Physical Sciences and Mathematics Commons^™

Heterogeneous Anisotropy Index And Scaling In Multiphase Random Polycrystals, Muhammad Ridwan Murshed

Theses and Dissertations

Under consideration is the finite-size scaling of elastic properties in single and two-phase random polycrystals with individual grains belonging to any crystal class (from cubic to triclinic). These polycrystals are generated by Voronoi tessellations with varying grain sizes and volume fractions. By employing variational principles in elasticity, we introduce the notion of a 'Heterogeneous Anisotropy Index' and investigate its role in the scaling of elastic properties at finite mesoscales. The index turns out to be a function of 43 variables, 21 independent components for each phase and the volume fraction of either phase. Furthermore, the relationship between Heterogeneous Anisotropy Index …

Soil-Grapevine Interactions: Insight From Verdicchio In The Marche Wine Region, Italy, Megan Luna Barlow

Theses and Dissertations

Verdicchio is a white grape varietal notably grown in the Marche wine region of east-central Italy within two Denominazione Origine Controllata (DOCs); Castelli di Jesi and Matelica, located less than 50 km apart. Jesi lies in the Apennine foothills near the coast of the Adriatic Sea and produces a smooth wine noted with apple-pear undertones and crisp, clean acidity. Conversely, Matelica is located in a synclinal valley of a fold-and-thrust belt and produces stronger wine with penetrating floral aromas and bold acidity. While macro-climatic variations do exist between DOCs, this research focuses on geological variations, specifically variations in soil composition, …

Intraneti Dhe Pagesat Elektronike Ne Komunen E Istogut, Faton Bytyçi

Theses and Dissertations

Shfrytëzimi i përparësive të teknologjisë informative është bërë pjesë e pandashme e jetës tonë për të punuar, informuar, argëtuar etj. Një sferë e veçantë e përdorimit të teknologjisë informative është edhe e-Qeverisja e cila po gjënë vend çdo ditë në administratë për të ofruar shërbime të shpejta, të lehta e të sakta për ata që punojnë dhe për ata që i marrin shërbimet nga administrata.

Komuna e Istogut në dhjetë vitet e fundit ka avancuar në masë të madhe përdorimin e teknologjisë informative dhe i ka bërë modernizimin e shërbimeve. Një prej shërbimeve elektronike në këtë komunë është edhe Sistemi …

Building An Albanian Knowledge Graph From Unstructured Text, Hakan Shehu

Theses and Dissertations

We live in the golden area of information. The World Wide web contains a vast amount of unstructured text in different digital formats, including newswire, blogs, email communications, governmental documents, chat logs, and so on. Some of the biggest companies and organizations have created knowledge bases which represent a semantic network of facts, entities and relations between them. Even though this area has been well researched for a considerable time, there is a lack of implementation of such a knowledge extraction for Albanian language. In this thesis we will try to create an Albanian general knowledge graph from unstructured text. …

Vlerësimi I Karakteristikave Të Rrjetit Në Testimin E Aplikacioneve Përmes Rrjetit Të Virtualizuar, Redon Berisha

Theses and Dissertations

Aplikacionet rrjetëzuese janë bërë pjesë e rëndësishme e përdorimit personal dhe biznesor duke mundësar shkëmbim dhe menaxhim të informacioneve nga të gjitha vendet ku ndodhemi, ndërsa rëndësia e testimit të aplikacioneve është pikë kyçe në ofrimin e eksperiencës së shfrytëzuesit dhe performancës së saj. Qëllimi i këtij studimi është përdorimi i Rrjetit të Virtualizuar në krijimin e mjedisit testues, për emulimin e trafikut në të cilin aplikacionet pranojnë të dhënat. Punimi ka dy qëllime, që të shërbejë si udhërrefyes për virtualizimin e rrjetit dhe për te testuar performancat e rrjetit në kushte të ndryshme. Në këtë drejtim janë formuluar tre …

Integration Of Scale-Themed Instruction Across The General Chemistry Curriculum And Selected In-Depth Studies, Jaclyn Trate

Theses and Dissertations

In 1982, in response to a growing demand for a scientifically literate population, two organizations, the AAAS and NCISE published reports that proposed using themes to bridge scientific disciplines1,2. The NCISE report identified “9 explanatory concepts” which included organization, cause and effect, systems, scale, models, change, structure or function, discontinuous and continuous properties, and diversity. The AAAS report, as part of Project 2061, identified 4 themes that define science literacy which included systems, models, constancy and change, and scale. In 1993, the AAAS released the Benchmarks for Science Literacy3 which outlined what all students should know or be able to …

The Growth, Structure, And Dynamics Of Crime In Cities, Marcos Oliveira

Theses and Dissertations

Crime is ubiquitous in cities but lacks a statistical characterization that could lead to uncovering its underlying mechanisms. Cities are, however, in a constant process of organization making difficult to analyze urban phenomena. Yet, to understand urbanization and its consequences, we need to approach cities as evolving processes, instead of static objects. With this perspective, we examined regularities in crime regarding its growth, structure, and dynamics. We developed frameworks to examine the spatial, temporal, and periodic variations of crime in cities. Though thefts increase super-linearly with the population, we found burglaries showing a linear increase. Our analyses also confirmed crime …

Information Densification Of Social Constructs Via Behavior Analysis Of Social Media Users – A Study On Twitter, Diogo F. Pacheco

Theses and Dissertations

We live in a digital era where everyday activities are increasingly being replaced by online interactions. In addition, technology advances and data availability are changing the way we expand our knowledge about ourselves, society, and the environment. The increasing availability of data, especially social media data, has called the attention of researchers, and we have been witnessing an outbreak in studies relying on this rich source of information. However, most social media research is tuned to improve the outcomes of specific problems. Therefore, the reuse of techniques used in different areas is limited to data specialists. We propose a straightforward …

Investigation Of Tribochemical Reactions Using The Model System Of Methyl Thiolate On Copper Foil In Ultrahigh Vacuum And Ab-Initio Calculations, Heather Loren Adams

Theses and Dissertations

Advancement in the understanding of tribochemical systems suffers from several obstacles that hinder the progress in advancing an understanding of the fundamental processes involved in the evolution of friction and wear. Characterizing ephemeral chemical states within a buried interface is an experimental challenge and work in this dissertation uses a model system, methyl thiolate on copper foil, that undergoes tribo-activated decomposition to investigate the rate of change of the chemical components in the interface. The elementary steps in the tribochemical reaction were identified and consist of a shear-induced decomposition of methyl thiolate species to produce gas-phase hydrocarbons and form surface …

Star Formation Density And Galactic Outflows At Z~2, Matthew Coon

Theses and Dissertations

Galactic-scale outflows of gas play a significant role in galaxy evolution. They push gas to larger radii, slowing the star formation rate near the center of the galaxy, and increasing it at larger radii. Eventually, these outflows can expel the gas from the galaxy, depositing metals into the intergalactic medium, and limiting star formation in the galaxy. Galaxies from the Keck Baryonic Structure Survey (KBSS) and 3D- Hubble Space Telescope (3D-HST) Survey were used in order to measure the velocities of galactic outflows from the KBSS spectra, and the grism spectra from the 3D- HST survey were used in order …

Design And Implementation Of A Multi-Port Solid State Transformer For Flexible Der Integration, Mohammad Rashidi

Theses and Dissertations

Conventional power system includes four major sections, bulk generation, transmission network, distribution network, and loads. The main converter in the conventional electric grid is the low-frequency passive transformer providing galvanic isolation and voltage regulation for various voltage zones. In this configuration, small-scale renewable energy resources are generally connected to the power system at low voltage zones or inside microgrids.

Recent developments in the design of power electronic elements with higher voltage and power ratings and medium/high frequency enable making use of solid state transformer at different voltage levels in the distribution system and microgrid design. In this work, the concept …

Enhanced Version Control For Unconventional Applications, Ahmed Saleh Shatnawi

Theses and Dissertations

The Extensible Markup Language (XML) is widely used to store, retrieve, and share digital documents. Recently, a form of Version Control System has been applied to the language, resulting in Version-Aware XML allowing for enhanced portability and scalability. While Version Control Systems are able to keep track of changes made to documents, we think that there is untapped potential in the technology. In this dissertation, we present novel ways of using Version Control System to enhance the security and performance of existing applications. We present a framework to maintain integrity in offline XML documents and provide non-repudiation security features that …

A Public Humanity: The Application Of Isotopic Analysis To The Intersection Between Body And Law At The Milwaukee County Poor Farm Cemetery, Shannon Kate Freire

Theses and Dissertations

The Milwaukee County Poor Farm Cemetery is an umbrella term used to describe the four cemeteries that were used by Milwaukee County from 1878 through 1974 for the burial of the indigent, unclaimed, institutionalized, and anatomized. Three of these cemeteries remain undisturbed. The primary focus of this research is the twice-excavated Cemetery II (Wisconsin Burial Site 47BMI0076), in use between 1882 and 1925. Archaeological excavations in 1991-1992 and again in 2013 resulted in the recovery of over 2,400 individuals from this cemetery location.

In Wisconsin, legislative efforts to govern indigent burial and dissection mediated competing aspirations between medical education and …

God's Number In The Simultaneously-Possible Turn Metric, Andrew James Gould

Theses and Dissertations

In 2010 it was found that God’s number is 20 in the face turn metric. That is, if the Rubik’s cube hasn’t been disassembled, it can always be solved in 20 twists or fewer, but sometimes requires 20 twists. However, the face turn metric only allows one face to be turned at a time for a total of 18 generators, or 18 possible twists at any time. This dissertation allows opposing, parallel faces to be twisted independent amounts at the same time and still get counted as 1 twist for a total of 45 generators. A new optimal-solving program was …

Threshold Free Detection Of Elliptical Landmarks Using Machine Learning, Lifan Zhang

Theses and Dissertations

Elliptical shape detection is widely used in practical applications. Nearly all classical ellipse detection algorithms require some form of threshold, which can be a major cause of detection failure, especially in the challenging case of Moire Phase Tracking (MPT) target images. To meet the challenge, a threshold free detection algorithm for elliptical landmarks is proposed in this thesis. The proposed Aligned Gradient and Unaligned Gradient (AGUG) algorithm is a Support Vector Machine (SVM)-based classification algorithm, original features are extracted from the gradient information corresponding to the sampled pixels. with proper selection of features, the proposed algorithm has a high accuracy …

Understanding And Developing Estimates Based On Practical Foundation Methods For Alaska's Discontinuous Permafrost Region, Paul P. Dennison

Theses and Dissertations

This research uses a quantitative analysis to develop a family of curves and a calculator for potential foundation thresholds in the discontinuous permafrost region of Alaska. The United States Pacific Command (PACAF) is bolstering the region by advocating for the F-35, KC-46, and the newly proposed long-range bomber to be stationed in Alaska. These next generation aircrafts and warfighters will need new facilities and beddown plans to efficiently and effectively carry out their mission. The biggest obstacle in the region is permafrost; this unique polar phenomenon is found throughout the northern half of Alaska. Fairbanks in particular has multiple military …

Short Synthesis And Biological Evaluation Of 5-Chloro-7-Benzoyl 2,3-Dihydrobenzo[B]Furan -3-Carboxylic Acid(Brl-37959) And Its Analogs., Shamsul Arefin Ahmed

Theses and Dissertations

The synthesis of BRL-37959 has previously been reported. As an NSAID, the compound was tested for and found that it had very low gastric irritancy. Commercially available NSAIDs are non-selective COX inhibitors that enhance the risk of gastric, duodenal mucosal injury or erosions and ulcer problems as well as lead to nephrotoxicity. The COX-2 selective inhibitor Celecoxib (Celebrex) increases the risk of serious cardiovascular (CV) thrombotic events, myocardial infarction and stroke as well as increased nephrotoxicity. COX inhibitors are active against inflammation, pain, fever and different types of cancers. Considering the enormous potential benefits and side effects of non-selective COX …

Development Of Pre-Clinical Assays Based On Tandem Mass Spectrometry To Investigate Gabaa Receptor Modulators, Margaret Laurel Guthrie

Theses and Dissertations

ABSTRACT

DEVELOPMENT OF PRE-CLINICAL ASSAYS BASED ON TANDEM MASS SPECTROMETRY TO INVESTIGATE GABAA RECEPTOR MODULATORS

by

Margaret L. Guthrie

The University of Wisconsin – Milwaukee, 2017

Under the Supervision of Professor Alexander (Leggy) Arnold

Drugs are compounds that interact with a biological system to produce a specific biological response. The goal of drug discovery is to design and synthesize a pharmaceutical agent that will produce a desired biological effect. However, the in-vivo effects of a drug molecule cannot be predicted without a variety of test results prior to human clinical trials. In order to designate any drug compound as a …

Improving Version-Aware Word Documents, Alexandre Gustavo Valenca De Azevedo Filho

Theses and Dissertations

Coakley~\textit{et al.} described how they developed Version Aware Word Documents, which is an enhanced document representation that includes a detailed version history that is self-contained and portable. However, they were not able to adopt the unique-ID-based techniques that have been shown to support efficient merging and differencing algorithms.

This thesis describes how it is possible to adapt existing features of MS Word's OOXML representation to provide a system of unique element IDs suitable for those algorithms. This requires taking over Word's Revision Save ID (RSID) system and also defining procedures for specifying ID values for elements that do not support …

Real-Time, Selective Detection Of Heavy Metal Ions In Water Using 2d Nanomaterials-Based Field-Effect Transistors, Guihua Zhou

Theses and Dissertations

Excessive intake of heavy metals damages the central nervous system and causes brain and blood disorders in mammals. Heavy metal contamination is commonly associated with exposure to mercury, lead, arsenic, and cadmium (arsenic is a metalloid, but classified as a heavy metal). Traditional methods to detect heavy metal ions include graphite furnace atomic absorption spectroscopy (GFAAS), inductively-coupled plasma optical emission spectroscopy (ICP-OES), and inductively-coupled plasma mass spectroscopy (ICP-MS). Recently, many new methods have been proposed to detect heavy metal ions, including atomic absorption spectrometry, fluorescent sensors, colorimetric sensors, electrochemical sensors, X-ray absorption fine structure spectroscopy, ultrasensitive dynamic light scatting assays, …

Utilizing Consumer Health Posts For Pharmacovigilance: Identifying Underlying Factors Associated With Patients’ Attitudes Towards Antidepressants, Maryam Zolnoori

Theses and Dissertations

Non-adherence to antidepressants is a major obstacle to antidepressants therapeutic benefits, resulting in increased risk of relapse, emergency visits, and significant burden on individuals and the healthcare system. Several studies showed that non-adherence is weakly associated with personal and clinical variables, but strongly associated with patients’ beliefs and attitudes towards medications. The traditional methods for identifying the key dimensions of patients’ attitudes towards antidepressants are associated with some methodological limitations, such as concern about confidentiality of personal information. In this study, attempts have been made to address the limitations by utilizing patients’ self report experiences in online healthcare forums to …

Dissolved Organic Carbon And Dissolved Metal Pulses During Snowmelt Runoff In The Upper Provo River Watershed, Utah, Usa, Hannah Nicole Checketts

Theses and Dissertations

Snowmelt river systems exhibit seasonal fluxes in water chemistry, potentially affecting the water supply of one-sixth of the worlds population. In this study, we examined water chemistry of the upper Provo River, northern Utah, which supplies water to over two million people along the urban Wasatch Front. Seasonal changes in water chemistry were characterized by analyzing discharge and dissolved organic carbon (DOC) with dissolved trace metal and cation concentrations (La, Pb, Cu, Al, Be, Sr and K) over three consecutive water years 20142016, with intensive sampling during snowmelt runoff. To better understand links between metal movement and DOC, we sampled …

Evaporated Aluminum Fluoride As A Barrier Layer To Retard Oxidation Of Aluminum Mirrors, Margaret Miles

Theses and Dissertations

The aluminum oxide growth rate for aluminum protected with 2.4 nm of aluminum fluoride has been determined. We show that a 2.4 nm aluminum fluoride layer does not prevent aluminum from oxidation but does significantly retard the oxide growth – decreasing the oxide layer thickness from 1 nm in less than an hour to 0.9 nm over 116 hours. Additionally, the optical constants for aluminum oxide growing under an aluminum fluoride barrier layer have been determined – showing an increase in absorption at high energies for Al₂O₃ forming at room temperature as compared to highly ordered Al …

The Morphology And Uniformity Of Circumstellar Oh/H2O Masers Around Oh/Ir Stars, Derek Sean Felli

Theses and Dissertations

Even though low mass stars (< 8 solar masses) vastly outnumber high mass stars (< 8 solar masses), the more massive stars drive the chemical evolution of galaxies from which the next generation of stars and planets can form. Understanding mass loss of asymptotic giant branch stars contributes to our understanding of the chemical evolution of the galaxy, stellar populations, and star formation history. Stars with mass < 8 solar masses form planetary nebulae, while those with mass < 8 solar masses go supernova. In both cases, these stars enrich their environments with elements heavier than simple hydrogen and helium molecules. While some general info about how stars die and form planetary nebulae are known, specific details are missing due to a lack of high-resolution observations and analysis of the intermediate stages. For example, we know that mass loss in stars creates morphologically diverse planetary nebulae, but we do not know the uniformity of these processes, and therefore lack detailed models to better predict how spherically symmetric stars form asymmetric nebulae. We have selected a specific group of late-stage stars and observed them at different scales to reveal the uniformity of mass loss through different layers close to the star. This includes observing nearby masers that trace the molecular shell structure around these stars. This study revealed detailed structure that was analyzed for uniformity to place constraints on how the mass loss processes behave in models. These results will feed into our ability to create more detailed models to better predict the chemical evolution of the next generation of stars and planets.

Acoustic Intensity Of Narrowband Signals In Free-Field Environments, Kelli Fredrickson Succo

Theses and Dissertations

The phase and amplitude gradient estimator (PAGE) method has proven successful in improving the accuracy of measured energy quantities over the p-p method, which has traditionally been used, in several applications. One advantage of the PAGE method is the use of phase unwrapping, which allows for increased measurement bandwidth above the spatial Nyquist frequency. However, phase unwrapping works best for broadband sources in free-field environments with high coherence. Narrowband sources often do not have coherent phase information over a sufficient bandwidth for a phase unwrapping algorithm to unwrap properly. In fact, phase unwrapping processing can cause significant error when there …

A Mixed-Reality Approach For Cyber-Situation Awareness, Tapas Dipakkumar Joshi

Theses and Dissertations

As the proliferation and adoption of smart devices increase, there is an unprecedented amount of data being released into the network every second. Computer networks are the carriers for the movement of this ever generating amounts of data, but are dumb in a way that they do not distinguish between suspicious data traffic and valid data traffic. Also, for however secure a computer network be, suspicious network traffic activities are bound to happen. These suspicious traffic activities have to be detected, analyzed and stopped before it compromises the entire network and leaves the information and data security of an organization …

A Context-Free Method Of Visualizing Streaming Object Data For The Purpose Of Identifying Known Events: An Implementation And Analysis, Quinn Gregory Carver

Theses and Dissertations

This year, every second, five gigabytes of new data will be streamed to storage and yet less than half a percent of all this data will ever be analyzed. Much of this muted data is high-variety object data, unnoticed in a void of sorely needed tools to make it readily understandable. A software tool for visualizing streaming object data in a context-free manner can be built, and this tool would aid in finding predictor data for known events which are functions of the data. The design of the tool to support the hypothesis is presented and field results from over …

Computational Exploration Of Vortex Nucleation In Type Ii Superconductors Using A Finite Element Method In Ginzburg-Landau Theory, Alden Roy Pack

Theses and Dissertations

Using a finite element method, we numerically solve the time-dependent Ginzburg-Landau equations of superconductivity to explore vortex nucleation in type II superconductors. We consider a cylindrical geometry and simulate the transition from a superconducting state to a mixed state. Using saddle-node bifurcation theory we evaluate the superheating field for a cylinder. We explore how surface roughness and thermal fluctuations influence vortex nucleation. This allows us to simulate material inhomogeneities that may lead to instabilities in superconducting resonant frequency cavities used in particle accelerators.

Dissolved Organic Carbon And Dissolved Metal Pulses During Snowmelt Runoff In The Upper Provo River Watershed, Utah, Usa, Hannah Nicole Checketts

Theses and Dissertations

Snowmelt river systems exhibit seasonal fluxes in water chemistry, potentially affecting the water supply of one-sixth of the worlds population. In this study, we examined water chemistry of the upper Provo River, northern Utah, which supplies water to over two million people along the urban Wasatch Front. Seasonal changes in water chemistry were characterized by analyzing discharge and dissolved organic carbon (DOC) with dissolved trace metal and cation concentrations (La, Pb, Cu, Al, Be, Sr and K) over three consecutive water years 2014”2016, with intensive sampling during snowmelt runoff. To better understand links between metal movement and DOC, we sampled …

Capacity Of Human Immunodeficiency Virus Targeting Chimeric Antigen Receptor T Cells To Eliminate Follicular Dendritic Cells Bearing Human Immunodeficiency Virus Immune Complexes, Matthew T. Ollerton

Theses and Dissertations

An important obstacle to a functional cure for HIV/AIDS is the persistence of viral reservoirs found throughout the body in various cells and tissues. Reservoirs can be latently infected cells, or in the case of follicular dendritic cells (FDC), non-infected cells that trap infectious virus on their surface through immune complexes (HIV-IC). Although several strategies have been employed to target and eliminate viral reservoirs, they are short-lived and ineffective. In an attempt to provide a long-term approach, chimeric antigen receptor T (CAR-T) cells were designed to eliminate native HIV on FDCs. Although effective at eliminating HIV-infected cells, and halting spreading …