Physical Sciences and Mathematics Commons^™

Influencing Factors On The Velocity And Temperature Of Propagating Fronts In Acrylate Composites, Samuel Morris Bynum

LSU Doctoral Dissertations

Thermal frontal polymerization is a type of polymerization in which a localized reaction zone propagates through an unstirred system. It is incumbent upon the production and transport of heat produced as a result of the exothermic reaction associated with free-radical polymerization. First discovered in the 1970s, frontal polymerization has been since utilized to produce a variety of different materials, utilizing a variety of different chemistries. The temperature of the propagating front and the velocity at which it propagates can be influenced via chemical or physical means. We show that through careful selection of monomers and control of the concentration of …

Modeling And Simulations Of Peptoids, Pu Du

LSU Doctoral Dissertations

Polypeptoids, or poly-N-substituted glycines, are a class of sequence defined polymers that are structural mimics of polypeptides. Polypeptoids currently have received a growing interest due to their improved thermal stability, larger chemical diversity, and easier synthetic pathways as compared to peptides. Their lack of backbone hydrogen bonding and stereochemistry coupled with their easily tunability make them an ideal prototypical model system to study the effect of secondary/non-covalent interactions on self-assembly in solution. In order to develop a molecular level understanding of the effect of secondary interactions on polypeptoid self-assembly, systematic studies were carried out using molecular dynamics simulations on several …

Dynamical Modeling In Cell Biology With Ordinary Differential Equations, Renee Marie Dale

LSU Doctoral Dissertations

Dynamical systems have been of interest to biologists and mathematicians alike. Many processes in biology lend themselves to dynamical study. Movement, change, and response to stimuli are dynamical characteristics that define what is 'alive'. A scientific relationship between these two fields is therefore natural. In this thesis, I describe how my PhD research variously related to biological, mathematical, and computational problems in cell biology. In chapter 1 I introduce some of the current problems in the field. In chapter 2, my mathematical model of firefly luciferase in vivo shows the importance of dynamical models to understand systems. Data originally collected …

Measurements Of The 16c + 12c And 16c + 13c Fusion Cross Sections With Implications For Astrophysics, Ashley Ann Hood

LSU Doctoral Dissertations

The fusion of neutron-rich nuclei is of interest to nuclear astrophysics and nuclear structure. X-ray superbursts are powered by runaway thermonuclear burning deep inside of a neutron star, where heating from the pycnonuclear fusion of neutron-rich isotopes is an important heat source. Experimental measurements of fusion cross sections of neutron-rich isotopes have provided insights regarding nucleon transfer and nuclear structure properties affecting fusion. Recently, the ¹⁵C + ¹²C total fusion cross section was measured using a ¹⁵C beam produced by the in-flight beam production facility, which is part of the Argonne Tandem LINAC Accelerator System (ATLAS) at …

Hierarchical Conjugated Polymer Systems Prepared By Controlled Chain-Growth Polymerization, Chunwa Peter Kei

LSU Doctoral Dissertations

π-Conjugated polymer materials may have a significant economic impact on society by providing means for designing affordable, flexible, and portable organic electronic devices. Their successful commercialization will depend on major scientific advancements, which will challenge human society to seek out ever more detailed and fundamental processes to command. Controlled polymerization affords such a power; allowing for the design of meticulous and precisely defined systems granting detailed insight into structure-property relationships in the polymer materials and bettering understanding of novel physical phenomena.

This dissertation primarily focuses on development and preparation of well-defined hierarchically organized macromolecular systems. The novel chain-growth polymerization methodologies …

Managing Overheads In Asynchronous Many-Task Runtime Systems, Bibek Wagle

LSU Doctoral Dissertations

Asynchronous Many-Task (AMT) runtime systems are based on the idea of dividing an algorithm into small units of work, known as tasks. The runtime system is then responsible for scheduling and executing these tasks in an efficient manner by taking into account the resources provided to it and the associated data dependencies between the tasks. One of the primary challenges faced by AMTs is managing such fine-grained parallelism and the overheads associated with creating, scheduling and executing tasks. This work develops methodologies for assessing and managing overheads associated with fine-grained task execution in HPX, our exemplar Asynchronous Many-Task runtime system. …

The Use Of Social Media In Emergency Management By Public Agencies And Non-Governmental Organizations: Lessons Learned From Areas Affected By Hurricanes Isaac, Sandy, And Harvey, Ryan Hamilton Kirby

LSU Doctoral Dissertations

Natural disasters are increasingly costly for the United States. The literature suggests emergency managers may improve disaster outcomes and enhance disaster resilience by supplementing their official public-communications methods with more bi-directional communication tactics using social media. This study aims to understand how social media is used within the “whole community” of emergency management in areas affected by recent hurricanes. The first research objective examines how social media is used by governmental and non-governmental organizations across the four phases of emergency management (preparedness, response, recovery, mitigation). The second objective is to identify challenges governmental and non-governmental groups have encountered and strategies …

The Effects Of Temperature On The Yields Of Aliphatic And Aromatic Products From The Supercritical Pyrolysis Of 1-Octene, Elizabeth Anne Hurst

LSU Doctoral Dissertations

Prior to their combustion, fuels for future high-speed aircraft are expected to experience supercritical conditions, leading to the production of polycyclic aromatic hydrocarbons (PAH), precursors to solid carbonaceous deposits, via pyrolytic reactions. These solid deposits can clog fuel-transfer lines, causing unsafe aircraft operation. To prevent the formation of fuel-line deposits, it is critical to understand the reaction pathways that lead to PAH formation in the supercritical fuel pyrolysis environment.

To better understand the role of large 1-alkenes in PAH formation, supercritical pyrolysis experiments with model fuel 1-octene, a representative 1-alkene product from supercritical n-alkane pyrolysis, have been performed. The …

High Power And Optomechanics In Advanced Ligo Detectors, Terra Christine Hardwick

LSU Doctoral Dissertations

In September 2015, a new era of astronomy began with the first direct detection of grav- itational waves from a binary black hole coalescence. The event was captured by the Laser Interferometer Gravitational-wave Observatory, comprised of two long-baseline interferometers, one in Livingston, LA and one in Hanford, WA. At the time of the first detection, the interferometers were part way through an upgrade to an advanced configuration and were operating with a strain sensitivity of just better than 10⁻²³/Hz^1/2 around 100Hz. The full Advanced LIGO design calls for sensitivity of a few parts in 10⁻²⁴/Hz …

Alpha Capture Reaction Rates For Nucleosynthesis Within An Ab Initio Framework, Alison Constance Dreyfuss

LSU Doctoral Dissertations

Clustering in nuclear systems has broad impacts on all phases of stellar burning, and plays a significant role in our understanding of nucleosynthesis, or how and where nuclei are produced in the universe. The role of alpha particles in particular is extremely important for nuclear astrophysics: ⁴He was one of the earliest elements produced in the Big Bang, it is one of the most abundant elements in the universe, and helium burning -- in particular, the triple-alpha process -- is one of the most important ``engines'' in stars. To better understand nucleosynthesis and stellar burning, then, it is important …

Electrification Ionization: Fundamentals And Applications, Bijay Kumar Banstola

LSU Doctoral Dissertations

Electrification ionization is a method to produce ions from solid samples by charge separation. This separation of charge can be enhanced by organic molecules known as matrix compounds to produce highly charged molecules. In this research, new methods were developed for the application of electrification ionization for surface analysis and the ionization mechanism was investigated. First, an electrification ionization matrix was used for tissue imaging using laser ablation. A two-component matrix of 2-nitrophloroglucinol and silica nanoparticles was found to increase the number of multiply charged ions from the tissue. Images of mouse brain with multiply charged ions were obtained. In …

Habitat Associations And Reproduction Of Fishes On The Northwestern Gulf Of Mexico Shelf Edge, Elizabeth Marie Keller

LSU Doctoral Dissertations

Several of the northwestern Gulf of Mexico (GOM) shelf-edge banks provide critical hard bottom habitat for coral and fish communities, supporting a wide diversity of ecologically and economically important species. These sites may be fish aggregation and spawning sites and provide important habitat for fish growth and reproduction. Already designated as habitat areas of particular concern, many of these banks are also under consideration for inclusion in the expansion of the Flower Garden Banks National Marine Sanctuary. This project aimed to gain a more comprehensive understanding of the communities and fish species on shelf-edge banks by way of gonad histology, …

Exploring Planetary Surfaces With Remote Sensing, Donald R. Hood

LSU Doctoral Dissertations

Aside from Earth, Mars is the most well-explored planetary body in our solar system. Much has been learned about its geologic past including a history of volcanism, ice ages, and potentially long-lasting liquid water. Much of this knowledge of Mars comes from remote observations of the surface and atmosphere from Mars-orbiting satellites. Such remote observations remain the only way to examine the entirety of Mars’ surface as rovers and landers can only examine small areas. The chapters of this work cover three projects that explore the surface of Mars through a variety of remote sensing methods.

In chapter 1, Gamma-ray …

Neogene Chemical Weathering And Provenance Records Of The Western Himalaya Preserved In The Arabian Sea, Peng Zhou

LSU Doctoral Dissertations

Some tectonic models for the Himalaya emphasize the importance of surface processes in controlling the structural evolution. To investigate this tectonic–climatic interactions, and the weathering and erosion of the western Himalaya, International Ocean Discovery Program (IODP) Expedition 355 drilled two sites (site U1456 and U1457) in Laxmi Basin, which located in the Eastern Arabian Sea. In my research project, I plan to use a series of geochemical and geochronological methods on the sediment samples from the cores of these two sites, and sediments from an industrial borehole Indus Marine A-1, which near the Indus river mouth, to reconstruct a climatic …

Quartz Crystal Microbalance Based Sensors For Detection And Discrimination Of Volatile Organic Compounds Using Ionic Materials, Stephanie R. Vaughan

LSU Doctoral Dissertations

Volatile organic compounds (VOCs) are prevalent in everyday life, ranging from household chemicals, naturally occurring scents from common plants and animals, to industrial-scale chemicals. Many of these VOCs are known to cause adverse health and environmental effects and require regulation to prevent pollution. Detecting VOCs plays a critical role in food quality control, environmental quality control, medical diagnostics, and explosives detection. Thus, development of adequate sensing devices for detection and discrimination of VOCs is of great importance. In recent years, use of quartz crystal microbalance (QCM) based sensor arrays for analyses of VOCs has attracted significant interest. Detection of VOCs …

Development Of A Tunable Platform For The Study Of Geomacromolecular Matrices Using Controlled Radical Polymerization, Arjun Pandey

LSU Doctoral Dissertations

Soil is an important environmental component, and the study of soil processes have many practical implications such as improvement in agriculture, mitigation of climate change etc. The widespread use of Agricultural Chemicals (ACs) in modern agriculture has resulted in adverse effects in environment and human health mostly through contamination into food and water sources. Study of fate, bioavailability, and transport of ACs involves molecular level understanding of their interactions with soil. This can be challenging due to complex and heterogeneous nature of soil. One common approach used is the correlation of macroscopic properties of soil, (e.g. sorption) with empirical parameters …

Thioenamide Synthesis Inspired By Peptide Macrocycles, Joshua Allen Lutz

LSU Doctoral Dissertations

Despite advances in medicine, antibiotic resistance threatens to return once preventable diseases to the human population. The microbisporicins are 24-amino acid antibiotic peptides belonging to the lantibiotic class, which pathogens have been slow to develop resistance. The uncommon post-translational modification S-[(Z)-2-aminovinyl]-D-cysteine (AviCys) is likely crucial to their activity, and appears in a small number of other peptides with compelling biological activities. Total synthesis of an AviCys-containing peptide has eluded the chemical community.

The primary challenge of AviCys synthesis is the construction of a thioenamide functional group. We demonstrate that acid-promoted reactions between an amide and …

Investigation Of Subsurface Stratigraphy And Groundwater Dynamics In The Mississippi River Delta, An Li

LSU Doctoral Dissertations

The Mississippi River Delta (MRD) is socioeconomically important to the state of Louisiana and the United States. Various types of land-water system data have been collected in the MRD. However, very few efforts have been made to utilize these datasets in modeling regional stratigraphy and groundwater dynamics in the MRD, especially for the upper 50 m of the depth. In this interval of depth, the Mississippi River and surrounding interdistributary bays intensively interact with the groundwater system. The lack of knowledge in regional stratigraphy and groundwater dynamics hinder an understanding of how hydrogeological setting affects processes such as surface-groundwater interaction, …

Ultrafast And Real-Time Dynamics Of Nanomaterials Studied By Advanced Spectroscopic Techniques, Jeewan Chaminda Ranasinghe

LSU Doctoral Dissertations

Ultrafast and nonlinear spectroscopies are used to study excited-state dynamics and monitor real-time growth dynamics of different types of nanomaterials. In the first study, the growth dynamics of colloidal gold-silver core-shell nanoparticles are studied using in situ second harmonic generation and extinction spectroscopy. The growth lifetimes are studied under different reaction conditions, resulting in different silver shell thicknesses, with spectral comparisons to finite-difference time-domain calculations. The results are consistent with a three-step growth process. During the first step of the nanoparticle growth reaction, rough and uneven surfaces are formed rapidly giving rise to plasmonic hot spots with corresponding broad, red-shifted …

A Numerical Investigation Of Sediment Dynamics In The Northern Gulf Of Mexico In Connection With Hurricanes, Fluid Mud, Climate Change, And Biogeochemical Cycling, Zhengchen Zang

LSU Doctoral Dissertations

Sediment transport and deposition in marginal seas is jointly controlled by many factors including hydrodynamics, fluvial inputs, and the characteristics of sediment particles. This dissertation study employs the coupled ocean-atmosphere-wave-and-sediment transport modeling system (COAWST) to investigate the mechanism of sediment transport in the northern Gulf of Mexico (nGoM) on different temporal scales, as well as its interaction with biogeochemical processes.

First of all, a three-way coupled (atmosphere-wave-ocean) hurricane model reproduced the hydro- and sediment dynamics during hurricane Gustav (2008). Intensive alongshore and offshore currents were simulated on the eastern/western sectors of hurricane track, respectively. High suspended sediment concentration (SSC) was …

Turn-On Near-Infrared Fluorescent Sensors For Selective Monitoring Of Kinase Activity, Gerard Thomas Ducharme

LSU Doctoral Dissertations

Reliable and selective detection of specific biopolymers is critical in a broad range of biomedical and technological areas, including availability of simple and efficient point-of-care-compatible systems for the detection of prognostic, pharmacodynamic and predictive biomarkers. Monitoring epidermal growth factor receptor (EGFR) tyrosine kinase is of major significance due to its link to many epithelial cancers. This task is complicated by the high rate of mutation occurring in patients treated with kinase inhibitors. This dissertation describes a conceptually novel design and synthesis of turn-on near-infrared fluorescent sensors for selective and sensitive detection of EGFR. The fluorescent signal generation mechanism is based …

Coupled Landscape And Channel Dynamics Across The Ganges-Brahmaputra Tidal-Fluvial Continuum, Southwest Bangladesh, Edwin Jefferson Bomer Iv

LSU Doctoral Dissertations

The Ganges-Brahmaputra (G-B) Delta of Bangladesh and India is widely considered to be one of the most vulnerable coastal systems in the world, owing to locally-accelerated sea level rise and landscape modification by human activities. Recent research efforts have identified pronounced elevation differences between natural and embanked areas in the G-B tidal delta plain, suggesting that natural landscapes are keeping pace with sea-level rise while anthropogenic locations are actively subsiding. However, this observation represents a singular point in time, and longitudinal trends of surface elevation in these regions are presently unknown. For communities residing in upstream regions of G-B delta …

Sequence-Defined Ionic Peptoid Block Copolymers: Synthesis And Solution Self-Assembly, Garrett Leigh Sternhagen

LSU Doctoral Dissertations

This work covers efforts to develop a peptoid-based model system for systematically studying the role of ionic functional groups in determining the structure of ionic block copolymer (BCP) self-assemblies in water. A key challenge in the study of polyelectrolytes is the lack of synthetic control over the location of ionic monomers along a polymer chain. We developed a model system based on sequence-defined ionic peptoid BCPs having discrete chain length and precisely positioned ionic monomers along the chain to specifically address this issue. In Chapter 1, synthetic strategies to access well-defined polypeptoids and their application in BCP synthesis are reviewed. …

Sub-Tidal Hydrodynamics Of The Multi-Inlet Lake Pontchartrain Estuary Influenced By Mississippi River Diversion And Wind Associated With Atmospheric Fronts, Wei Huang

LSU Doctoral Dissertations

In-situ observations and a Finite Volume Community Ocean Model (FVCOM) are used to investigate the cold front induced sub-tidal hydrodynamics of Lake Pontchartrain, a semi-enclosed low-salinity estuary with multiple inlets connecting to the open ocean. Observations show that the sub-tidal hydrodynamic responses are highly correlated with the meteorological parameters during cold front events. Model results indicate that, under barotropic conditions, the remote wind effect has the greatest contribution to the overall water level variation, while the local wind stress during cold front events determines the slope for the water level inside the estuary. An examination of a quasi-steady state force …

Modeling Chemical Reactivity In Aqueous And Organic Systems: From Electronic Structure Methods To Force Field Development, Caitlin Gibson Bresnahan

LSU Doctoral Dissertations

Modeling reactivity in chemical systems has evolved dramatically in line with the capabilities of modern computing. Despite the advances in computational ability, the level in which one can model a system depends on a number of factors including the region of reactivity, size of the system, level of sophistication required in the molecular description, and so on. Electronic structure methods allow for a detailed description of the potential energy surface and inherently include all essential physics required for reactivity to occur, however these methods are limited by their computational expense. On the other hand, force fields allow for an atomistic …

The Importance Of Landscape Position Information And Elevation Uncertainty For Barrier Island Habitat Mapping And Modeling, Nicholas Matthew Enwright

LSU Doctoral Dissertations

Barrier islands provide important ecosystem services, including storm protection and erosion control to the mainland, habitat for fish and wildlife, and tourism. As a result, natural resource managers are concerned with monitoring changes to these islands and modeling future states of these environments. Landscape position, such as elevation and distance from shore, influences habitat coverage on barrier islands by regulating exposure to abiotic factors, including waves, tides, and salt spray. Geographers commonly use aerial topographic lidar data for extracting landscape position information. However, researchers rarely consider lidar elevation uncertainty when using automated processes for extracting elevation-dependent habitats from lidar data. …

Electromagnetic Sum Rules And Response Functions From The Symmetry-Adapted No-Core Shell Model, Robert Byron Baker

LSU Doctoral Dissertations

Recent developments in ab initio nuclear structure have provided us with a variety of many-body methods capable of describing nuclei into the medium-mass region of the chart of nuclides. One of these, the symmetry-adapted no-core shell model (SA-NCSM), capitalizes on inherent symmetries of the nucleus and is uniquely suited to examine the underlying physics of dynamical quantities, such as the response function.

We examine the applicability of the SA-NCSM to calculations of these quantities and assess the quality of its inputs by calculating electromagnetic sum rules and response functions with the Lanczos sum rule method and Lanczos response function method, …

Quantum Cluster Algebras At Roots Of Unity, Poisson-Lie Groups, And Discriminants, Kurt Malcolm Trampel Iii

LSU Doctoral Dissertations

This dissertation studies quantum algebras at roots of unity in regards to cluster structure and Poisson structure. Moreover, quantum cluster algebras at roots of unity are rigorously defined. The discriminants of these algebras are described, in terms of frozen cluster variables for quantum cluster algebras and Poisson primes for specializations of quantum algebras. The discriminant is a useful invariant for representation theoretic and algebraic study, whose laborious computation deters direct evaluation. The discriminants of quantum Schubert cells at roots of unity will be computed from the two distinct approaches. These methods can be applied to many other quantum algebras.

Hourly Precipitation Climatology Of The Southeast United States, Vincent Brown

LSU Doctoral Dissertations

Precipitation changes are one of the most important potential outcomes of a warming climate because of how essential it is to society and ecosystems. Sub-daily precipitation time series provide more information on precipitation characteristics, particularly frequency, intensity, and duration compared to daily data. In a series of four peer-reviewed manuscripts, this research investigates sub-daily precipitation characteristics from a climatological perspective. The first study introduces a climatology of hourly precipitation for four first-order weather stations across Louisiana, explores possible changes in the hourly precipitation distribution, and links winter Gulf of Mexico sea surface temperatures to the frequency of hours with precipitation. …

Design Of Metamaterials For Optics, Abiti Adili

LSU Doctoral Dissertations

First part of this dissertation studies the problem of designing metamaterial crystals with double negative effective properties for applications in optics by investigating the conditions necessary for generating novel dispersion properties in a metamaterial crystal with subwavelength microstructure. This provides novel optical properties created through local resonances tied to the geometry of the media in subwavelength regime.

In the second part, this dissertation studies the representation formula used to describe band structures in photonic crystals with plasmonic inclusions. By using layer potential techniques, a magnetic dipole operator describing the tangential component of the electrical field generated by magnetic distribution is …