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Physical Sciences and Mathematics Commons

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Full-Text Articles in Physical Sciences and Mathematics

Measurement Of Free Radicals Oh And Ho₂ In Los Angeles Smog, Linda Acha George, Thomas M. Hard, Robert J. O'Brien May 1999

Measurement Of Free Radicals Oh And Ho₂ In Los Angeles Smog, Linda Acha George, Thomas M. Hard, Robert J. O'Brien

Environmental Science and Management Faculty Publications and Presentations

Atmospheric free radicals hydroxyl and hydroperoxyl (OH and HO₂, collectively HOᵪ ) are the catalysts that cause secondary or photochemical air pollution. Chemical mechanisms for oxidant and acid formation, on which expensive air pollution control strategies are based, must accurately predict these radical concentrations. We have used the fluorescence assay with gas expansion (FAGE) technique to carry out the first simultaneous, in situ measurements of these two radicals in highly polluted air during the Los Angeles Free Radical Experiment. A complete suite of ancillary measurements was also made, including speciated hydrocarbons, carbon monoxide, aldehydes, nitric oxide, nitrogen dioxide, and ozone …


Internal Temperature Of Douglas-Fir Buds Is Altered At Elevated Temperature, Martha E. Apple, Melissa S. Lucash, David M. Olszyk, David T. Tingey, Donald L. Phillips Feb 1999

Internal Temperature Of Douglas-Fir Buds Is Altered At Elevated Temperature, Martha E. Apple, Melissa S. Lucash, David M. Olszyk, David T. Tingey, Donald L. Phillips

Environmental Science and Management Faculty Publications and Presentations

Pseudotsuga menziesii (Douglas-fir) saplings were grown in sun-lit controlled environment chambers at ambient or elevated (4°C above ambient) temperature. We measured internal temperatures of vegetative buds with thermocouple probes and compared temperatures of normal buds and abnormal buds with loosened, rosetted outer scales in elevated temperature chambers. The abnormal buds had higher and earlier peak daily temperatures than normal buds. Elevated temperature may influence the internal temperature of buds and contribute to the development of abnormal, rosetted buds with loosened outer scales. Abnormal bud development may alter branching patterns and allometry of Douglas-fir trees subjected to climatic change.