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Full-Text Articles in Physical Sciences and Mathematics

Drag On Particles In A Nematic Suspension By A Moving Nematic-Isotropic Interface, John L. West, A Glushchenko, Gx Liao, Y Reznikov, D Andrienko, Mp Allen Oct 2013

Drag On Particles In A Nematic Suspension By A Moving Nematic-Isotropic Interface, John L. West, A Glushchenko, Gx Liao, Y Reznikov, D Andrienko, Mp Allen

John L West

We report a clear demonstration of drag on colloidal particles by a moving nematic-isotropic interface. The balance of forces explains our observation of periodic, striplike structures that are produced by the movement of these particles.


Optically Isotropic Liquid-Crystal Phase Of Bent-Core Molecules With Polar Nanostructure, Guangxun Liao, S. Stojadinovic, Gerhard Pelzl, Wolfgang Weissflog, Samuel N. Sprunt, Antal Jakli Oct 2013

Optically Isotropic Liquid-Crystal Phase Of Bent-Core Molecules With Polar Nanostructure, Guangxun Liao, S. Stojadinovic, Gerhard Pelzl, Wolfgang Weissflog, Samuel N. Sprunt, Antal Jakli

Antal Jakli

We found that the optically isotropic (I-M) mesophase observed recently below the nematic phase of the bent-core liquid crystal 4-chlororesorcinol bis[4-(4-n-dodecyloxybenzoyloxy)benzoate] shows ferroelectric-type switching. Polarizing microscopic, electric current, dielectric, and dynamic light scattering studies lead us to propose that the I-M phase is composed of interconnected orthoconic racemic smectic (Sm-CaPF) nanodomains with random layer orientations. Near the nematic phase, where the polarization can be saturated by electric fields, the system responds in a fashion analogous to the granular structure of a magnetic spin glass-in particular, we observed that the relaxation back to the nonpoled structure follows a similar, inverse logarithmic …


Biaxial Nematic Phase In Bent-Core Thermotropic Mesogens, Bharat R. Acharya, Andrew Primak, Satyendra Kumar Oct 2013

Biaxial Nematic Phase In Bent-Core Thermotropic Mesogens, Bharat R. Acharya, Andrew Primak, Satyendra Kumar

Satyendra Kumar

A biaxial nematic phase had been predicted with D2h symmetry, wherein the mesogen’s long and short transverse axes are simultaneously aligned along the two orthogonal, primary and secondary directors, n and m, respectively. The unique low-angle x-ray diffraction patterns in the nematic phases exhibited by three rigid bent-core mesogens clearly reveal their biaxiality. The results of x-ray diffraction can be readily reproduced by ab initio calculations that explicitly include the bent-core shape in the form factor and assume short-range positional correlations.


Finite Molecular Anchoring In The Escaped-Radial Nematic Configuration: A 2-H-Nmr Study, G. P. Crawford, David W. Allender, J. William Doane, M. Vilfan, I. Vilfan Oct 2013

Finite Molecular Anchoring In The Escaped-Radial Nematic Configuration: A 2-H-Nmr Study, G. P. Crawford, David W. Allender, J. William Doane, M. Vilfan, I. Vilfan

David W Allender

The director-field configuration of a nematic liquid crystal confined to cylindrical cavities of polycarbonate Nuclepore membranes ranging from 0.3 to 0.05-mu-m in radius is determined using deuterium nuclear magnetic resonance (H-2 NMR). Spectral patterns from cavities of radius 0.3-mu-m reveal the escaped-radial configuration with singular point defects, but as the cylinder size is decreased, the elastic energy imposed by the curvature of the confining walls competes with the anchoring energy to tilt the directors away from their preferred perpendicular anchoring direction, preventing the expected transition to the planar-radial configuration. A surface fitting parameter is directly determined by simulating H-2-NMR line …


Engaging With The (Un)Familiar: Field Teaching In A Multi-Campus Teaching Environment, Nicholas Gill, Michael Adams, Christine Eriksen Jul 2013

Engaging With The (Un)Familiar: Field Teaching In A Multi-Campus Teaching Environment, Nicholas Gill, Michael Adams, Christine Eriksen

Nicholas J Gill

Field trips have long been central to geography, but have been subject to assessment of the role of the 'field' in teaching. At the same time, academics face barriers to running field trips. Distance education and enhanced educational access for non-metropolitan students represented such an obstacle at an Australian university. These obstacles were taken as an opportunity to draw on the regional nature of the students and staff to enhance teaching goals, run critically informed field trips by and manage academic workloads. We evaluate the field trips by conducting surveys and interviews with students and tutors, and as an example …


Investigation Of The Critical Behavior In Mn0.94nb 0.06coge Alloy By Using The Field Dependence Of Magnetic Entropy Change, J C. Debnath, P Shamba, A M. Strydom, Jianli Wang, S X. Dou Jul 2013

Investigation Of The Critical Behavior In Mn0.94nb 0.06coge Alloy By Using The Field Dependence Of Magnetic Entropy Change, J C. Debnath, P Shamba, A M. Strydom, Jianli Wang, S X. Dou

Jianli Wang

The critical behaviour of Mn0.94Nb0.06CoGe alloy around the paramagnetic-ferromagnetic phase transition was studied based on the field dependence on magnetic entropy change. By using the obtained exponents, the modified Arrott plot is consistent with that by using conventional method. These critical exponents are confirmed by the Widom scaling relation. Based on these critical exponents, the magnetization, field and temperature data around Tc collapse into two curves obeying the single scaling equation MðH; e)¼ebf6(H/ebþc). The calculated critical exponents not only obey the scaling theory but also anastomose the deduced results from the Kouvel-Fisher method [J. S. Kouvel and M. E. Fisher, …


The Effects Of Annealing Temperature On The In-Field Jc And Surface Pinning In Silicone Oil Doped Mgb2 Bulks And Wires, M S. Hossain, A Motaman, O Cicek, H Agil, E Ertekin, A Gencer, Xiaolin Wang, S X. Dou Jun 2013

The Effects Of Annealing Temperature On The In-Field Jc And Surface Pinning In Silicone Oil Doped Mgb2 Bulks And Wires, M S. Hossain, A Motaman, O Cicek, H Agil, E Ertekin, A Gencer, Xiaolin Wang, S X. Dou

Shi Xue Dou

No abstract provided.


In-Field Jc Improvement By Oxygen-Free Pyrene Gas Diffusion Into Highly Dense Mgb2 Superconductor, Minoru Maeda, Jung Ho Kim, Y Zhao, Yoon-Uk Heo, K Takase, Y Kubota, C Moriyoshi, F Yoshida, Y Kuroiwa, S X. Dou Jun 2013

In-Field Jc Improvement By Oxygen-Free Pyrene Gas Diffusion Into Highly Dense Mgb2 Superconductor, Minoru Maeda, Jung Ho Kim, Y Zhao, Yoon-Uk Heo, K Takase, Y Kubota, C Moriyoshi, F Yoshida, Y Kuroiwa, S X. Dou

Shi Xue Dou

Oxygen-free pyrene gas as a carbon (C) dopant was delinked and incorporated into highly dense MgB2 structure via a gas phase diffusion method. The technique offers the advantages that molecular C is homogeneously distributed into MgB2 and substituted at the boron sites without any severe deterioration of grain connectivity. The C substitution causes a significant shrinkage of the a-lattice parameter and an increase in the lattice strain, resulting in high disorder. The introduction of structural disorder as a result of C doping leads to a considerable enhancement of the in-field critical current density (Jc) and upper critical field.


Comparison Of Small-Field Behaviour In Mgb2, Low And High Temperature Superconductors, Alexey V. Pan, S X. Dou Jun 2013

Comparison Of Small-Field Behaviour In Mgb2, Low And High Temperature Superconductors, Alexey V. Pan, S X. Dou

Shi Xue Dou

Different types of superconductors have been investigated at small magnetic fields (Ba) over wide temperature (T) ranges at different Ba orientations. It has been shown that the temperature dependence of the characteristic field (B*), separating the Ba-independent critical current density (Jc) plateau (single vortex pinning regime) and the region with Jc(Ba) (collective pinning), can be attributed either to the temperature dependence of the magnetic penetration depth for Nb-film and MgB2bulk superconductors, or to thermally activated processes for Bi-based superconductors and YBa2Cu3O7−δ superconducting films. In both cases the vortex pinning influence appears to have a secondary role, affecting the effective vortex …


Investigation Of The Critical Behavior In Mn0.94nb 0.06coge Alloy By Using The Field Dependence Of Magnetic Entropy Change, J C. Debnath, P Shamba, A M. Strydom, Jianli Wang, S X. Dou Jun 2013

Investigation Of The Critical Behavior In Mn0.94nb 0.06coge Alloy By Using The Field Dependence Of Magnetic Entropy Change, J C. Debnath, P Shamba, A M. Strydom, Jianli Wang, S X. Dou

Shi Xue Dou

The critical behaviour of Mn0.94Nb0.06CoGe alloy around the paramagnetic-ferromagnetic phase transition was studied based on the field dependence on magnetic entropy change. By using the obtained exponents, the modified Arrott plot is consistent with that by using conventional method. These critical exponents are confirmed by the Widom scaling relation. Based on these critical exponents, the magnetization, field and temperature data around Tc collapse into two curves obeying the single scaling equation MðH; e)¼ebf6(H/ebþc). The calculated critical exponents not only obey the scaling theory but also anastomose the deduced results from the Kouvel-Fisher method [J. S. Kouvel and M. E. Fisher, …


A Sign Of Field-Induced First Order Magnetic State Transition And Giant Reversible Magnetocaloric Effect In Cobalt Hydroxide Nanosheets, Precious Shamba, Rong Zeng, J Q Wang, S X. Dou Jun 2013

A Sign Of Field-Induced First Order Magnetic State Transition And Giant Reversible Magnetocaloric Effect In Cobalt Hydroxide Nanosheets, Precious Shamba, Rong Zeng, J Q Wang, S X. Dou

Shi Xue Dou

We report the synthesis of β−Co(OH)2 nanosheets using microwave assisted hydrothermal and conventional chemical reaction methods. A magnetic transition at an onset temperature, T1 ~ 96 K, and a sign of antiferromagnetic state transition at the Néel temperature, TN=9~10 K, can be determined from M-T curves and M-H curves magnetic properties investigation. It is found that a sign of field-induced first order transition below 9 K, act as a role of reversing the magnetocaloric effect from negative to positive value. The large reversible magnetic-entropy change (∆SM) of 17 J/kg K around 11 K for a field change of 5 T …


Giant Magnetic Entropy Change In Colossal Magnetoresistance In La0.7ca0.3mno3 Material In Low Field, Jyotish Debnath, Rong Zeng, Jung Ho Kim, S X. Dou Jun 2013

Giant Magnetic Entropy Change In Colossal Magnetoresistance In La0.7ca0.3mno3 Material In Low Field, Jyotish Debnath, Rong Zeng, Jung Ho Kim, S X. Dou

Shi Xue Dou

The structural, magnetic, and magnetocaloric properties of the manganite La0.7Ca0.3MnO3 have been studied. Change in the giant magnetic entropy was observed without any noticeable magnetic hysteresis but with small thermal hysteresis losses. We observed a first order magnetic phase transition around 251 K. The magnetic entropy change observed in this work is estimated to be 5.27 J/kg K for field changes from 0 to 1.5 T based on magnetization measurements. This value is about twice as large as those for other perovskite manganites and is even larger than for Gd-based magnetic materials at low fields. In addition, the entropy change …


Silicon Oil: A Cheap Liquid Additive For Enhancing In-Field Critical Current Density In Mgb2, Xiaolin Wang, Zhenxiang Cheng, S X. Dou Jun 2013

Silicon Oil: A Cheap Liquid Additive For Enhancing In-Field Critical Current Density In Mgb2, Xiaolin Wang, Zhenxiang Cheng, S X. Dou

Shi Xue Dou

In this work, the authors report on significant flux pinning enhancement in MgB2 that has been easily obtained using a liquid additive, silicon oil. MgB2 bulk samples with 0 up to 30 wt % silicon oil added were prepared by an in situ reaction. Results showed that the Si and C released from the decomposition of the silicon oil formed Mg2Si and substituted into B sites, respectively. Increasing the amount of the Si oil up to 15 wt % has resulted in the reduction of the lattice parameters, as well as Tc and R(300 K)/R(Tc) values, accompanied by a significant …


Enhancement Of The In-Field Jc Of Mgb2 Via Sicl4 Doping, Xiaolin Wang, S X. Dou, Md S. Hossain, Zhenxiang Cheng, X.Z Liao, Shaban R. Ghorbani, Qiwen Yao, Jung Ho Kim, Tania M. Silver Jun 2013

Enhancement Of The In-Field Jc Of Mgb2 Via Sicl4 Doping, Xiaolin Wang, S X. Dou, Md S. Hossain, Zhenxiang Cheng, X.Z Liao, Shaban R. Ghorbani, Qiwen Yao, Jung Ho Kim, Tania M. Silver

Shi Xue Dou

We present the following results. (1) We introduce a doping source for MgB2, liquid SiCl4, which is free of C, to significantly enhance the irreversibility field (Hirr), the upper critical field (Hc2), and the critical current density (Jc) with a little reduction in the critical temperature (Tc). (2) Although Si can not be incorporated into the crystal lattice, a significant reduction in the a-axis lattice parameter was found, to the same extent as for carbon doping. (3) Based on the first-principles calculation, it is found that it is reliable to estimate the C concentration just from the reduction in the …


Detecting Humans Under Occlusion Using Variational Mean Field Method, Duc Thanh Nguyen, Philip Ogunbona, Wanqing Li Dec 2012

Detecting Humans Under Occlusion Using Variational Mean Field Method, Duc Thanh Nguyen, Philip Ogunbona, Wanqing Li

Associate Professor Wanqing Li

This paper proposes a human detection method using variational mean field approximation for occlusion reasoning. In the method, parts of human objects are detected individually using template matching. Initial detection hypotheses with spatial layout information are represented in a graphical model and refined through a Bayesian estimation. In this paper, mean field method is employed for such an estimation. The proposed method was evaluated on the popular CAVIAR-INRIA dataset. Experimental results show that the proposed algorithm is able to detect humans in severe occlusion within reasonable processing time.


Result Of Ac Loss Tests On Twisted And Untwisted Htsc Tape Exposed To An External Field, Tri Hardono, Christopher David Cook, Frank Darmann Aug 2012

Result Of Ac Loss Tests On Twisted And Untwisted Htsc Tape Exposed To An External Field, Tri Hardono, Christopher David Cook, Frank Darmann

Christopher Cook

This paper presents the results of magnetic loss tests on twisted and untwisted 37 multifilament tapes exposed to an alternating field at power frequencies. The losses are measured using calorimetric methods, which are capable of measuring losses in short tapes with the accuracy of several microwatts per centimeter of tape. The losses of the tape due to the longitudinal field of the untwisted tape agree well with theoretical calculations. The measurement results on the twisted filament tape, with 50-mm twist pitch, show that the losses are slightly lower than that in the untwisted tape. This is due to the reduction …


Hybrid Rod-Like And Bent-Core Liquid Crystal Dimers Exhibiting Biaxial Smectic A And Nematic Phases, Yan Wang, Hyung Yoon, Hari Bisoyi, Satyendra Kumar, Quan Li Jan 2012

Hybrid Rod-Like And Bent-Core Liquid Crystal Dimers Exhibiting Biaxial Smectic A And Nematic Phases, Yan Wang, Hyung Yoon, Hari Bisoyi, Satyendra Kumar, Quan Li

Satyendra Kumar

Liquid crystal hybrid dimers involving bent-core units and rod-like units were designed, synthesized and investigated by a combination of polarizing optical microscopy (POM), differential scanning calorimetry (DSC) and X-ray diffraction studies. All the four unsymmetrical dimers 1–4 exhibited stable nematic phases over a wide temperature range. Moreover, dimer 1exhibited the biaxial smectic A (SmA) phase and dimer 2 exhibited a highly ordered mesophase below the nematic (N) phase. Two rod-like and bent-core nematogenic units were covalently linked in dimers 3 and 4 to furnish exclusively the nematic phase. The observation of the biaxial SmA phase underlying the nematic phase in …


Bent-Core Liquid Crystal Elastomers, Rafael Verduzco, Paul Luchette, Seung Ho Hong, John Harden, Elaine Dimasi, Peter Palffy-Muhoray, S. Michael Kilbey Ii, Jim T. Gleeson, Antal Jákli Dec 2009

Bent-Core Liquid Crystal Elastomers, Rafael Verduzco, Paul Luchette, Seung Ho Hong, John Harden, Elaine Dimasi, Peter Palffy-Muhoray, S. Michael Kilbey Ii, Jim T. Gleeson, Antal Jákli

Peter Palffy-Muhoray

Liquid crystal (LC) elastomers with bent-core side-groups incorporate the properties of bent-core liquid crystals in a flexible and self-supporting polymer network. Bent-core liquid crystal elastomers (BCEs) with uniform alignment were prepared by attaching a reactive bent-core LC to poly(hydrogenmethylsiloxane) and crosslinking with a divinyl crosslinker. Phase behavior studies indicate a nematic phase over a wide temperature range that approaches room temperature, and thermoelastic measurements show that these BCEs can reversibly change their length by more than a factor of two upon heating and cooling. Small-angle X-ray scattering studies reveal multiple, broad low-angle peaks consistent with short-range smectic C order of …


F3 Layerduring Penetration Electric Field, N. Balan, H. Alleyne, S. V. Thampi, K. Lynn, Y. Otsuka, Bela G. Fejer, M. A. Abdu Mar 2008

F3 Layerduring Penetration Electric Field, N. Balan, H. Alleyne, S. V. Thampi, K. Lynn, Y. Otsuka, Bela G. Fejer, M. A. Abdu

Bela G. Fejer

[1] The occurrence of an additional layer, called F3 layer, in the equatorial ionosphere at American, Indian, and Australian longitudes during the super double geomagnetic storm of 7–11 November 2004 is presented using observations and modeling. The observations show the occurrence, reoccurrence, and quick ascent to the topside ionosphere of unusually strong F3 layer in Australian longitude during the first super storm (8 November) and in Indian longitude during the second super storm (10 November), all with large reductions in peak electron density (Nmax) and total electron content (GPS-TEC). The unusual F3 layers can arise mainly from unusually strong fluctuations …


Equatorial Ionospheric Electric Fields During The November 2004 Magnetic Storm, Bela G. Fejer, J. W. Jensen, T. Kikuchi, M. A. Abdu, J. L. Chau Oct 2007

Equatorial Ionospheric Electric Fields During The November 2004 Magnetic Storm, Bela G. Fejer, J. W. Jensen, T. Kikuchi, M. A. Abdu, J. L. Chau

Bela G. Fejer

[1] We use radar measurements from the Jicamarca Radio Observatory, magnetometer observations from the Pacific sector and ionosonde data from Brazil to study equatorial ionospheric electric fields during the November 2004 geomagnetic storm. Our data show very large eastward and westward daytime electrojet current perturbations with lifetimes of about an hour (indicative of undershielding and overshielding prompt penetration electric fields) in the Pacific equatorial region during the November 7 main phase of the storm, when the southward IMF, the solar wind and reconnection electric fields, and the polar cap potential drops had very large and nearly steady values. This result …


Electrically Tunable Lens Based On A Dual-Frequency Nematic Liquid Crystal, Oleg Pishnyak, Susumu Sato, Oleg Lavrentovich Jul 2006

Electrically Tunable Lens Based On A Dual-Frequency Nematic Liquid Crystal, Oleg Pishnyak, Susumu Sato, Oleg Lavrentovich

Oleg Lavrentovich

We report on an electrically controlled liquid-crystal-based variable optical lens filled with a dual-frequency nematic material. The lens design employs a hole-patterned electrode structure in a flat nematic cell. In order to decrease the lens switching time we maximize the dielectric torque by using a dual-frequency nematic material that is aligned at an angle approximately 45 degrees with respect to the bounding plates by obliquely deposited SiOx, and by using an overdrive scheme of electrical switching. Depending on the frequency of the applied field, the director realigns either toward the homeotropic state (perpendicular to the substrates) or toward the planar …


Finite-Difference Time-Domain Simulation Of A Liquid-Crystal Optical Phased Array, Xinghua Wang, Bin Wang, Philip Bos, James E. Anderson, John J. Pouch, Felix A. Miranda Jan 2005

Finite-Difference Time-Domain Simulation Of A Liquid-Crystal Optical Phased Array, Xinghua Wang, Bin Wang, Philip Bos, James E. Anderson, John J. Pouch, Felix A. Miranda

Philip J. Bos

Accurate modeling of a high-resolution, liquid-crystal-based, optical phased array (OPA) is demonstrated. The modeling method is extendable to cases where the array element size is close to the wavelength of light. This is accomplished through calculating an equilibrium liquid-crystal (LC) director field that takes into account the fringing electric fields in LC OPAs with small array elements and by calculating the light transmission with a finite-difference time-domain method that has been extended for use in birefringent materials. The diffraction efficiency for a test device is calculated and compared with the simulation.


Magnetospheric Electric Fields And Plasma Sheet Injections To Low-Lshells During The June 4-5, 1991 Magnetic Storm: Comparison Between The Rice Convectionmodel And Observations, T. W. Garner, R. A. Wolf, R. W. Spiro, W. J. Burke, Bela G. Fejer, S. Sazykin, J. L. Roeder, M. R. Hairston Jan 2004

Magnetospheric Electric Fields And Plasma Sheet Injections To Low-Lshells During The June 4-5, 1991 Magnetic Storm: Comparison Between The Rice Convectionmodel And Observations, T. W. Garner, R. A. Wolf, R. W. Spiro, W. J. Burke, Bela G. Fejer, S. Sazykin, J. L. Roeder, M. R. Hairston

Bela G. Fejer

[1] The major magnetic storm of 4–5 June 1991 was well observed with the Combined Release and Radiation Experiment (CRRES) satellite in the duskside inner magnetosphere and with three Defense Meteorological Satellite Program (DMSP) spacecraft in the polar ionosphere. These observations are compared to results from the Rice Convection Model (RCM), which calculates the inner magnetospheric electric field and particle distribution self-consistently. This case study, which uses the most complete RCM runs to date, demonstrates two significant features of magnetospheric storms, the development of subauroral polarization streams (SAPS) and plasma-sheet particle injection deep into the inner magnetosphere. In particular, the …


Global Dayside Ionospheric Uplift And Enhancements Due To Interplanetary Shock Electric Fields, B. R. Tsurutani, A. Mannucci, B. Ijima, A. Saito, K. Yumoto, M. A. Abdu, J. H.A. Sobral, W. D. Gonzalez, F. L. Guarnieri, T. Tsuda, Bela G. Fejer, T. J. Fuller-Rowell, J. U.O. Kozyra, J. C. Foster, A. Coster, V. M. Vasyliumas Jan 2004

Global Dayside Ionospheric Uplift And Enhancements Due To Interplanetary Shock Electric Fields, B. R. Tsurutani, A. Mannucci, B. Ijima, A. Saito, K. Yumoto, M. A. Abdu, J. H.A. Sobral, W. D. Gonzalez, F. L. Guarnieri, T. Tsuda, Bela G. Fejer, T. J. Fuller-Rowell, J. U.O. Kozyra, J. C. Foster, A. Coster, V. M. Vasyliumas

Bela G. Fejer

[1] The interplanetary shock/electric field event of 5–6 November 2001 is analyzed using ACE interplanetary data. The consequential ionospheric effects are studied using GPS receiver data from the CHAMP and SAC-C satellites and altimeter data from the TOPEX/Poseidon satellite. Data from ∼100 ground-based GPS receivers as well as Brazilian Digisonde and Pacific sector magnetometer data are also used. The dawn-to-dusk interplanetary electric field was initially ∼33 mV/m just after the forward shock (IMF BZ = −48 nT) and later reached a peak value of ∼54 mV/m 1 hour and 40 min later (BZ = −78 nT). The electric field was …


Low Latitude Ionospheric Disturbance Electric Field Effects Duringthe Recovery Phase Of The October 19-21, 1998 Magnetic Storm, Bela G. Fejer, J. T. Emmert Dec 2003

Low Latitude Ionospheric Disturbance Electric Field Effects Duringthe Recovery Phase Of The October 19-21, 1998 Magnetic Storm, Bela G. Fejer, J. T. Emmert

Bela G. Fejer

[1] Low-latitude ionospheric electric fields and currents are often strongly disturbed during periods of enhanced geomagnetic activity. These perturbations can last for several hours after geomagnetic quieting. We use incoherent scatter radar measurements from Jicamarca and Arecibo during 19–21 October 1998 to study, for the first time, the low-latitude disturbance electric fields during the recovery phase of a large magnetic storm. On 19 October the Jicamarca data showed initially large and short-lived (time scale of about 10–20 min) upward and westward drift perturbations in the early afternoon sector, due to the penetration of strong magnetospheric electric fields probably driven by …


Novel Examples Of Achiral Bent-Core Azo Compounds Exhibiting B1 And Anticlinic-Antiferroelectric B2 Mesophases, Veena Prasad, Shin-Woong Kang, Satyendra Kumar Dec 2002

Novel Examples Of Achiral Bent-Core Azo Compounds Exhibiting B1 And Anticlinic-Antiferroelectric B2 Mesophases, Veena Prasad, Shin-Woong Kang, Satyendra Kumar

Satyendra Kumar

The first examples of achiral bent-core molecules consisting of an azo linkage and five aromatic rings exhibiting bent-core mesophases are reported. They exhibit B1 and B2 phases as identified by optical microscopy, differential scanning calorimetry, X-ray diffraction, and electro-optical techniques. The B2 phase of these materials is identified to be the anticlinic–antiferroelectric, SmCAPA phase. The mesophases of these compounds have relatively low transition temperatures and wide temperature ranges. The observation of bent-core phases in azo compounds assumes significance from the fact that the introduction of the –NN– linkage adds a new dimension, namely photochromism, to this field.


Optical Vortices Generated By Dislocations In A Cholesteric Liquid Crystal, D. Voloschenko, Oleg Lavrentovich Mar 2000

Optical Vortices Generated By Dislocations In A Cholesteric Liquid Crystal, D. Voloschenko, Oleg Lavrentovich

Oleg Lavrentovich

We report the observation of optical vortices in a laser beam propagating through the stripe pattern of a cholesteric liquid crystal. The liquid crystal is confined in a cell with homogeneous boundary conditions and forms a diffraction phase grating. Optical vortices are produced by edge dislocations of the cholesteric grating. The vortices show up as spots of zero light intensity in the diffraction maxima. There is one spot in each +1 and -1 diffraction maximum and two spots in diffraction maxima +2 and -2. (C) 2000 Optical Society of America. OCIS codes: 160.3710, 050.1940, 180.1790, 070.4690.


Time Dependent Response Of Equatorial Ionospheric Electric Fieldsto Magnetospheric Disturbances, Bela G. Fejer, L. Scherliess Apr 1995

Time Dependent Response Of Equatorial Ionospheric Electric Fieldsto Magnetospheric Disturbances, Bela G. Fejer, L. Scherliess

Bela G. Fejer

We use extensive radar measurements of F region vertical plasma drifts and auroral electrojet indices to determine the storm time dependence of equatorial zonal electric fields. These disturbance drifts result from the prompt penetration of high latitude electric fields and from the dynamo action of storm time winds which produce largest perturbations a few hours after the onset of magnetic activity. The signatures of the equatorial disturbance electric fields change significantly depending on the relative contributions of these two components. The prompt electric field responses, with lifetimes of about one hour, are in excellent agreement with results from global convection …


Calculation Of Barriers To Proton Transfer Using Variations Of Multi-Configuration Self‐Consistent Field Methods. I. Combinations Of Orbitals, K. Luth, Steve Scheiner Jan 1992

Calculation Of Barriers To Proton Transfer Using Variations Of Multi-Configuration Self‐Consistent Field Methods. I. Combinations Of Orbitals, K. Luth, Steve Scheiner

Steve Scheiner

The usefulness of multiconfiguration self‐consistent‐field (MCSCF) calculations in computing correlated proton transfer potentials is investigated for the systems HF2, H7N2+, H3O2, and H5O2+. In deciding whether to include particular molecular orbitals, it is important to consider the balance of electron density between the donor and acceptor groups and the interactions that are incorporated in the orbitals. Only orbitals which have the proper symmetry to interact with the transferring hydrogen need be included in the MCSCF active space. Reasonable transfer barriers are obtained …


Lowand Mid-Latitude Ionospheric Electric Fields During The January 1984 Gismos Campaign, Bela G. Fejer, M. C. Kelley, C. Senior, O. De La Beaujardiere, J. A. Holt, C. A. Tepley, R. Burnside, M. A. Abdu, J. H.A. Sobral, R. F. Woodman, Y. Kamide, R. Lepping Mar 1990

Lowand Mid-Latitude Ionospheric Electric Fields During The January 1984 Gismos Campaign, Bela G. Fejer, M. C. Kelley, C. Senior, O. De La Beaujardiere, J. A. Holt, C. A. Tepley, R. Burnside, M. A. Abdu, J. H.A. Sobral, R. F. Woodman, Y. Kamide, R. Lepping

Bela G. Fejer

This paper examines in detail the electrical coupling between the high-, middle-, and low-latitude ionospheres during January 17–19, 1984, using interplanetary and high-latitude magnetic field data together with F region plasma drift measurements from the EISCAT, Sondre Stromfjord, Millstone Hill, Saint-Santin, Arecibo, and Jicamarca incoherent scatter radars. We study the penetration of both the zonal and meridional electric field components of high-latitude origin into the low-latitude and the equatorial ionospheres. In the dusk sector, a large perturbation of the zonal equatorial electric field was observed in the absence of similar changes at low and middle latitudes in the same longitudinal …