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Full-Text Articles in Physical Sciences and Mathematics
Reduced Dimensionality Effects In Gd-Based Magnetocaloric Materials, Hillary Faith Belliveau
Reduced Dimensionality Effects In Gd-Based Magnetocaloric Materials, Hillary Faith Belliveau
USF Tampa Graduate Theses and Dissertations
Magnetic refrigeration based on the magnetocaloric effect (MCE) is a promising alternative to conventional gas compression based cooling techniques. Understanding impacts of reduced dimensionality on the magnetocaloric response of a material such as Gadolinium (Gd) or its alloys is essential in optimizing the performance of cooling devices, which is also the overall goal of this thesis. We have determined, in the first part of the thesis, that laminate structures of pure Gd produced by magnetron sputtering have several disadvantages. The target material (pure Gd), ultra-high vacuum components, and the electrical energy it takes to run the manufacturing process are all …
The Role Of Partial Surface Charge Compensation In The Properties Of Ferroelectric And Antiferroelectric Thin Films, Elena Glazkova
The Role Of Partial Surface Charge Compensation In The Properties Of Ferroelectric And Antiferroelectric Thin Films, Elena Glazkova
USF Tampa Graduate Theses and Dissertations
Ferroelectric and antiferroelectric ultrathin films have attracted a lot of attention recently due to their remarkable properties and their potential to allow for device miniaturization in numerous applications. However, when the ferroelectric films are scaled down, it brings about an unavoidable depolarizing field. A partial surface charge compensation allows to control the residual depolarizing field and manipulate the properties of ultrathin ferroelectric films. In this dissertation we take advantage of atomistic first-principles-based simulations to expand our understanding of the role of the partial surface charge compensation in the properties of ferroelectric and antiferroelectric ultrathin films.
The application of our computational …