss Fibrils By Small Organofluorine Molecules, Abha Sood, Abid Shaikh, Catharine Sauer, Samson Hailemichael, Michelle Foster, Béla Török, Marianna Török

Abid Shaikh

A potential therapeutic approach for Alzheimer’s disease is to reduce the amount of toxic amyloid-beta oligomers and fibrillar amyloid plaques. In order to contribute to this approach the ability of small organofluorine compounds that were previously reported as successful inhibitors of fibrillogenesis to destabilize preformed fibrils of the amyloid-beta peptide was studied. These organofluorine molecules including chiral compounds were tested in vitro using standard methods based on Thioflavin-T (THT) fluorescence spectroscopy, atomic force microscopy (AFM) and Fourier-transform infrared spectroscopy (FTIR). It was observed that 5′-halogen substituted 3,3,3-trifluoromethyl-2-hydroxyl-(indol-3-yl)-propionic acid esters showed significant activity in the disassembly of the preformed fibrils. Since …


A Local Energy Estimate On Kerr Black Hole Backgrounds, Daniel Tataru, Mihai H. Tohaneanu Jan 2011

A Local Energy Estimate On Kerr Black Hole Backgrounds, Daniel Tataru, Mihai H. Tohaneanu

Mihai H. Tohaneanu

We study dispersive properties for the wave equation in the Kerr space–time with small angular momentum. The main result of this paper is to establish uniform energy bounds and local energy decay for such backgrounds. This follows similar results for the Schwarzschild space–time proved earlier in [3], [8], and [16] and extended in earlier work [29] of the authors and collaborators.


Diffusive Transport Enhanced By Thermal Velocity Fluctuations, Alejandro Garcia, A. Donev, A. De La Fuente, J. B. Bell Jan 2011

Diffusive Transport Enhanced By Thermal Velocity Fluctuations, Alejandro Garcia, A. Donev, A. De La Fuente, J. B. Bell

Faculty Publications

We study the contribution of advection by thermal velocity fluctuations to the effective diffusion coefficient in a mixture of two identical fluids. We find good agreement between a simple fluctuating hydrodynamics theory and particle and finite-volume simulations. The enhancement of the diffusive transport depends on the system size L and grows as ln⁡(L/L0) in quasi-two-dimensional systems, while in three dimensions it scales as L0-1-L-1, where L0 is a reference length. Our results demonstrate that fluctuations play an important role in the hydrodynamics of small-scale systems.


Speciation, Luminescence, And Alkaline Fluorescence Quenching Of 4-(2-Methylbutyl)Aminodipicolinic Acid (H2mebadpa), Gilles Muller, A. J. Ingram, A. G. Dunpal, R. Dipietro Jan 2011

Speciation, Luminescence, And Alkaline Fluorescence Quenching Of 4-(2-Methylbutyl)Aminodipicolinic Acid (H2mebadpa), Gilles Muller, A. J. Ingram, A. G. Dunpal, R. Dipietro

Gilles Muller

4-(2-Methylbutyl)aminodipicolinic acid (H2MEBADPA) has been synthesized and fully characterized in terms of aqueous phase protonation constants (pKa's) and photophysical measurements. The pKa's were determined by spectrophotometric titrations, utilizing a fully sealed titration system. Photophysical measurements consisted of room temperature fluorescence and frozen solution phosphorescence as well as quantum yield determinations at various pH, which showed that only fully deprotonated MEBADPA2– is appreciably emissive. The fluorescence of MEBADPA2– has been determined to be quenched by hydroxide and methoxide anions, most likely through base-catalyzed excited-state tautomerism or proton transfer. This quenching phenomenon has been quantitatively explored through steady-state and time-resolved fluorescence measurements. …


Diffusive Transport Enhanced By Thermal Velocity Fluctuations, Alejandro Garcia, Aleksandar Donev, Anton De La Fuente, John B. Bell Jan 2011

Diffusive Transport Enhanced By Thermal Velocity Fluctuations, Alejandro Garcia, Aleksandar Donev, Anton De La Fuente, John B. Bell

Alejandro Garcia

We study the contribution of advection by thermal velocity fluctuations to the effective diffusion coefficient in a mixture of two identical fluids. We find good agreement between a simple fluctuating hydrodynamics theory and particle and finite-volume simulations. The enhancement of the diffusive transport depends on the system size L and grows as ln⁡(L/L0) in quasi-two-dimensional systems, while in three dimensions it scales as L0-1-L-1, where L0 is a reference length. Our results demonstrate that fluctuations play an important role in the hydrodynamics of small-scale systems.


Speciation, Luminescence, And Alkaline Fluorescence Quenching Of 4-(2-Methylbutyl)Aminodipicolinic Acid (H2mebadpa), Gilles Muller, A. J. Ingram, A. G. Dunpal, R. Dipietro Jan 2011

Speciation, Luminescence, And Alkaline Fluorescence Quenching Of 4-(2-Methylbutyl)Aminodipicolinic Acid (H2mebadpa), Gilles Muller, A. J. Ingram, A. G. Dunpal, R. Dipietro

Faculty Publications, Chemistry

4-(2-Methylbutyl)aminodipicolinic acid (H2MEBADPA) has been synthesized and fully characterized in terms of aqueous phase protonation constants (pKa's) and photophysical measurements. The pKa's were determined by spectrophotometric titrations, utilizing a fully sealed titration system. Photophysical measurements consisted of room temperature fluorescence and frozen solution phosphorescence as well as quantum yield determinations at various pH, which showed that only fully deprotonated MEBADPA2– is appreciably emissive. The fluorescence of MEBADPA2– has been determined to be quenched by hydroxide and methoxide anions, most likely through base-catalyzed excited-state tautomerism or proton transfer. This quenching phenomenon has been quantitatively explored through steady-state and time-resolved fluorescence measurements. …


A New Acridine-Imidazolium-Based Cholestane Receptor For Anion Sensing, Jyoti Ramesh Jadhav, Md Wasi Ahmad, Hong Seok Kim Dec 2010

A New Acridine-Imidazolium-Based Cholestane Receptor For Anion Sensing, Jyoti Ramesh Jadhav, Md Wasi Ahmad, Hong Seok Kim

Dr. Mohammad Wasi Ahmad (Md Wasi Ahmad)

A new highly selective receptor (3) based on an acridine-imidazolium functionalized cholestane for anion sensing was designed and synthesized. A binding study of 3 with various anions was assessed by UV-vis and fluorescence spectroscopies in dry CH3CN. Receptor 3 showed the highest selectivity toward hydrogen pyrophosphate.


Pyrenyl-Appended Imidazolium Receptor For Selective Fluorescence Sensing Of Oxalic Acid, Md Wasi Ahmad, Sung Hong Kim, Hong Seok Kim Dec 2010

Pyrenyl-Appended Imidazolium Receptor For Selective Fluorescence Sensing Of Oxalic Acid, Md Wasi Ahmad, Sung Hong Kim, Hong Seok Kim

Dr. Mohammad Wasi Ahmad (Md Wasi Ahmad)

A new fluorescent imidazolium-based cholestane receptor 4 bearing a pyrene moiety was synthesized. The binding ability of 4 toward various dicarboxylic acids was examined by UV–vis and fluorescence spectroscopy. Receptor 4 showed the highest binding constant for oxalic acid among all the tested dicarboxylic acids. Oxalic acid formed a complex with 4 with a 1:2 ratio in ethanol.


Ticl(Oipr)3-Mediated One-Pot Reductive Amination Of 1,1'-Diacetylferrocene With Aryl Amines, Md Wasi Ahmad, Sang Yeon Lee, Tae Jeong Kim, Hong Seok Kim Dec 2010

Ticl(Oipr)3-Mediated One-Pot Reductive Amination Of 1,1'-Diacetylferrocene With Aryl Amines, Md Wasi Ahmad, Sang Yeon Lee, Tae Jeong Kim, Hong Seok Kim

Dr. Mohammad Wasi Ahmad (Md Wasi Ahmad)

No abstract provided.