Physical Sciences and Mathematics Commons^™

The Isotope Effect On Proton Conduction And Glass Transition In Phosphoric Acid, Maximilian Ferdinand Heres

Masters Theses

Hydrogen fuel cells combine hydrogen and oxygen to create water and electricity. Polymer electrolyte membranes (PEM) make up barriers within the fuel cell allowing only protons to pass through, while keeping other components separate. Many PEM contain phosphoric acid (PA) as a building block due to its excellent proton conducting properties. Improved ionic conductivity in PEM can lead to the development of better, more efficient fuel cells.

While ionic conductivity in PA at high temperatures is extensively characterized, the low temperature dynamics are not so well explored. Below the glass transition, molecular motion is frozen and proton motion is forced …

Structural Dynamics And Charge Transport In Room Temperature Ionic Liquids, Philip James Griffin

Doctoral Dissertations

Room temperature ionic liquids are an important class of materials due to their chemical tunability and numerous advantageous physicochemical properties. As a result, ionic liquids are currently being investigated for use in a wide array of chemical and electrochemical applications. Despite their great potential, however, the relationship between the chemical structure and physicochemical properties of ionic liquids is not well understood.

To this end, this dissertation presents experimental studies of the reorientational structural dynamics and charge transport properties of a variety of room temperature ionic liquids using quasielastic light scattering spectroscopy and broadband dielectric spectroscopy.

Studies of a series of …