Physical Sciences and Mathematics Commons^™

Non-Professional Scuba Training Fatalities In The United States (1970-1976), Peter Redmayne

Theses and Major Papers

From 1970 to 1976 ninety seven fatalities occurred during scuba diving training courses taught by nationally recognized scuba certification agencies. Data from these fatalities was gathered and analyzed at the University of Rhode Island's National Underwater Accident Data Center (NUADC) from September 1977 to June 1978. After analysis of each case and compilation of data for the statistical tables, an effort was made to look for specific trends that occurred over the course of the period investigated. In the course of analysis it became evident that a high percentage of training facilities occurred to students who were diving in less …

Bulk Composition, Mineralogy, And Petrology Of Chondrules In Type H3 To H6 Chondrites, Gayle Elizabeth Lux

Earth and Planetary Sciences ETDs

Chondrules in thin' sections of 18 different H3 to H6 group chondrites were analyzed by 100 µm broad beam electron probe techniques. Chondrule textures, crystal, and chondrule sizes were determined microscopically. Results indicate a decrease in variance or standard deviation from chondrules of petrologic types 3 to 6 of FeO, MgO, TiO₂, MnO, K₂O, and P₂0₅ content. Mean TiO₂ and Cr₂O₃ content decrease from petrologic types 3 to 6 and mean FeO, Al₂O₃, CaO, and Na₂O increase slightly from lower to higher petrologic …

Geology And Mineralogy Of Cave Nitrates, Carol A. Hill

Earth and Planetary Sciences ETDs

ABSTRACT

Southeastern saltpeter caves have temperatures between 10-15° C and humidities between 90-99%. Saltpeter sediments are alkaline (pH= 6-9), dry and porous (moisture = 5-10 wt. %) and non-organic (low levels of compost, guano and animal remains); sediments have nitrate concentrations ranging between 0.01-4.0 wt. %, low total nitrogen (0.08-0.13 wt. %) and relatively low phosphorous (0.1-1.4 wt. %). Lixiviated cave sediments regenerate in nitrate in several years. Areal extent of cave nitrate is uniform; vertical concentration is in the top few meters of sediment. Nitrate is a minor constituent in sulfate speleothems (up to 1 wt. %). Surface and …

Nmr Instrumentation With Solid State Devices, Syed M. Ahmed

Masters Theses

No abstract provided.

A Feasibility Study Concerning The Use Of Alternate Energy Sources In Taiwan, Li-Juan Lee

Masters Theses

No abstract provided.

A Computer Simulation Study Of Seven Pairwise Comparison Procedures: Imbalanced Case, Wayne S. Petroelje

Dissertations

No abstract provided.

Petrology And Structure Of Precambrian Rocks In The Bosque Peak Quadrangle, North Manzano Mountains, Central New Mexico, Duncan L. Edwards

Earth and Planetary Sciences ETDs

Precambrian metamorphic rocks in a part of the North Manzano Mountains, New Mexico, underwent regional synkinematic greenschist facies metamorphism. Abundant green hornblende in greenstones and muscovite, chlorite, and biotite in metapelites tentatively suggest p4 kb and TC during metamorphism. The greenstones were probably derived from basic volcanic rocks; the metapelites were probably derived from shales, siltstones, clay-rich sandstones, cherts (7), and mature quartz sandstones.

The oldest exposed rocks are the Moyos metasediments, a sequence of phyllites and schistose grits that is lithologically transitional to a younger greenstone complex of mostly aphanitic greenstone with intercalated phyllites and metasiltstones and intrusive metadiorite. …

Limnological Observations Of Sugar Creek, Lincoln County, Missouri, Joann Bull

Theses

Not available.

Paleoecology Of The Spiriferid Brachiopods Of The Silica Shale Formation (Middle Devonian), S.E. Michigan And N.W. Ohio, Darioush T. Ghahremani

Masters Theses

Spiriferid brachiopods of the Middle Devonian Silica Formation in northwestern Ohio and southeastern Michigan show many Features that are useful For paleoecologic interpretation. This study is undertaken to examine and interpret the paleoecology and paleobiology of six spiriferid brachiopods Mucrospirifer prolificus, Mucrospirifer grabaui, Mucrospirifer profundus, Mucrospirifer mucronatus, Paraspirifer bownockeri and Spinocyrtia euryteines. All are very abundant and can be easily collected from quarries in the Silica Formation near Sylvania, Ohio.

Fourteen different morphologic characteristics have been tabulated for all specimens used in this study. These characteristics allow interpretations of the ontogenetic de velopment and ecologic relationships of the six studied …

Structural Effects On Micellar Catalyzed Reaction Of Hydroxamic Acids, Nop Utrapiromsuk

Masters Theses

Introduction

For many years scientists have tried to find a model which resembles a biological system, so that they can use this model for studying biological systems in human and in living organisms. Micelle systems provide the environment to mimic enzyme systems to some degree.¹

Soaps and detergents generate micelles. Soaps and detergents have been used as cleansing agents for a long time. Their cleansing properties are related to micelle formation. Actually, soap is simply a mixture of sodium salts of long chain fatty acids, R-COO^- Na⁺, and some detergents are general sodium salts of straight …

The Effects Of Electron-Donating And Electron-Withdrawing Groups On The Alkylation Sites Of Para-Substituted Phenylacetones, Abraham L. Faburada

Masters Theses

The dianions of phenylacetone and its para-substituted derivatives were generated using potassium hydride and n-butyl lithium in tetrahydrofuran. Methyl, ethyl, and n-butyl iodides were used to alkylate the dianions. The results of alkulation indicated that C₁ is preferentially attacked by the less active ethyl and n-butyl iodides. The results further show that terminal alkylation is enhanced by electron-donating groups at the para-position of the phenyl ring. The results are rationalized in terms of the difference in electron density at C₁ and at C₃ in the dianion, on the basis of resonance theory. The regio-selectivity of alkylation as …

The Unexpected Preferential Formation Of 1-Alkyl-1-Phenyl-2–Propanones On Monoalkylation Of The 1-Phenyl-2-Propanone Dianion, Jack M. Hinkley

Masters Theses

No abstract provided.

The Analysis Of N-Methylscopolamine Bromide By High Speed Ion Pair Partition Chromatography, John L. Nappier

Masters Theses

No abstract provided.

On A System Of Nonlinear Ordinary Differential Equations With An Irregular Type Singularity: A Degenerate Case, Jerome John Przybylski

Dissertations

No abstract provided.

The Response Of The Micro-Adsorption Detector To Inorganic Anions, Maria E. Munera

Masters Theses

No abstract provided.

An Assessment Of The Transmission Electron Microscope For The Study Of Aerosol-Gas Interactions: Direct Observations Of Sodium Chloride Hydration Phenomena, Antony David Clarke

Dissertations and Theses

An experimental study of solid-gas interactions was made for sodium chloride particles, using a specially fabricated environmental chamber in a transmission electron microscope. It was found that under suitable conditions the hydration and dehydration of these particles could be directly observed and quantitatively measured. Measurements of growth were obtained with a time resolution of one-thirtieth of a second for particles having diameters ranging from 0.02 μm to 1.0 μm.

Ferrimagnetic Resonance In Nife2o4, Yig, Fe3o4 And Mg-Fe Ferrite, Nabil Naeem Nagib

Archived Theses and Dissertations

No abstract provided.

Spring Phytoplankton Composition And Distribution In Coastal Waters Between Nova Scotia And The Chesapeake Bay, Larry William Neal

OES Theses and Dissertations

This investigation was directed toward satisfying a recognized lack of informat on regarding phytoplankton composition and density in shelf waters between Nova Scotia and the Chesapeake Bay. A sedimentation technique was used in determining the phytoplankton composition of 99 samples collected between 2 March and 3 April 1971. Chlorophyll-a samples collected concurrently were analyzed fluorometrically. Simple correlation analyses were utilized in describing distributional patterns of phytoplankton density and chlorophyll-a concentration with respect to water temperature, salinity, density, depth, distance from shore and latitude. Analysis of variance was employed in assessing regional differences in phytoplankton density and chlorophyll-a.

The phytoplankton flora …

Mercury, Copper, And Zinc In Selected Ichthyofauna Of Lower Chesapeake Bay And Hampton Roads, Virginia, W. Bruce Aitenhead

OES Theses and Dissertations

Anchovys, croaker, spat, summer flounder and hogchokers were collected monthly to seasonally from November 1972 to October 1973 at three locations in the southern Chesapeake Bay region of Virginia.

The concentrations of mercury, copper and zinc were determined by atomic absorption spectrophotometry in whole fishes. Metal concentration varied with species and location. Anchovys had the highest mean concentrations of mercury and zinc while hog- chokers had the highest mean copper concentration. Mercury levels exceeding O.5 ppm were observed in species from all three loca- tions, but maximum heavy metal concentrations per species were highest in Craney Island fishes.

Temporal variations …

The Electric Resistivity Of Bismuth And Bismuth Based Alloys Between 295 And 520ok, Omar Selim Asim Es-Said

Archived Theses and Dissertations

No abstract provided.

The Distribution Of Several Metals And Cation Exchange Capacity In Sediment Fractions From An Artificial And Natural Marsh, James River, Virginia, William Nivens

OES Theses and Dissertations

In order to examine the mechanisms by which Fe, Mn, Ca, Zn, Cu, Ni and Pb are bound in sediments, a sequential selective extraction procedure was employed on sediment samples collected at an experimental dredge disposal marsh and a neighboring natural marsh located near Windmill Point, James River, Va. The metal concentrations were determined in six phases, interstitial water, exchangeable, easily reducible (oxides of Mn), organic, moderately, reducible (oxides of Fe), and residual fractions. In addition, the cation exchange capacity (CEC) of the sediments was determined as well as the actual role of organics and colloidal iron coatings as they …

Influence Of Denervation And Hemithyroidectomy On The Age Related Increase In The Number Of Calcitonin-Containing Cells In Mouse Thyroid, Nualnoi Wechbanjong

Loma Linda University Electronic Theses, Dissertations & Projects

It has been concluded from this study that nerve fibers in the superior laryngeal nerves have an influence on the development of C-cells in the mouse thyroid. This conclusion is based on the results of two types of investigation. The first is an analysis of the effect of age on the number of C-cells and the second is an investigation of the influence of denervation and hemithyroid-parathyroidectomy on the age related changes in C-cells numbers.

I. The distribution and c011centraticn of C-cells in mouse thyroid at various ages.

Serial 6 µm sections of thyroid glands from Swjss Webster mice at …

Kinetics Of Oxidation Of Bismuth And Bismuth Based Alloys In Air Between 500 And 530 (Degree) K, Magda Ishak Ahmed Waly El-Guindy

Archived Theses and Dissertations

No abstract provided.

Dredge Spoil Disposal With Particular Reference To Management Practices In Southern New England, Lynne A. Melville

Theses and Major Papers

One-half million acres of U.S. coastal wetlands have been destroyed by dredging and filling operations since 1956. They are being destroyed at the rate of 0.5-1.0% each year. In one ten year period, Rhode Island lost 5% of its 2000 acres of wetlands to urban development, and Connecticut lost 12% of its marsh lands. Less than 1500 acres of marsh remain in Connecticut. During the course of this research project, I examined one aspect of wetland destruction - the dredging and disposal of spoil materials onto wetlands and into the coastal waters of Southern New England. What follows is a …

Co2 Laser Induced Decomposition Of Freon 113, Richard S. Herrick

Honors Theses

Irradiations were made on CCl2FCClF2, Freon 113, to see if the resulting decomposition was photochemical in nature. The irradiation source was Molectron 250, continuous wave, infrared laser operating in the single line mode. The wavelength of irradiation was varied over the range 9.473 µ to 9.734 µ. The pressure except one (in which the cell window broke). Relative rates of reaction were calculated for a constant power absorbed by the sample of 7.8 ± 4W. These relative rates were plotted against the irradiation wavelength. This was superimposed on a plot of the IR band for Freon 113 which was irradiated …

A Study Of The Acid Etch Pretreatment Used With The Nuva-Seal" Dental Process, Judith Ann Komoroski

Honors Theses

Nuva-Seal, a bisphenol-A-glycidyl-methacrylate polymer, is applied to the occlusal surface of teeth to prevent tooth decay. Before application of the sealant, the enamel surface is etched for one minute by a 50 percent by weight solution of phosphoric acid containing seven percent by weight of zinc oxide. This treatment renders the tooth surface more porous and surface active to insure a strong bond between tooth and sealant. Past studies at Union College have shown that the etching treatment removes much of the enamel from the tooth. In the current work the amount of tooth removed by acid etching was determined …

The Decomposition Of Azibenzil In The Presence Of Oxygen, Nancy C. Westby

Honors Theses

The ozonolysis of acetylenes is thought to proceed through the formation of ∝-carbonyl carbonyl oxide intermediates. This reaction has been shown to parallel the effect of molecular oxygen on ketocarbenes. Azibenzil, a diazo-ketone, will decompose to a ketocarbene by the action of heat, light or catalyst. The ketocarbene may decompose by two pathways: Wolff rearrangement and non-rearrangement. The Wolff rearrangement route will produce methyldiphenylacetate (upon addition of methanol), benzophenone, tetraphenylglycolide and possibly other high molecular weight polymeric species. The non-rearrangement pathway will presumably produce ∝-carbonyl carbonyl oxides which will decompose under varying circumstances to produce benzyl, benzoic anhydride, benzophenone, tetraphenylglycolide …

The Addition Of Singlet Oxygen To N, N-Diethyl-1-Propynylamine, Kenneth S. Zimmerman

Honors Theses

The addition of singlet oxygen to N, N-diethyl-1-pro-pynylamine produced 60-75% yields of N, N-diethyl pyruvamide and various carbon dioxide contamination products under several conditions. Products under several conditions. Product formation was independent of solvent and photosensitizer and was shown to proceed via a singlet oxygen addition mechanism with no free radical involvement. The water addition product was also demonstrated to be N, N-diethyl propanamide. A dioxetene intermediate is suggested as the precursor of N, N-diethyl pyruvamide.

The Preparation And Kinetics Of A Sterically Hindered Gold (Iii) Complex, Michael R. Golden

Honors Theses

The alkyl substituted gold (III) complex [Au(1, 4, 7-Me3dien)Cl] (PF6)2 [where 1, 4, 7-Me3dien respresents (CH3) HNCH2CH2N(CH3)CH2CH2NH(CH3)] has been synthesized. The cation of this compound differs from previously synthesized gold (III) complexes of similar structure since it can form a conjugate base only by loss of hydrogen from a terminal nitrogen. Aqueous solution chemistry studies of this ion reveals that the Cl- is hydrolyzed before loss of a proton from the ligand which is the reverse of the sequence observed with previously studied ions. Monobromo substitution rates are found to be slower than for the complex with no alkyl substitution …

Reactions Of Diazoketones With Neighboring Carbon-To-Carbon Double Bonds, Robert James Perry

Honors Theses

It was hoped that the carbon-carbon double bond in an unsaturated diazoketone would act as a nucleophile in an intramolecular attack to give a ring closure. Experimental results indicate that the double bond did participate, but in such a manner so as to give only substituted products, rather than cyclic ones. We suggest a diazonium salt intermediate in the initial formation of these substituted products. Polymerization and oxonium formation after reactopm with a Lewis acid solvent account for the polymers formed and some of the substituted products.