Physical Sciences and Mathematics Commons^™

A Structural And Stratigraphic Study Of The A-2 Carbonate In Southwest Michigan And Reservoir Characterization Of An A-2 Carbonate Gas Storage Field, Clayton Joupperi

Masters Theses

The Overisel and Salem gas storage fields of southwest Michigan annually store 34 Bcf of natural working gas in the upper dolomitized portion of the Silurian A-2 Carbonate. Porosity and permeability in these fields is thought to be enhanced by fracturing and dolomitization associated with the dissolution and collapse of underlying salt units. This study utilizes wire-line logs from 383 wells to explore the structural and stratigraphic controls on the deposition and diagenesis of the A-2 Carbonate in southwest Michigan. Core and thin sections from 4 wells serve as the primary data for investigating the depositional and diagenetic history of …

Regional Sulfur Isotope Study Of The Vms Deposits In The Penokean Volcanic Belt, Nicholas M. Moleski

Masters Theses

The Penokean Volcanic Belt (PVB), located in northern Wisconsin and Upper Peninsula, Michigan hosts several volcanogenic massive sulfide deposits (VMS) including the well-known deposits of Flambeau and Crandon. The host rocks of the VMS deposits are Paleoproterozoic in age overlying Archean age basement rocks. This study provides δ³⁴S (VCDT) values for the following deposits within the PVB; (1) Eisenbrey, (2) Schoolhouse, (3) Bend, (4) Flambeau, (5) Reef, (6) Horseshoe, and (7) Back Forty, and explains the distribution of δ³⁴S values in the region.

The study reveals tight ranges of δ³⁴S values for each deposit …

Exploring The Impact Of Pretrained Bidirectional Language Models On Protein Secondary Structure Prediction, Dillon G. Daudert

Masters Theses

Protein secondary structure prediction (PSSP) involves determining the local conformations of the peptide backbone in a folded protein, and is often the first step in resolving a protein's global folded structure. Accurate structure prediction has important implications for understanding protein function and de novo protein design, with progress in recent years being driven by the application of deep learning methods such as convolutional and recurrent neural networks. Language models pretrained on large text corpora have been shown to learn useful representations for feature extraction and transfer learning across problem domains in natural language processing, most notably in instances where the …

Computational Study Of The Nature Of Tetrel Bond, Yama Aman

Masters Theses

For more than a hundred years, the type of a chemical bond has been distinguished according to the relative electronegativities of chemical units at the ends of a bond. Whereas, the bond of unequally electronegative on both ends is called a polar covalent or even ionic bond or a non-polar covalent bond in case of both equal. Regardless the type of bonded elements, the whole idea for the bond was believed to be electron driven only. In the 20th century the development of the idea, that not just the electronic relation but specific elements are also able to characterize the …

Use Of Fluorescein Dye For Characterizing Water And Solute Flux Across The Groundwater – Surface Water Interface, Ryan Nicholas Cascarano

Masters Theses

Quantifying groundwater discharge across the sediment—surface water interface remains a challenge due to streambed heterogeneity and the integration of disparate measurements over a continuum of spatial and temporal scales. In this study, mini-piezometers are first used to identify areas of groundwater discharge in lakes and streams, and micro-pulses of fluorescein dye are released at precisely known shallow depths as a conservative tracer. The use of fluorescein dye allows for visual dye detection regardless of light conditions, and measurements of dye concentrations over time using a fluorometer are used to generate high resolution breakthrough curves. Accurate determination of groundwater velocity and …

An Investigation Of Sub-Meter Skill In Stem And Non-Stem Undergraduate Students, Laura A. Tingin

Masters Theses

This study designed a nationally-relevant, valid, and reliable survey that measures STEM and Non-STEM undergraduate student familiarity with sub-meter metric scale and common sub-meter sized science objects. The instrument assesses scalar relationship and scalar magnitude, as explained by Cheek, LaDue, and Shipley (2017). The instrument development was based on an existing Scale of Objects Questionnaire (SOQ) instrument created by Tretter, Jones, Andre, Negishi, & Minogue (2006a) which was modified to be nationally relevant and in an electronic format in two phases: online survey development and undergraduate pilot testing. Online survey development was framed in the tailored design method described by …

Spatio-Temporal Variability Of Precipitation And Drought In The State Of Arizona, Usa, Samuel Nimako Nyarkoh

Masters Theses

As a result of climate change, several dry regions continue to get drier as precipitation amounts decline. This decline impact water resources and hinder economic development. Understanding the variability of precipitation and drought through climatic, agricultural and hydrological studies is therefore critical to decision makers and stakeholders in developing proactive measures that promotes economic development.

This study therefore uses dataset from 55 Meteorological stations containing 110-year (1900-2010) monthly precipitation data and a series of spatial and temporal tests to investigate the spatial and temporal patterns of precipitation and drought as well as the effects of local factors such as topography …

Synthesis And Characterization Of Fluorescent Nanojars, Vageesha Warnajith Liyana Gunawardana

Masters Theses

Self-assembly is a powerful tool utilized by synthetic chemists to create large, intricate structures for a variety of applications such as drug delivery, adaptable materials and electronics. In contrast to stepwise synthesis, this process allows the formation of intricate molecular architectures starting from synthetically rudimentary building blocks. Nanojars are class of self-assembling, cyclic copper(II) pyrazolate coordination compounds that encapsulate oxoanions with negative two or three charge. The strong anion binding characteristics of nanojars have potential towards developing novel tools for detecting biologically and environmentally relevant anions such as carbonate, sulfate and phosphate.

This work addresses the design and synthesis of …

Application Of Handheld Ed-Xrf For High-Resolution Chemostratigraphy In Texturally Homogeneous Carbonate Mudstones: Salina A-1 Carbonate (Silurian), Michigan Basin, Matthew A. Hemenway

Masters Theses

Handheld energy dispersive x-ray fluorescence spectrometry (ED-XRF) is routinely used to observe elemental variability in fine-grained siliciclastics but has been applied rarely in fine-grained carbonates. Here, ED-XRF chemostratigraphy is utilized in the texturally homogenous, mudstones of the Silurian A-1 Carbonate (A-1C), Michigan Basin. Previous studies on the A-1C focused on the stratigraphic relationship with the underlying Niagaran reefs, so little is known about the geological variability in the basin center. In this study, high-resolution elemental data from nine cores were integrated with petrographic and mineralogical observations to evaluate two hypotheses: (1) Texturally homogeneous, basin-center mudstones in the A-1C have spatially …

Mapping Bedrock Topography Of The Portage And Schoolcraft Nw 7.5’ Quadrangles, Kalamazoo Co. Mi, Using The Hvsr Passive Seismic Method, Benjamin B. Seiderman

Masters Theses

This study utilizes the Horizontal to Vertical Spectral Ratio (HVSR) technique to map bedrock topography in the Portage and Schoolcraft NW quadrangles, Kalamazoo Co., MI, looking for buried bedrock valleys. Glacial sediment-landform assemblages dominate the study area, due to multiple advances of the Laurentide Ice Sheet (LIS). Tunnel valleys, which are one type of buried valley, are eroded by subglacial meltwater and commonly filled with the coarser varieties of glacial outwash, making them potential aquifers. The HVSR technique measures the ratio of horizontal to vertical ground motion, excited by ambient seismic noise, resulting in a peak at the resonance frequency. …

A Survey Of Security And Privacy In Mobile Cloud Computing, Bhuvaneswari Rayapuri

Masters Theses

Cloud Computing is an emerging technology that provides shared processing resources and data to computers and other devices on demand. On the other hand, Mobile Computing allows transmission of data, voice and video. From these two there emerges a new concept Mobile Cloud Computing which not only overcomes the problems of Mobile Computing but also integrates Cloud Computing into Mobile Environments to overcome obstacles related to Performance, Security and Environment. This paper also provides a decent description on Security and Privacy, its related problems, threats and challenges. This paper first provides details on survey of Mobile Cloud Computing, then it …

Determinants Of Household Water Use In The City Of Kalamazoo, Michigan: The Role Of Climate And Socioeconomic Factors, Danielle Molenaar

Masters Theses

Located in the Great Lakes Watershed, the City of Kalamazoo can be considered “water rich”. Therefore, the area has been absent from water use studies. Water use studies are beneficial in all locations; as they can aid city planners, water resource managers, and utility companies. This study examines how household monthly water use in the City of Kalamazoo is impacted by both climate and socioeconomic variables over the period 2006-2016. Household level data were aggregated into census tracts to obtain monthly tract averages for the eleven-year period. Ordinary least squares regression (OLS) was used to determine which variables impact the …

Interannual Variations Of Snowfall In The Lower Peninsula Of Michigan And Impacts Of Local And Remote Meteorological Conditions, Nirjala Koirala

Masters Theses

Inter-annual variation of snowfall and its relation to climate indices will help clarify and improve the prediction of total snowfall in the Lower Peninsula of Michigan (LPM). This study examines the trend and variability of annual snowfall (November- March) using 8 homogeneous weather stations in the LPM. The statistical relationship between snowfall and air temperature, Sea Surface Temperature (SST), North Atlantic Oscillation (NAO), Pacific Decadal Oscillation (PDO) and Maximum Ice Coverage(MIC) of Lake Michigan is calculated. The long-term trend in the snowfall data set from 1950 to 2015 is removed before any statistical correlation analysis is conducted. My analysis suggests …

Organocatalyzed Synthesis Of Epoxides From Chalcones Utilizing Amino Acids, Sabrina N. Kegeler

Masters Theses

The epoxide functional group is important throughout the chemical and pharmaceutical industries, as well as in nature. In the chemical industry, epoxides are present in resins and fragrances. In the pharmaceutical industry, epoxide-containing compounds are used as intermediates in the manufacturing of drugs. In nature, many natural products contain epoxide groups and are used for medicinal purposes, and for models to create synthetic molecules.

One approach to epoxide synthesis involves the use of an alkene precursor, a base, and an oxidizing agent. This is where my investigations began. The first step was to optimize the epoxidation reaction, examining substrate scope, …

Geochemical And Petrological Investigation Of The Prospective Ni-Cu-Pge Mineralization At The Echo Lake Intrusion In The Upper Peninsula Of Michigan, Usa, Alexander J. Koerber

Masters Theses

The Echo Lake Intrusion is located in Houghton and Ontonagon counties in the Upper Peninsula (UP) of Michigan. The intrusion is approximately 200 m below the surface and covers approximately 18 km2 in lateral extent. It is associated with the magmatic activities of a 1.1 Ga geologic event called the Midcontinent Rift. The rift is responsible for the formation of Ni-Cu ± PGE deposits in the Lake Superior Region. Based on its association with the Midcontinent Rift and a Cu and PGE enriched layer, the Echo Lake intrusion is identified as a prospect for an economic magmatic sulfide deposit.

The …

Geologic Mapping Of The Bronson North And Bronson South 7.5-Minute Quadrangles, Branch County, Michigan, Karl John Backhaus

Masters Theses

This study contributes to a better understanding of the glacial history of southwest Michigan through detailed surficial geologic and bedrock topography mapping within the Bronson North and Bronson South Quadrangles in Branch County, Michigan. This project was supported during the summer of 2017 by the USGS EDMAP program in conjunction with the Michigan Geological Survey. Hand-auger borings, grain size analysis tests, passive seismic depth-to-bedrock measurements, and ground penetrating radar transects were collected for this study. There are 350 feet of bedrock relief from west to east across the quadrangles, including a bedrock cuesta of Mississippian Coldwater Shale. This cuesta underlies …