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Full-Text Articles in Physical Sciences and Mathematics
Fragmentation Processes Following Core Excitation In Acetylene And Ethylene By Partial Ion Yield Spectroscopy, Maria Novella Piancastelli, Wayne C. Stolte, Gunnar Ohrwall, S-W Yu, D. Bull, K. Lantz, Alfred S. Schlachter, Dennis W. Lindle
Fragmentation Processes Following Core Excitation In Acetylene And Ethylene By Partial Ion Yield Spectroscopy, Maria Novella Piancastelli, Wayne C. Stolte, Gunnar Ohrwall, S-W Yu, D. Bull, K. Lantz, Alfred S. Schlachter, Dennis W. Lindle
Chemistry and Biochemistry Faculty Research
Partial ion yield spectroscopy provides a very detailed picture of fragmentation processes following core excitation in isolated molecules. We exploit this potential in the analysis of decay processes following C1s→π and C1s→Rydberg excitations in ethylene and acetylene. We show that the relative intensity of spectral features related to the excitation to empty molecular orbitals or to Rydberg states is a function of the time variation of the fragmentation process. Namely, we see an intensity increase in the Rydberg states compared to the molecular orbitals as the fragmentation process becomes more extensive, a result attributable to the diffuse nature of the …
Mathematical Modeling Of Plasmachemical Processes, Meli̇k-Aslanova Tamilla
Mathematical Modeling Of Plasmachemical Processes, Meli̇k-Aslanova Tamilla
Turkish Journal of Physics
In this research, we studied the kinetics of plasmachemical processes in quasiequilibrium and nonequilibrium conditions. The example of methane conversion into acetylene showed that the most efficient plasmachemical process may be achieved under nonequilibrium conditions, especially, when the reaction was stimulated by vibrational excitation of molecules.