Physical Sciences and Mathematics Commons^™

Investigation Of Flow Disturbances And Multi-Directional Wall Shear Stress In The Stenosed Carotid Artery Bifurcation Using Particle Image Velocimetry, Amanda L. Dicarlo

Electronic Thesis and Dissertation Repository

Hemodynamics and shear forces are associated with pathological changes in the vascular wall and its function, resulting in the focal development of atherosclerosis. Flow complexities that develop in the presence of established plaques create environments favourable to thrombosis formation and potentially plaque rupture leading to stroke. The carotid artery bifurcation is a common site of atherosclerosis development. Recently, the multi-directional nature of shear stress acting on the endothelial layer has been highlighted as a risk factor for atherogenesis, emphasizing the need for accurate measurements of shear stress magnitude as well direction. In the absence of comprehensive patient specific datasets numerical …

Properties Of Si Quantum Dots, Carolyn C. F Cadogan

Electronic Thesis and Dissertation Repository

The fundamental properties of matter in confined particles change dramatically due to quantum effects. In this work, we have explored the optical properties of silicon quantum dots (Si-QDs) embedded in Si₃N₄; and the role of crystallinity on the optical properties and formation of Si-QDs in Al₂O₃. This work examined the role of (1) annealing temperature and the composition of the film, (2) Al doping of the host Si₃N₄ film, (3) doping Si-QDs and (4) Al and P passivation of Si-QDs on the PL intensity of Si-QDs embedded in Si …

Copper-Nanoparticle Decorated Graphene Thin Films: Applications In Metal-Assisted Etching And Synthesis Of Next-Generation Graphene-Based Nanomaterials, Jaewoo Park

Electronic Thesis and Dissertation Repository

Since 2006, the experimental discovery of graphene, a single-layer of carbon atoms, has spurred tremendous efforts towards new graphene-based materials. In graphene research, there is a recent trend towards next-generation materials in which graphene layers are locally modified in a controlled fashion at the nanoscale and tailored for specific applications. Examples include nanoparticle-decorated graphene thin films with surface potential tailored for nanoelectronics or advanced catalysis, graphene nanoribbons, graphene quantum dots, and the scalable fabrication of tiny pores in graphene, which are suitable to applications requiring ultrathin molecular sieving membranes. This research is focused on the development of new applications of …

High Resolution Ion Beam Investigations Of The Mechanisms Of Titanium Anodization, Mitchell A. Brocklebank

Electronic Thesis and Dissertation Repository

The unique behaviour of thin films, and their surfaces and interfaces, significantly impact material and device properties. Probing these structures with ion beams (IB) provides quantitative composition and thicknesses measurements. In this dissertation, the IB techniques of medium energy ion scattering (MEIS), nuclear reaction profiling (NRP) and Rutherford backscattering spectrometry (RBS) are used to analyze energy losses in ultra-thin films, as well as elucidate the mechanisms of anodic film growth.

Accurate stopping cross sections of protons, ε, in the medium energy range (50-170 kV) often show deviations from Bragg’s rule. Here, ε_Ti, ε_Si, and ε_{TiO2 …}

Experimental Measurements Of Human Cough Airflows From Healthy Subjects And Those Infected With Respiratory Viruses, Nicholas Dudalski

Electronic Thesis and Dissertation Repository

Research concerning person-to-person respiratory virus transmission is required to develop reliable, evidence-based infection prevention and control measures. Experimental studies of human coughs were comprehensively critiqued from the point of view of methodologies, aerodynamics, droplet dispersion and virology. Particle image velocimetry (PIV) and hot-wire anemometry (HWA) measurements were conducted at x=1 m away from the mouth of human subjects to develop a model for cough flow behaviour at greater distances from the mouth than those studied previously. Experiments were conducted for sick subjects who had presented with influenza-like illness, together with a cohort of healthy subjects. Biological aerosol sampling was conducted …

The Periglacial Landscape Of Mars: Insight Into The 'Decameter-Scale Rimmed Depressions' In Utopia Planitia, Arya Bina

Electronic Thesis and Dissertation Repository

Currently, Mars appears to be in a ‘frozen’ and ‘dry’ state, with the clear majority of the planet’s surface maintaining year-round sub-zero temperatures. However, the discovery of features consistent with landforms found in periglacial environments on Earth, suggests a climate history for Mars that may have involved freeze and thaw cycles. Such landforms include hummocky, polygonised, scalloped, and pitted terrains, as well as ice-rich deposits and gullies, along the mid- to high-latitude bands, typically with no lower than 20o N/S. The detection of near-surface and surface ice via the Phoenix lander, excavation of ice via recent impact cratering activity as …

Performance Impact Of Different Lower-Limb Setup Positions In The Backstroke Swimming Start, Gordon E. Barkwell

Electronic Thesis and Dissertation Repository

The performance impact of different knee extension angles in the setup position for a backstroke start was evaluated using an instrumented starting surface. Ten backstroke swimmers completed maximum-effort starts in each of two setup positions: one with the knees flexed, and one with the knees extended. The start handles and touchpad were instrumented with tri-axial force plates. Activity of major hip and knee extensors was measured using surface electromyography. Body position was recorded throughout the start using two high-speed cameras. There was no difference in time to 10 m between the two conditions, indicating there is likely no advantage in …

Topological Recursion And Random Finite Noncommutative Geometries, Shahab Azarfar

Electronic Thesis and Dissertation Repository

In this thesis, we investigate a model for quantum gravity on finite noncommutative spaces using the topological recursion method originated from random matrix theory. More precisely, we consider a particular type of finite noncommutative geometries, in the sense of Connes, called spectral triples of type ${(1,0)} \,$, introduced by Barrett. A random spectral triple of type ${(1,0)}$ has a fixed fermion space, and the moduli space of its Dirac operator ${D=\{ H , \cdot \} \, ,}$ ${H \in {\mathcal{H}_N}}$, encoding all the possible geometries over the fermion space, is the space of Hermitian matrices ${\mathcal{H}_N}$. A distribution of the …

Vibrating-Wire Rheometry, Cameron C. Hopkins

Electronic Thesis and Dissertation Repository

This thesis consists of two projects on the behaviour of a novel vibrating-wire rheometer and a third project studying the gelation dynamics of aqueous solutions of Pluronic F127. In the first study, we use COMSOL to perform two-dimensional simulations of the oscillations of a wire in Newtonian and shear-thinning fluids. Our results show that the resonant behaviour of the wire agrees well with the theory of a wire vibrating in Newtonian fluids. In shear-thinning fluids, we find resonant behaviour similar to that in Newtonian fluids. In addition, we find that the shear-rate and viscosity in the fluid vary significantly in …

Effects Of High Pressure On Photochemical Reactivity Of Organic Molecular Materials Probed By Vibrational Spectroscopy, Jiwen Guan

Electronic Thesis and Dissertation Repository

Chemical transformations of molecular materials induced by high pressure and light radiation exhibit novel and intriguing aspects that have attracted much attention in recent years. Particularly, under the two stimuli, entire transformations of molecular species can be realized in condensed phases without employing additional chemical constraints, e.g., the need of solvents, catalysts or radical initiators. This new synthetic approach in chemistry therefore satisfies increasing need for production methods with reduced environmental impacts. Motivated by these promises, my Ph. D thesis focuses on this state-of-the-art branch of high-pressure photochemistry. Specifically, high pressure is employed to create the necessary reaction conditions to …

Defect-Related Magnetic Properties Of Nanostructured Nickel Oxide Thin Films For Solar Cell Applications, Angela E. Ezugwu

Electronic Thesis and Dissertation Repository

Transparent conducting oxides (TCOs) are extensively investigated because of their applications as transparent electrodes in solar cells and light-emitting devices. TCOs of interest include indium-tin oxide, aluminum-doped zinc oxide, nickel oxide (NiO), and their combinations. There is strong interest in NiO because no heteroatoms are required to “dope” it at high transparency levels. It has been speculated that paramagnetic defects due to Ni³⁺ centers and O interstitials are responsible for the electrical conductivity of otherwise insulating and antiferromagnetic NiO, but direct investigation of such defects has been limited. Here, the electrical conductivity in nanostructured NiO thin films is investigated …

On The Reduction Of The Driving Force In Shear-Driven Flows, Sakib Shadman

Electronic Thesis and Dissertation Repository

In shear-driven flows, an external driving force is needed to maintain the relative movement of horizontal plates. This thesis presents a systematic analysis on using spatially periodic heating and grooved surfaces to control this force. It is found that the use of periodic heating creates a buoyancy-driven effect that always reduces this force. The use of proper heating may even lead to the complete elimination of this force. It is further found that the use of isothermal grooved surfaces always enhances flow resistance, resulting in an increase of this force. When grooves and heating are applied together, their interaction induces …

Compact Sensing Platforms Based On Localized Surface Plasmon Resonance, Zhutian Ding

Electronic Thesis and Dissertation Repository

The development of plasmonic sensors mainly focuses on the improvement of their sensitivities that are approaching the theoretical limit. This work aims to propose, fabricate and characterize compact sensing platforms that are highly adaptable and easy to be miniaturized, without compromising their sensitivities. A plasmonic sensing system that allows the excitation of localized surface plasmon resonance (LSPR) by individual waveguide modes is presented conceptually and experimentally. Another compact sensing platform is proposed based on the ensemble hypothesis developed in this thesis.

Numerical Studies Of Electrohydrodynamic Flow Induced By Corona And Dielectric Barrier Discharges, Chaoao Shi

Electronic Thesis and Dissertation Repository

Electrohyrodynamic (EHD) flow produced by gas discharges allows the control of airflow through electrostatic forces. Various promising applications of EHD can be considered, but this requires a deeper understanding of the physical mechanisms involved.

This thesis investigates the EHD flow generated by three forms of gas discharge. First, a multiple pin-plate EHD dryer associated with the positive corona discharge is studied using a stationary model. Second, the dynamics of a dielectric barrier discharge (DBD) plasma actuator is simulated with a time-dependent solver. Third, different configurations of the extended DBD are explored to enhance the EHD flow.

The results of the …

Optimization Of Design Procedures For Delta Relaxation Enhanced Magnetic Resonance, Daniel J. Martire

Electronic Thesis and Dissertation Repository

Delta relaxation enhanced magnetic resonance (dreMR) is a magnetic resonance imaging (MRI) method that produces contrast based on longitudinal relaxation dispersion. Through modulation of the magnetic field using an actively-shielded, field-cycling insert coil, this technique increases probe specificity and suppresses remaining signal. However, significant improvements are needed. This thesis addresses two advancements in dreMR with a focus on optimizing design procedures. A general procedure was developed to design split power solenoid magnets. The procedure was then applied to the design of a switched-field exposure system. A coil was constructed and the method was validated. This procedure can be used for …