Physical Sciences and Mathematics Commons^™

Leaf Litter Processing In Aquatic Systems Two Variable Model, Boyd Jay Hanson

Theses and Dissertations

The adequacy of the negative exponential model with one independent variable, days or accumulated time, as a descriptive equation for aquatic leaf litter processing was examined. The effect of adding a second independent variable, degree days or accumulated temperature, to the model was also examined. The two variable negative exponential model was shown to have at least two advantages over the single variable model. The two variable model adequately fits litter processing data for more cases than the single variable model. The expanded model also allows determination of rate coefficients for various temperature levels of the experiment rather than assuming …

High Pressure Liquid Chromatographic Methods For The Separations Of Derivatized Alpha-Keto Acids And Thiamine Phosphate Esters, Bruce Clark Hemming

Theses and Dissertations

Improved methods have been developed for separation of a-keto acid derivatives and for thiamine and its phosphate esters. Linear gradient reverse phase chromatography using ion-pair formation provides baseline resolution for a seven-component homologous series of a-keto acid dinitrophenylhydrazones having increasing carbon chain lengths. Branched-chain keto acids can also be separated. Aldehyde derivatives were examined as possible interfering compounds. Peak identification in biological material was confirmed for pyruvate by an enzymic peak shift technique. Monitoring near 365 nm permits low nanogram detection. Preliminary studies of keto acids in biological material illustrate the method's applicability. The same system with slight changes separates …

The Synthesis Of Novel Macrocyclic Multidentate Compounds From Dioxodioic Acids (1), R. Elliott Asay

Theses and Dissertations

A series of novel macrocyclic multidentate crown compounds have been prepared from a series of dioxodioic acids. The dioxodioic acids were prepared by treating various oligoethylene glycols or amines with maleic, succinic, citraconic, and glutaric anhydrides. The crown compounds were then synthesized from the dioxodioic acid chlorides obtained from the diacids and various oligoethylene glycols or ethylene diamine.

A Photochemical Study Of S-Triazolo[4,3-B] Pyridazine And 3-Diazo-4-Oxo-3,4-Dihydroquinoline, John Timothy Carlock

Theses and Dissertations

When subjected to ultraviolet radiation in the presence of an alkene, s-triazolo[4,3-b]pyridazine (STP) undergoes an unusual 3 + 2 photocycloaddition wherein the alkene adds to the 1 and 8 positions of STP with concommitant N4-N5 bond cleavage yielding 5,6-disubstituted-6,7-dihydro-7-methylene (and 7-cyanomethyl)-5H-pyrrolo[1,2-b]-s-triazoles. Amides and esters of indole-3-carboxylic acid have been synthesized by a novel reaction employing the ultraviolet irradiation of 3-diazo-4-oxo-3,4-dihydroquinoline (QDA) in the presence of amines or alcohols respectively. QDA, when irradiated, is postulated to undergo an internal Wolff Rearrangement to Indole-3-ketene which can add any amine or alcohol to form the corresponding amide or ester in modest to good …

Real-Time Computer Optimized Scanning Potential Coulometry For Multi-Component Trace Analysis, Norman W. Petty

Theses and Dissertations

The instrumentation and methodology for real-time computer controlled scanning potential coulometry for multi-component trace analysis is described. The sensitivity limit was determined to be 10^-8 F for electrochemically reversible constituents. The sensitivity limit could be extended if measures were taken to compensate for the periodic signal found on the electrolysis current. Non-linear least squares curve fitting methods accurately resolved iron-platinum and silver-iron interferences to give accurate determinations for iron and silver. The resolving capability of this method was tested using theoretically generated scanning potential coulograms. The computer resolved sample constituents with a 1 to 100 concentration ratio and a formal …

The Dependence Of The Apparent Pk Of Ion Exchange Celluloses Of Ionic Strength, Paul Cyril Gillespie

Theses and Dissertations

Diethylaminoethyl cellulose was titrated with acid and base in various concentrations of NaCl. The pK values were determined from titration curves using a graphical technique. Two titratable groups were observed from the acid titration curve, a major and a minor group. The minor group, which represented 20% of the acid titration, was barely detectable in the base titration curve and had a salt-independent pK of 6.0. The pK of the major group was strongly salt-dependent and was approximately a linear function of log N NaCl. An equilibrium shift caused by the counter ion may explain the salt dependence. Hydrogen bonding …

Isolation, Purification, Scanning Electron Microscopy And Bacterial Dna Uptake Of Plant Protoplasts, Bronwyn G. Hughes

Theses and Dissertations

Protoplasts were isolated from tobacco and barley leaves in sucrose or mannitol using commercially available cellulases and macerozymes. Barley growth and protoplast isolation and purification conditions were optimized so that protoplasts were obtained in high yields free of unwanted debris and organelles. A technique for processing barley and tobacco protoplasts for examination by scanning electron microscopy was developed in which protoplasts seem to have maintained their structural integrity. Barley and tobacco protoplasts took up 3H-B. subtilis DNA, 125I-B. subtilis DNA or 125I-M. luteus DNA as a linear function of time (0-6 hr) and DNA concentration (0-200 μg/ml). Up to 16 …

Certain Edaphic And Biotic Factors Affecting Vegetation In The Shadscale Community Of The Kaiparowits Area, Vane Orlan Campbell

Theses and Dissertations

A study area on the southern extensions of the Great Basin cold desert (Kaiparowits Basin, Utah) was selected which has had varying amounts of disturbance. Areas with similar slope and exposure in the Shadscale community were sampled. At each site, soil samples were collected and percent sand, percent clay, percent silt, soluble salts, and hydrogen ion concentrations were measured. Cluster analysis based on percent frequency of the perennial species showed that eight groups or sub-communities were definable within the area sampled. Patterns within the vegetation were shown to be independent with the use of cluster analysis. Discriminant analysis on soil …

Paleozoology Of Cores From The Tyler Formation (Pennsylvanian) In North Dakota, U.S.A., James C. Grenda

Theses and Dissertations

A well-preserved fauna from the Tyler Formation was studied in cores from 34 wells drilled for oil in Billings, Golden Valley, McKenzie, Slope, and Stark Counties. Forty-four species of invertebrates, eleven form-species of conodonts, at least three types of fish, and at least four genera of plants· are present. Invertebrate species include 1 bryozoan, 15 brachiopods, 14 bivalves, 2 gastropods, 2 cephalopods, 2 annelids, 2 branchiopoda, at least 2 ostracodes, 2 malacostracans, 1 insect, and 1 echinoderm. Chordates include 1 "nonmarine" shark, at least 1 paleoniscoid fish, and 1 possible crossopterygian fish. A new genus and species of eocarid malacostracan …

Stratigraphy And Paleontology Of The Upper Cretaceous Morden Member (Vermilion River Formation) In The Outcrop Area, Northeastern North Dakota, Fredrick D. Wosick

Theses and Dissertations

The Late Cretaceous Morden Member is the oldest exposed bedrock unit in North Dakota, cropping out in eastern Cavalier County in the northeastern part of the state. The Morden overlies the Greenhorn Formation and underlies the Niobrara Formation. The Canadian Morden Member of the Vermilion River Formation is used in lieu of the Carlile Formation because of the lithologic similarity and proximity to the Morden type area, and the distance from the Carlile Formation type section in southeastern Colorado.

Three principal sections were measured and sampled at 2-meter intervals for microfaunal and lithologic analysis. A single well was used for …

Petrology Of The Alaskites Of The Boulder Batholith, Montana, Kenneth C. Malick

Theses and Dissertations

The Boulder batbolith outcrops in the Northern Rookies of western Montana. It is exposed over an area of 5700 km2 and extends about 112 km along the continental divide from Mullen Pass on the north to 32 km south of Butte. The Boulder batholith represents an invasion of the upper zones of the crust by a large volume of fluid granodioritia quartz monzonitic magma emplaced at the close of a main orogenic episode during late Cretaceous and Paleocene time.

Eight alaskite bodies were chosen for sampling from previous field experience and from geologic maps published by the U.S.O.S. Textural descriptions, …

Glacial Stratigraphy Of Southeastern North Dakota, Michael Camara

Theses and Dissertations

Seven lithostratigraphic units are recognized in the glacial sediment {till) of southeastern North Dakota. Five of these units are not formally named; eventually most of these units will be correlated with formations in surrounding regions. Two of these units, Gardar and Dahlen, are formations recognized in northeastern North Dakota {Hobbs, 1975). The seven lithostratigraphic units are differentiated and correlated using the percentage of the sand, silt, and clay fractions of the till and using the proportion of igneous and metamorphic rock fragments, limestone and dolomite fragments, and shale fragments in the very-coarse-sand fraction (1 to 2 mm) of the till. …

Western North Dakota Lignite Strip Mining Processes And Resulting Subsurface Characteristics, Laramie M. Winczewski

Theses and Dissertations

Data on subsurface conditions obtained prior to strip mining is useful in planning effective mining and reclamation procedures as well as predicting the subsurface characteristics after reclamation. The redistribution of the overburden sediments is less predictable, however.

Through field observations, the major mining factors controlling subsurface structure and overburden sediment redistribution were determined. These include the geometry of the coal body, pit sequence, pit curvature, overburden thickness and managerial input. At a given location, however, the detailed structures and distribution of sediment types within a waste bank were observed to depend upon the dragline cutting pattern, distance between dragline positions, …

The Late Cenozoic Geology Of West-Central Minnesota From Moorhead To Park Rapids, Roderic L. Perkins

Theses and Dissertations

Based on lithostratigraphic and geomorphic information, the Quaternary history of an area bounded by the Red River of the North, 95°00' west longitude, 47°00' and 46°45' north latitude in west central Minnesota, includes seven geologic episodes:

Glacial advances and retreats over all or part of the study area occurred during the first six geologic episodes. The glaciers advanced either southward across northern Minnesota, entering the study area from the northeast; or across eastern North Dakota and southwestern Manitoba, entering the study area from the northwest. As a result of these glacial events the sediment of Unit A, Sebeka Formation, New …