Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
- Discipline
Articles 1 - 2 of 2
Full-Text Articles in Physical Sciences and Mathematics
The Electrochemical And Corrosion Study Of Copper For Nuclear Waste Containers Under Deep Geological Disposal Conditions, Mengnan Guo
Electronic Thesis and Dissertation Repository
The proposed method for the safe disposal of Swedish, Finnish, and Canadian high-level nuclear waste (HLNW) is to isolate it in iron or steel containers with an outer copper (Cu) shell or coating and bury it in a deep geological repository (DGR). Copper has been selected as the corrosion barrier due to its stability in the aqueous anoxic environments anticipated in DGR conditions. The container will initially be exposed to humid aerated conditions which will evolve to cool and anoxic as radiation fields in the fuel decay and heat production ceases. When the DGR is cool and anoxic, sulphide (SH …
The Influence Of Radiolytically Produced Nitric Acid On The Corrosion Resistance Of Copper-Coated Used Nuclear Fuel Containers, Joseph P. Turnbull
The Influence Of Radiolytically Produced Nitric Acid On The Corrosion Resistance Of Copper-Coated Used Nuclear Fuel Containers, Joseph P. Turnbull
Electronic Thesis and Dissertation Repository
In Canada, the proposed disposal method for high level nuclear waste involves sealing the waste in steel containers with a 3 mm outer copper coating and burying it in a deep geologic repository. However, the thickness of the container is significantly reduced making a reassessment of the influence of γ-radiation, emitted by the waste form, on container corrosion a potential licensing requirement. Under humid aerated conditions, the formation of nitric acid is expected, potentially resulting in the formation of droplets or wetted layers on the container surface. Currently available literature on the corrosion of copper in nitric acid does not …