Physical Sciences and Mathematics Commons^™

Intra-Population Variation Of Hair And Fingernail Stable Hydrogen, Oxygen, Carbon And Nitrogen Isotopes In London, Ontario, Canada Residents During The Covid-19 Pandemic, Sawyer C E Rowe

Electronic Thesis and Dissertation Repository

Lockdowns and travel restrictions during the COVID-19 pandemic forced a significant fraction of London, Ontario, Canada residents to remain in one location for long enough to reach isotopic equilibrium with their primary drinking water source(s). This situation created ideal natural conditions for measuring the isotopic fractionation between the stable hydrogen and oxygen isotopes of drinking water and hair or nail tissues, and for determining the magnitude of intra-population variation in tissue δ²H and δ¹⁸O. Hair and nail of participants who reported exclusively drinking London municipal tap water spanned much larger δ²H and δ^{18 …}

Effects Of Glutamine Deamidation On The Oxygen Isotope Compositions Of Bone Collagen, Curtis W. Russell

Electronic Thesis and Dissertation Repository

The oxygen (O) isotope composition of mammalian collagen has the potential to provide information about the drinking water and hence geographic location and climate during the life of modern and ancient animals. An accurate and reproducible O-isotope analysis of collagen, however, has been elusive. Here, the O-isotope compositions of collagen from cortical bone of four megaherbivores were compared using two extraction procedures: the traditional Longin (HCl) method and the less commonly employed EDTA method. Preservation of O-isotope compositions was evaluated by measuring collagen peptide-chain masses, specifically the glutamine deamidation level (GDL). The EDTA method yielded collagen with a GDL of …

Impact Of Interlayer Cation Composition And Strongly Bound Water On Smectite ẟ²H, As Determined By A Modified Tcea Method, Nadine J. Kanik

Electronic Thesis and Dissertation Repository

Interlayer cation composition and cation hydration enthalpy can potentially affect the excess hydrogen-yield and δ²H of smectitic clays. Complexities arise from condensed atmospheric water adsorbed on the clay, as it constitutes a potential additional source of hydrogen when attempting to measure the δ²H of structural OH groups. To approach this problem, the δ²H of different cation-saturated, dried forms of six Clay Minerals Society Source Clay smectites were measured. A modified sample drying and on-line High-Temperature-Conversion-Elemental-Analysis (TCEA) Continuous-Flow-Isotope-Ratio-Mass-Spectrometry protocol, facilitated isotopic measurements. A stronger interlayer cation hydration enthalpy (Ca²⁺>Na⁺>K⁺), …

Condition And Function Of Red River Valley Streams Receiving Nutrients From Human Activities In Manitoba, Canada, Kristin J. Painter

Electronic Thesis and Dissertation Repository

Small tributary streams are conduits between the landscape and larger waterbodies and provide important ecosystem services including assimilation of nutrients from human activities which may be protective of downstream waterbodies. In the Red River Valley (RRV), Manitoba, numerous nutrient sources including agricultural runoff, livestock manure, and municipal wastewater effluent, have been attributed to the eutrophication of Lake Winnipeg and thus require targeted management to prevent loss of nutrients from land to lake. However, linkages between land-based nutrient-producing human activities in the RRV and the ecological status of the tributaries remain poorly understood. Furthermore, the proportional contribution of each source of …

Paleoproductivity Of Late Holocene Lake Huron, Jamal Khaled Nigim

Electronic Thesis and Dissertation Repository

The paleolimnology of North America’s Lake Huron is described using lead-210 dating, mineralogy, magnetic susceptibility, total organic carbon (TOC), total nitrogen (TN), carbon:nitrogen (C/N) ratio, grain size, and the δ¹³C_OM and δ¹⁵N_TN of organic matter. Sediment cores from Lake Huron’s 6 depositional basins and Georgian Bay span the Medieval Warm Period, Little Ice Age, and Canadian-European settlement. The main organic matter source is lacustrine algae, as indicated by δ¹³C_OM, δ¹⁵N_TN and C/N. Prior to the 19th century, primary production changes are reflected only by small variations in …

Using Stable Isotopes To Understand Survival Versus Extinction Of Late Pleistocene Muskoxen, Stephanie Mabee

Electronic Thesis and Dissertation Repository

This thesis uses stable isotopes to investigate the adaptive advantages of Ovibos moschatus, a muskox, relative to now-extinct Pleistocene megafauna in eastern Beringia (Yukon Territory and Alaska), including another muskox Bootherium bombifrons. Ecological niches were defined for Ovibos and Bootherium using stable carbon and nitrogen isotope compositions of bone collagen. Plant remains trapped in modern Ovibos molars were used to determine the carbon and nitrogen isotope collagen-diet discrimination factors, which were then applied to ancient specimens. Ovibos possessed larger isotopic – and hence ecological – niches than Bootherium across eastern Beringian sites. The larger niche suggests that Ovibos …

Reframing The Mammoth Steppe: Examining Mammoth Steppe Ecology Using Carbon And Nitrogen Isotopic Compositions Of Megafauna Collagen, Rachel E. Schwartz-Narbonne

Electronic Thesis and Dissertation Repository

The Pleistocene mammoth steppe was a vast biome that stretched from northwestern Europe to central Canada. A diverse set of megaherbivore and megacarnivore species lived within this biome and there was significant ecosystem faunal and floral homogeneity. At the end of the Pleistocene, this biome disappeared, with the extinction or extirpation of many of the megafaunal species that inhabited it. This thesis reconstructs the ecology of the mammoth steppe using the isotopic compositions of carbon and nitrogen from megafaunal collagen. The reconstruction is done at a variety of ecological scales, beginning with individual animal- and season-specific isotopic studies of antlers, …

Stable Isotope Paleolimnology Of Barry Lake, Ontario, Canada Since Ad - 1268, Zijun Liu

Electronic Thesis and Dissertation Repository

The paleolimnology of Barry Lake, SE Ontario, Canada is described using mineralogy, magnetic susceptibility, carbon:nitrogen ratio, mass accumulation rates, grain-size, δ¹⁸O and δ¹³C of authigenic calcite and mollusc aragonite, δ¹³C and δ¹⁵N of organic matter, and archival records. These sediments span the Medieval Warm Period (MWP), Little Ice Age (LIA), and human settlement. Interval I proxies (AD 1268-1350, MWP) indicate warmer and drier conditions and elevated lacustrine production. Interval II (AD 1350-1615) was cooler and wetter, with lower lacustrine production and low-oxygen conditions causing loss of shelly fauna. Interval III (AD 1615-1850, …

Identification Of Ancient Maya Agriculture In The Periphery Of Motul De San José, Alexandra E. Smofsky

Electronic Thesis and Dissertation Repository

Agricultural systems were investigated in the Motul de San José periphery, an ancient Maya polity in Guatemala, using soil geochemical techniques. The δ¹³C values of soil organic matter delineated areas of ancient maize agriculture at the satellite center of Kante’t’u’ul. A new method to locate areas of former cacao cultivation or processing was developed using HPLC to detect theobromine, an alkaloid of the cacao plant, preserved in soils. Extraction of spiked soils revealed that theobromine adsorption is inversely correlated with organic matter content of soils. Detection of naturally occurring theobromine was successful, demonstrating its utility as a tracer. …

The Late Quaternary Paleolimnology Of Lake Ontario, Ryan Hladyniuk

Electronic Thesis and Dissertation Repository

We examined the oxygen isotopic composition of biogenic carbonates, carbon and nitrogen abundances and isotopic compositions of bulk organic matter (OM), and the abundances and carbon isotopic compositions of individual n-alkanes (C₁₇ to C₃₅) for samples from three, 18 m long sediment cores from Lake Ontario in order to: (i) assess how changing environmental parameters affected the hydrologic history of Lake Ontario, and (ii) evaluate changes in organic productivity and sources since the last deglaciation. Knowledge of the hydrologic and ecological behaviour of the Lake Ontario basin during past climate change provides insight into its future …

Isotopic Fingerprinting Of Shallow And Deep Groundwaters In Southwestern Ontario And Its Applications To Abandoned Well Remediation, Mitchell E. Skuce

Electronic Thesis and Dissertation Repository

Abandoned hydrocarbon wells in southwestern Ontario can act as conduits for Sulphur water, brines, and hydrocarbons from deep Paleozoic bedrock aquifers. Such leakage may pose a threat to shallow groundwater and the environment. Cost-effective plugging of these wells requires knowledge of the sources of the leaking fluids. This study characterizes the isotopic compositions (δ18OH2O, δ2HH2O, δ34SSO4, δ18OSO4, δ13CDIC, 87Sr/86Sr) of groundwaters in the region, which are distinct in different bedrock formations. A Bayesian mixing model was applied to these data to develop a tool for identifying the source(s) of leaking fluids. The geochemical data also improve our understanding of groundwater …

Stable Isotope Ecology And Human-Animal Interactions In Northern Peru, Paul Szpak

Electronic Thesis and Dissertation Repository

This dissertation addresses several issues related to isotopic ecology in northern Peru. The first portion of the dissertation focuses on baseline carbon and nitrogen isotopic variability in plants for comparison with paleodietary data. The second portion applies these data to assess animal management practices (camelids) in the Virú Valley on the north coast of Peru using isotopic analysis of bone collagen and serially sampled hair. A detailed survey of plants from the Moche River Valley region demonstrates significant east-west variation in plant carbon and nitrogen isotopic compositions, following changes in altitude from the Pacific coast to the highlands. A growth …

Origins Of Stable Isotopic Variations In Late Pleistocene Horse Enamel And Bone From Alberta, Nicolle S. Bellissimo

Electronic Thesis and Dissertation Repository

Oxygen and carbon isotopic measurements of coevally formed bone and tooth enamel bioapatite from a modern equid show that these tissues record drinking water and diet isotopic signals in an identical fashion. Hence, data for both tissues can be combined to track movement, dietary changes, and seasonal variability over the animal’s lifetime, and climatic variability over longer time periods. This tool was tested for horses using ten paired tooth and bone samples to reconstruct conditions in Alberta during the Late Pleistocene. While post-mortem isotopic alteration confounded interpretation of the results, two key findings emerged: (i) pre- and post-Last Glacial Maximum …

Late Pleistocene Climate And Proboscidean Paleoecology In North America: Insights From Stable Isotope Compositions Of Skeletal Remains, Jessica Z. Metcalfe

Electronic Thesis and Dissertation Repository

This thesis uses the carbon, nitrogen, and oxygen isotope compositions of mammoth (Mammuthus) and mastodon (Mammut) skeletal remains to reconstruct paleoclimate and paleoecology in Late Pleistocene North America. Analytical methods, sampling strategies, environmental adaptations and seasonal behaviors of proboscideans were investigated.

Reliable and reproducible results are crucial for a study of this nature. A persistent methodological problem in the isotope analysis of structural carbonate in bioapatite was solved by reacting bioapatite under “sealed vessel” conditions.

Growth rate determinations are critical for designing sampling strategies and interpreting results. Histological and isotopic measurements demonstrated variations in enamel growth …

The Holocene Paleolimnology Of Lake Superior, Ayumi Hyodo

Electronic Thesis and Dissertation Repository

This study describes contributions of glacial meltwater to Lake Superior over the last ~11,000 cal BP (calibrated years before 1950 AD). This research has been motivated by a desire to understand whether glacial meltwater discharge via the Great Lakes into the North Atlantic played a role in Holocene cooling events, such as the Younger Dryas. Rhythmites (interpreted as varves), lithological, mineralogical and grain-size variations, and radiocarbon dating were used to establish chronostratigraphic correlation among four sediment cores from Lake Superior (Duluth, Caribou and Ile Parisienne basins, Thunder Bay Trough). Glacial sediments were deposited between ~10,850 and ~8,800 cal BP. The …