Physical Sciences and Mathematics Commons^™

Influence Of A Suite Of Environmentally Relevant Conditions On Pbt Leaching From, And Sorption To, Marine Microplastic Debris, Robert C. Hale, Da Chen

Reports

Synthetic polymers (plastics) enter marine environments from terrestrial and marine-based sources. The manner of release, the plastic’s composition/properties and ambient marine conditions determine debris fate and its impacts on living resources. It was long assumed that all plastics were persistent and inert, possessing negligible potential for chemical impacts. However, in reality, commercial polymers exhibit a range of potentials for interactions. Persistent, bioaccumulative and toxic (PBT) chemicals are lipophilic and may concentrate from ambient waters by orders of magnitude on polymer surfaces (Teuten et al., 2007). The type of polymer affects the degree of PBT sorption. Indeed, plastics have been found …

Net Primary Productivity Estimates And Environmental Variables In The Arctic Ocean; An Assessment Of Coupled Physical-Biogeochemical Models, Younjoo J. Lee, Patrica A. Matrai, Marjorie A.M. Friedrichs, Et Al

VIMS Articles

The relative skill of 21 regional and global biogeochemical models was assessed in terms of how well the models reproduced observed net primary productivity (NPP) and environmental variables such as nitrate concentration (NO (sub 3) ), mixed layer depth (MLD), euphotic layer depth (Z (sub eu) ), and sea ice concentration, by comparing results against a newly updated, quality-controlled in situ NPP database for the Arctic Ocean (1959-2011). The models broadly captured the spatial features of integrated NPP (iNPP) on a pan-Arctic scale. Most models underestimated iNPP by varying degrees in spite of overestimating surface NO (sub 3) , MLD, …

Analysis Of Drift Effects On The Tokamak Power Scrape-Off Width Using Solps-Iter, E. T. Meier, R. J. Goldston, E. G. Kaveeva, M. A. Makowski, Saskia Mordijck, V. A. Rozhansky, I. Yu Senichenkov, S. P. Voskoboynikov

Arts & Sciences Articles

SOLPS-ITER, a comprehensive 2D scrape-off layer modeling package, is used to examine the physical mechanisms that set the scrape-off width (lambda(q)) for inter-ELM power exhaust. Guided by Goldston's heuristic drift (HD) model, which shows remarkable quantitative agreement with experimental data, this research examines drift effects on lambda(q) in a DIII-D H-mode magnetic equilibrium. As a numerical expedient, a low target recycling coefficient of 0.9 is used in the simulations, resulting in outer target plasma that is sheath limited instead of conduction limited as in the experiment. Scrape-off layer (SOL) particle diffusivity (D-SOL) is scanned from 1 to 0.1 m(2) s(-1). …

Town Of Colonial Beach State Of The Beach Data Summary Report, Donna A. Milligan, C. Scott Hardaway Jr., Christine A. Wilcox

Reports

The Town of Colonial Beach occupies a peninsula between the Potomac River and Monroe Bay (Figure 1). Approximately 2.5 miles of the shoreline is publicly-owned. Two areas on the Potomac River have been enhanced as recreational beaches for swimming and sunbathing. Central Beach extends about 1,650 feet south of the Town Pier and is the main recreational beach. North Central Beach extends about 1,450 feet north of the Town Pier Colonial Avenue. Castlewood Beach is south of Central Beach near the entrance to Monroe Bay. It has about 1,150 feet of sandy beach.

Prince George County Shoreline Management Plan, C. Scott Hardaway Jr., Donna A. Milligan, Christine A. Wilcox, Marcia Berman, Tamia Rudnicky, Karinna Nunez, Sharon A. Killeen

Reports

Much of Prince George County’s shoreline is suitable for a “Living Shoreline” approach to shoreline management. The Commonwealth of Virginia has adopted policy stating that Living Shorelines are the preferred alternative for erosion control along tidal waters in Virginia (http://leg1.state.va.us/cgi‐bin/legp504.exe?111+ful+CHAP0885+pdf). The policy defines a Living Shoreline as …”a shoreline management practice that provides erosion control and water quality benefits; protects, restores or enhances natural shoreline habitat; and maintains coastal processes through the strategic placement of plants, stone, sand fill, and other structural and organic materials.” The key to effective implementation of this policy at the local level is understanding what …

Ecological And Economic Effects Of Derelict Fishing Gear In The Chesapeake Bay 2015/2016 Final Assessment Report, Donna M. Bilkovic, H. Ward Slacum Jr., Kirk J. Havens, Danielle Zaveta, Christopher F.G. Jeffrey, Andrew M. Scheld, David Stanhope, Kory Angstadt, John D. Evans

Reports

Derelict fishing gear represents a major challenge to marine resource management: whether through deliberate abandonment or through accidental loss, derelict traps in particular have significant negative effects both economic (e.g., reduced fishery harvest from ghost fishing and gear competition that leads to the reduced efficiency of active gear) and ecological (e.g., degraded habitats and marine food webs and crab and bycatch mortality). Throughout the Chesapeake Bay, commercial harvest of hard-shelled blue crabs is a major fishing activity: every year sees the deployment of several hundred thousand blue crab traps (known locally as crab “pots”) across the Bay, of which an …

Assessing Ecological And Economic Effects Of Derelict Fishing Gear: A Guiding Framework, Christopher F.G. Jeffrey, Kirk J. Havens, H. Ward Slacum Jr., Donna Marie Bilkovic, Danielle Zaveta, Andrew M. Scheld, Sean Willard, John D. Evans

Reports

Developing standardized protocols to assess the ecological and socio-economic effects of marine debris – especially, derelict fishing gear – is critical for the protection of natural resources and for evaluating policies and programs designed to reduce and remove debris. This document outlines a Derelict Fishing Gear Assessment Framework to guide the development and implementation of derelict gear assessment, management and mitigation. The framework draws from techniques and protocols developed to assess derelict crab traps effects in the Chesapeake Bay and on past derelict gear assessments either conducted by or known to the framework authors. However, this framework is generalized and …

Evaluation Of The Potential Impact On Flow And Sediment Transport From Proposed James River Crossings, Yinglong J. Zhang, Harry V. Wang, Zhuo Liu, Mac Sisson, Jian Shen

Reports

The purpose of this study is to evaluate the potential impact on flow and sedimentation potential due to the proposed new crossings on the lower James River by VDOT. This project was built upon previous effort in the same area (Boon et al. 1999); the latter used VIMS’ 3D Hydrodynamic-Sedimentation Model (HYSED) to study the impact of the bridge-tunnel infrastructure on the physical characteristics (including tides, currents, circulation, salinity and sedimentation) under the existing and alternative scenarios. Due to various limitations at that time, smaller bridge pilings were not resolved but instead parameterized. In this update study, we used an …

Gloucester County Shoreline Management Plan, C. Scott Hardaway Jr., Donna A. Milligan, Christine A. Wilcox, Marcia Berman, Tamia Rudnicky, Karinna Nunez, Sharon A. Killeen

Reports

With approximately 85 percent of the Chesapeake Bay shoreline privately owned, a critical need existsto increase awareness of erosion potential and the choices available for shore stabilization that maintainsecosystem services at the land-water interface. The National Academy of Science published a report thatspotlights the need to develop a shoreline management framework (NRC, 2007). It suggests that improvingawareness of the choices available for erosion control, considering cumulative consequences of erosionmitigation approaches, and improving shoreline management planning are key elements to minimizingadverse environmental impacts associated with mitigating shore erosion.
Actions taken by waterfront property owners to stabilize the shoreline can affect the …

Regression Or Significance Tests: What Other Choice Is There?—An Academic Perspective, Michael C. Newman, Marcos Krull

VIMS Articles

Both the no-observed-effect concentration and its null hypothesis significance testing foundation have drawn steady criticism since their inceptions [1–5]. Many in our field reasonably advocate regression to avoid conventional null hypothesis significance testing shortcomings; however, regression is compromised under commonly encountered conditions (Green, present Perspective’s Challenge). As the debate to favor null hypothesis significance testing or regression methods continues into the 21st century, a sensible strategy might be to take a moment to ask, Are there now other choices? Our goal is to sketch out 1 such choice.

Copper(I) Thiocyanate Networks With Aliphatic Sulfide Ligands, Gerardo Ayala, Robert D. Pike

Arts & Sciences Articles

A total of five new CuSCN-L compounds with alkyl sulfide ligands, L = methyl sulfide (Me2S), ethyl sulfide (Et2S), isopropyl sulfide (Pri2S) or tetrahydrothiophene (THT) have been prepared and characterized. X-ray crystal structures for four of the compounds were obtained. Two compounds were collected from solutions of CuSCN in Me2S: {[Cu(SCN)(Me2S)2]}n (1a) in the form of colorless blocks and (CuSCN)(Me2S) (1b) as a white powder. Neat mixtures of CuSCN in the other alkyl sulfide ligands yielded only one product each: {[Cu(SCN)(Et2S)]}n (2); {[Cu(SCN)(Pri2S)]}n (3); and {[Cu(SCN)(THT)2]}n (4). Crystals of 2 and 4 …

Werowocomoco Shoreline Management Plan, Donna A. Milligan, C. Scott Hardaway Jr., Christine A. Wilcox

Reports

Werowocomoco is located on the York River in Gloucester County, Virginia (Figure 1). Historical documents identified Werowocomoco as the headquarters of Powhatan, the Algonquian political and spiritual leader when the English founded Jamestown in 1607. For many years, the exact location of the site was unknown; however, in 2003, archeological digs at the site on the York River between Leigh and Bland Creeks confirmed the location. The site has been occupied by Native Americans since 8,000 before the common era (BCE) and is one of the most important Native American sites in the nation.

In 2016, subsequent to the completion …

Shoreline Evolution: City Of Norfolk, Virginia Chesapeake Bay, Elizabeth And Lafayette River Shorelines, Donna A. Milligan, Christine Wilcox, C. Scott Hardaway Jr.

Reports

City of Norfolk is situated along the Chesapeake Bay, Elizabeth and Lafayette Rivers (Figure 1). Because the City’s shoreline is continually changing, determining where the shoreline was in the past, how far and how fast it is moving, and what factors drive shoreline change will help define where the shoreline will be going in the future. These rates and patterns of shore change along Chesapeake Bay’s estuarine shores will differ through time as winds, waves, tides and currents shape and modify coastlines by eroding, transporting and depositing sediments. The purpose of this report is to document how the shore zone …

Enhanced Superconductivity In Aluminum-Based Hyperbolic Metamaterials, Vera N. Smolyaninova, Christopher Jensen, William Zimmerman, (...), M. M. Qazilbash, Et Al.

Arts & Sciences Articles

One of the most important goals of condensed matter physics is materials by design, i.e. the ability to reliably predict and design materials with a set of desired properties. A striking example is the deterministic enhancement of the superconducting properties of materials. Recent experiments have demonstrated that the metamaterial approach is capable of achieving this goal, such as tripling the critical temperature T-C in Al-Al2O3 epsilon near zero (ENZ) core-shell metamaterial superconductors. Here, we demonstrate that an Al/Al2O3 hyperbolic metamaterial geometry is capable of a similar T-C enhancement, while having superior transport and magnetic properties compared to the core-shell metamaterial …

Accomack County, Virginia Shoreline Inventory Report Methods And Guidelines, Marcia Berman, Karinna Nunez, Sharon Killeen, Tamia Rudnicky, Julie Bradshaw, Kory Angstadt, Christine Tombleson, Karen Duhring, Kallie Brown, Jessica Hendricks, David Weiss, Carl Hershner, Comprehensive Coastal Inventory Program

Reports

In the 1970s, the Virginia Institute of Marine Science (VIMS) received a grant through the National Science Foundation’s Research Applied to National Needs Program to develop a series of reports that would describe the condition of tidal shorelines in the Commonwealth of Virginia. These reports became known as the Shoreline Situation Reports. They were published on a locality by locality basis with additional resources provided by the National Oceanic and Atmospheric Administration’s Office of Coastal Zone Management (Hobbs et al., 1975).

The Shoreline Situation Reports quickly became a common desktop reference for nearly all shoreline managers, regulators, and planners within …

Prince George County And The City Of Hopewell, Virginia Shoreline Inventory Report Methods And Guidelines, Marcia Berman, Karinna Nunez, Sharon Killeen, Tamia Rudnicky, Julie Bradshaw, David Stanhope, Karen Duhring, Jessica Hendricks, David Weiss, Carl Hershner

Reports

The 2016 Inventory for Prince George County and the City of Hopewell was generated using on-screen, digitizing techniques in ArcGIS® - ArcMap v10.2.2 while viewing conditions observed in Bing high resolution oblique imagery, Google Earth, and 2013 imagery from the Virginia Base Mapping Program (VBMP). Four GIS shapefiles are developed. The first describes land use and bank conditions (PrinceGeorge_Hopewell _lubc_2016). The second portrays the presence of beaches (PrinceGeorge_Hopewell_beaches_2016). The third reports shoreline structures that are described as arcs or lines (e.g riprap) (PrinceGeorge_Hopewell _sstru_2016). The final shapefile includes all structures that are represented as points (e.g. piers) (PrinceGeorge_Hopewell_astru_2016). The metadata …

Shoreline Evolution: City Of Chesapeake, Virginia Elizabeth River Shorelines Data Summary Report, Donna A. Milligan, Christine Wilcox, C. Scott Hardaway Jr.

Reports

City of Chesapeake is situated between the Cities of Norfolk and Portsmouth along several branches of the Elizabeth River (Figure 1). Because the City's shoreline is continually changing, determining where the shoreline was in the past, how far and how fast it is moving, and what factors drive shoreline change will help define where the shoreline will be going in the future. These rates and patterns of shore change along Chesapeake Bay’s estuarine shores will differ through time as winds, waves, tides and currents shape and modify coastlines by eroding, transporting and depositing sediments.

The purpose of this report is …

Role Of Electron-Electron Interactions In The Charge Dynamics Of Rare-Earth-Doped Cafe2as2, Zhen Xing, T. J. Huffman, Peng Xu, (...), M. M. Qazilbash, Et Al.

Arts & Sciences Articles

We have investigated the charge dynamics and the nature of many-body interactions in La- and Pr-doped CaFe2As2. From the infrared part of the optical conductivity, we discover that the scattering rate of mobile carriers above 200 K exhibits saturation at the Mott-Ioffe-Regel limit of metallic transport. However, the dc resistivity continues to increase with temperature above 200 K due to the loss of Drude spectral weight. The loss of Drude spectral weight with increasing temperature is seen in a wide temperature range in the uncollapsed tetragonal phase, and this spectral weight is recovered at energy scales about one order of …

Line Parameters Including Temperature Dependences Of Air- And Self-Broadened Line Shapes Of (Co2)-C-12-O-16: 2.06-Mu M Region, D. Chris Benner, V. Malathy Devi, Keeyoon Sung, Linda R. Brown, Et Al.

Arts & Sciences Articles

This study reports the results from analyzing a number of high resolution, high signal-to-noise ratio (S/N) spectra in the 2.06-μm spectral region for pure CO2 and mixtures of CO2 in dry air. A multispectrum nonlinear least squares curve fitting technique has been used to retrieve the various spectral line parameters. The dataset includes 27 spectra: ten pure CO2, two 99% 13C-enriched CO2 and fifteen spectra of mixtures of 12C-enriched CO2 in dry air. The spectra were recorded at various gas sample temperatures between 170 and 297 K. The absorption path lengths range from 0.347 to 49 m. The sample pressures …

Copper(I) Oligomers And Polymers With Dicyanobenzene And Cyanopyridine Ligands, Mark K. Broderick, Congqi Yang, Robert D. Pike, Aaron Nicholas, Et Al.

Arts & Sciences Articles

The reaction of [Cu(MeCN)4]BF4 with o-, m-, or p-dicyanobenzene (DCB) or o-, m-, or p-cyanopyridine (CPy) in the presence of two equivalents of PPh3 produces DCB- or CPy-bridged copper(I) complexes. Cyclic dimers are formed for the ortho ligands, and zigzag polymers are formed using the para ligands. m-DCB produces a polymer, however m-CPy results in a cyclic trimer. Multiple lattice-bound solvates are formed upon crystallization of the o-DCB dimer from various solvents. A total of 11 X-ray crystal structures are reported for [Cun(PPh3)2n(bridge)n](BF4)n·(solvent): …

Shoreline Evolution: Prince George County, Virginia Upper Chippokes Creek, James And Appomattox River Shorelines, Donna A. Milligan, Christine Wilcox, C. Scott Hardaway Jr.

Reports

Prince George County is situated between on the James River between Upper Chippokes Creek and the Appomattox Rivers (Figure 1). Because the County’s shoreline is continually changing, determining where the shoreline was in the past, how far and how fast it is moving, and what factors drive shoreline change will help define where the shoreline will be going in the future. These rates and patterns of shore change along Chesapeake Bay’s estuarine shores will differ through time as winds, waves, tides and currents shape and modify coastlines by eroding, transporting and depositing sediments.

The purpose of this report is to …

Sea-Level Rise & Virginia's Coastal Wetlands, Center For Coastal Resources Management, Virginia Institute Of Marine Science

Reports

Rivers & Coast is a periodic publication of the Center for Coastal Resources Management, Virginia Institute of Marine Science. The goal of Rivers & Coast is to keep readers well informed of current scientific understanding behind key environmental issues related to watershed rivers and coastal ecosystems of the Chesapeake Bay.

Alkali Metal Bismuth(Iii) Chloride Double Salts, Andrew W. Kelly, Aaron Nicholas, John C. Ahern, Benny Chan, Howard H. Patterson, Robert D. Pike

Arts & Sciences Articles

Evaporative co-crystallization of MCl (M = Na, K, Rb, Cs) with BiOCl in aqueous HCl produces double salts: MxBiyCl(x+3y)·zH2O. The sodium salt, Na2BiCl5·5H2O (monoclinic P21/c, a = 8.6983(7) Å, b = 21.7779(17) Å, c = 7.1831(6) Å, β = 103.0540(10)°, V = 1325.54(19) Å3, Z = 4) is composed of zigzag chains of μ2-Cl-cis-linked (BiCl5)n2n– chains. Edge-sharing chains of NaCln(OH2)6−n octahedra (n = 0, 2, 3) are linked through μ3-Cl to Bi. The potassium salt, K7Bi3Cl16 (trigonal R−3c, a = 12.7053(9) Å, …

Controlling Excited-State Contamination In Nucleon Matrix Elements, Boram Yoon, Rajan Gupta, (...), Kostas Orginos, Et Al.

Arts & Sciences Articles

We present a detailed analysis of methods to reduce statistical errors and excited-state contamination in the calculation of matrix elements of quark bilinear operators in nucleon states. All the calculations were done on a 2 + 1-flavor ensemble with lattices of size 32(3) x 64 generated using the rational hybrid Monte Carlo algorithm at a = 0.081 fm and with M-pi = 312 MeV. The statistical precision of the data is improved using the all-mode-averaging method. We compare two methods for reducing excited-state contamination: a variational analysis and a 2-state fit to data at multiple values of the source-sink separation …

Integrated Assessment Of Oyster Reef Ecosystem Services: Macrofauna Utilization Of Restored Oyster Reefs, M. Lisa Kellogg, Kennedy T. Paynter, Paige G. Ross, Jennifer C. Dreyer, Cate Turner, Manisha Pant, Alan Birch, Edward Smith

Reports

Within the Harris Creek Oyster Sanctuary in the Maryland portion of Chesapeake Bay, we evaluated relationships between basic oyster reef characteristics and the abundance and biomass of macrofauna. The eight sites selected for these studies included five restored oyster reef sites and three sites suitable for restoration that had not been restored. These sites encompassed a range of oyster biomass density and were spread throughout the sanctuary area. At each site one month prior to each of four sampling periods, divers filled four wire mesh baskets (0.1m2 surface area x 15 cm depth) with material from the site and embedded …

Sea Level Driven Marsh Expansion In A Coupled Model Of Marsh Erosion And Migration, Matthew L. Kirwan, Dc Walters, W. G. Reay, Ja Carr

VIMS Articles

Coastal wetlands are among the most valuable ecosystems on Earth, where ecosystem services such as flood protection depend nonlinearly on wetland size and are threatened by sea level rise and coastal development. Here we propose a simple model of marsh migration into adjacent uplands and couple it with existing models of seaward edge erosion and vertical soil accretion to explore how ecosystem connectivity influences marsh size and response to sea level rise. We find that marsh loss is nearly inevitable where topographic and anthropogenic barriers limit migration. Where unconstrained by barriers, however, rates of marsh migration are much more sensitive …

Virginia Game Fish Tagging Program Annual Report 2015, Susanna Musick, Lewis Gillingham

Reports

Through 2015, the Virginia Game Fish Tagging Program has maintained a 20-year database of records for tagged and recaptured fish. The program is a cooperative project of the Virginia Saltwater Fishing Tournament (under the Virginia Marine Resources Commission-VMRC) and the Virginia Institute of Marine Science (VIMS) of the College of William and Mary (under the VIMS Marine Advisory Program).

Monitoring Relative Abundance Of American Shad And River Herring In Virginia Rivers 2015 Annual Report, Eric J. Hilton, Robert Latour, Patrick E. Mcgrath, Brian Watkins, Ashleigh Magee

Reports

Concern about the decline in landings of American shad (Alosa sapidissima) along the Atlantic coast prompted the development of an interstate fisheries management plan (FMP) under the auspices of the Atlantic States Marine Fisheries Management Program (ASMFC 1999). Legislation enables imposition of federal sanctions on fishing in those states that fail to comply with the FMP. To be in compliance, coastal states are required to implement and maintain fishery-dependent and fishery-independent monitoring programs as specified by the FMP. For Virginia, these requirements include spawning stock assessments, the collection of biological data on the spawning run (e.g., age-structure, sex ratio, and …

A Hydrodynamic-Sediment Transport Numerical Model For The Waipaoa Shelf, New Zealand: Model Archive, Julia Moriarty, Courtney K. Harris, Mark G. Hadfield

Data

No abstract provided.

Turbulent Particle Transport As A Function Of Toroidal Rotation In Diii-D H-Mode Plasmas, X. Wang, Saskia Mordijck, L. Zeng, L. Schmitz, Et Al.

Arts & Sciences Articles

In this paper we show how changes in toroidal rotation, by controlling the injected torque, affect particle transport and confinement. The toroidal rotation is altered using the co- and counter neutral beam injection (NBI) in low collisionality H-mode plasmas on DIII-D (Luxon 2002 Nucl. Fusion 42 614) with dominant electron cyclotron heating (ECH). We find that there is no correlation between the toroidal rotation shear and the inverse density gradient, which is observed on AUG when T-e/T-i is varied using ECH (Angioni et al 2011 Phys. Rev. Lett. 107 215003). In DIII-D, we find that in a discharge with balanced …