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University of Arkansas, Fayetteville

2002

Articles 1 - 18 of 18

Full-Text Articles in Physical Sciences and Mathematics

Soils Of Mississippi County, Arkansas, J. M. Mckimmey, B. Dixon, H. D. Scott, C. M. Scarlat Nov 2002

Soils Of Mississippi County, Arkansas, J. M. Mckimmey, B. Dixon, H. D. Scott, C. M. Scarlat

Research Reports and Research Bulletins

Along with air and water, soil contributes essential processes to the natural order of global cycles. With the exception of edibles from the sea, virtually everything we, and most other land-based animals, eat is derived from soil. Soil is a storage medium of essential minerals and nutrients for fulfilling our agricultural and nutritional needs. Humans work the soil to provide the basics of food, clothing, and shelter. We also use the soil as a medium to store and discard our waste. Virtually everything we do is in some way connected to soil

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Illinois River 2001 Pollutant Loads At Arkansas Highway 59 Bridge, Marc A. Nelson, Thomas S. Soerens Sep 2002

Illinois River 2001 Pollutant Loads At Arkansas Highway 59 Bridge, Marc A. Nelson, Thomas S. Soerens

Technical Reports

Automatic water samplers and a U. S. Geological Survey gauging station were established in 1995 on the main stem of the Illinois River at the Arkansas Highway 59 Bridge. Since that time, continuous stage and discharge measurements and water quality sampling have been used to determine pollutant concentrations and loads in the Arkansas portion of the Illinois River. This report represents the results from the measurement and sampling for January 1, 2001 to December 31, 2001.

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Illinois River Bmp Implementation & Phosphorus Management, Marc A. Nelson, Keith Trost Jun 2002

Illinois River Bmp Implementation & Phosphorus Management, Marc A. Nelson, Keith Trost

Technical Reports

No abstract provided.

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Pesticide Ground Water Monitoring Project Phase Viii, K. F. Steele, M. A. Nelson, T. Nichols, R. Polite, H. D. Scott, Charles Armstrong May 2002

Pesticide Ground Water Monitoring Project Phase Viii, K. F. Steele, M. A. Nelson, T. Nichols, R. Polite, H. D. Scott, Charles Armstrong

Technical Reports

During Phase VIII monitoring (March 24, 2000 to June 30, 2001 ), 86 samples were collected from 77 new wells and 9 samples were collected from wells with previous detectable herbicide.

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Solid Phase Extraction Of Pesticides With Determination By Gas Chromatography, Anwar A. Bhuiyan, Harry O. Brotherton Jan 2002

Solid Phase Extraction Of Pesticides With Determination By Gas Chromatography, Anwar A. Bhuiyan, Harry O. Brotherton

Journal of the Arkansas Academy of Science

A simple, rapid, and effective method for the extraction of fifteen organochlorine and organophosphorus pesticides based on the use of solid phase Bond Elut C-18 cartridges was studied as an alternative method to those based on extraction with organic solvents. Solid phase extraction is an attractive chromatographic sample preparation technology that reduces analysis time, costs, labor, and solvent consumption relative to traditional liquid/liquid extraction methods. The sample recoveries with the use of solid phase extractions were excellent for most pesticides. Analyte concentration by a factor as great as 1000-fold was achieved readily. The adsorbed pesticides were eluted from the solid …

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Synthesis And Chemistry Of Naphthalene Annulated Trienyl Iron Complexes: Potential Anticancer Dna Alkylation Reagents, Traci Means Jan 2002

Synthesis And Chemistry Of Naphthalene Annulated Trienyl Iron Complexes: Potential Anticancer Dna Alkylation Reagents, Traci Means

Inquiry: The University of Arkansas Undergraduate Research Journal

Iron complex chemistry that opens a new door to the medicinal and pharmaceutical worlds is the aim of this research. Specifically, ortho-quinone methide moieties are intermediates in several antitumor drugs and have been identified as bioreductive alkylators of DNA. In our research, a class of iron compounds has been targeted to resemble these quinone methides. It is hoped that these new compounds could be modified to provide a window of opportunity toward the discovery of a selective mode of drug delivery. We have focused our efforts on generating a reactive transition metal complexed 5-membered ring analog of o-quinone methide based …

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Stimulation And Modeling Of Pond Formations On The Asteroid 433 Eros, Justin Thompson Jan 2002

Stimulation And Modeling Of Pond Formations On The Asteroid 433 Eros, Justin Thompson

Inquiry: The University of Arkansas Undergraduate Research Journal

"Ponds" are surface features that appear to be the result of the deposition of finer material on the asteroid's regolith, the layer of loose sediment that blankets the entire asteroid. Ponds were discovered by the NEAR Shoemaker spacecraft in January, 2001, on the asteroid 433 Eros. The objective of experimentation is to simulate the development of these ponds in the Andromeda planetary sciences environmental chamber. The Andromeda Chamber offers a unique ability to simulate surface environments that occur on Eros. The chamber was used to simulate the processes that occur as Eros emits gas through its outer surface, including the …

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Illinois River Phosphorus Sampling Results And Mass Balance Computation, Marc Nelson, K.L. White, T.S. Soerens Jan 2002

Illinois River Phosphorus Sampling Results And Mass Balance Computation, Marc Nelson, K.L. White, T.S. Soerens

Technical Reports

Phosphorus levels in the Illinois River are of great interest to the people of the States of Arkansas and Oklahoma. A great deal of effort has been expended to ascertain and modify the phosphorus impacts on the river. An automatic water sampling station was installed on the Illinois River just upstream from the State line in 1996 to accurately quantify the phosphorus in the Arkansas portion of the watershed. This paper summarizes five years worth of phosphorus sampling results at that site. In addition, a simple mass balance for phosphorus in the Illinois River Watershed above the sampling station was …

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Land-Use Effects On Soil-Water Retention Characteristic, Naomi Colton, Kristofor Brye Jan 2002

Land-Use Effects On Soil-Water Retention Characteristic, Naomi Colton, Kristofor Brye

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Tillage can negatively affect soil physical properties such as bulk density, organic matter content, and soil hydraulic properties, which in turn affect how plants grow. The objective of this study was to evaluate water retention characteristics of a Jay silt loam soil under cultivated agriculture and native tallgrass prairie in northwest Arkansas. Air-dry soil samples collected from 0-10 cm depth were re-wet with varying amounts of distilled water to create a range of water contents. After overnight equilibration, the water potential was measured on the re-wet soil samples using a dewpoint potentiameter. The relationship between water potential (Ψ) and water …

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Reduction Of Dendrite Formations To Improve The Appearance Of The Powder Cured Films For Automotive Industry, Alexandru S. Biris, C. U. Yurteri, Malay K. Mazumder, Robert A. Sims, P. H. Williams Jan 2002

Reduction Of Dendrite Formations To Improve The Appearance Of The Powder Cured Films For Automotive Industry, Alexandru S. Biris, C. U. Yurteri, Malay K. Mazumder, Robert A. Sims, P. H. Williams

Journal of the Arkansas Academy of Science

The appearance of powder-coated films is dependent upon powder chemistry and spraying parameters. One of the most important physical factors controlling the powder film appearance is the microdeposition of the powder particles on the grounded substrate. During the electrostatic deposition of powder, the formation of dendrites and agglomerates was observed; these formations have an adverse effect on the final film appearance and their elimination may result in smoother and glossier films. Dendrites are generated due to bipolar charging and inter-particulate electrostatic attractive forces. The corona charging technique is mostly used in industrial powder coating applications. At low corona voltages (- …

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Simulation Video Electric Single Particle Aerodynamic Relaxation Time Analyzers, Steve Farmer, Robert A. Sims Jan 2002

Simulation Video Electric Single Particle Aerodynamic Relaxation Time Analyzers, Steve Farmer, Robert A. Sims

Journal of the Arkansas Academy of Science

The simulation of physical parameters provides a virtual environment for the design and optimization of instrumentation. applying physical laws and theorems to natural phenomena defines the behavior of analytical processes. Simulation provides means for the adjustment of specific operating parameters while maintaining the repeatability of constant parameters. The video Electric Single Particle Aerodynamic Relaxation Time Analyzer (VESPART) is an instrument that provides the diameter and charge-to-mass (q/m) ratio of particles. The simulation of the VESPART requires the modeling of the physical environment and application of modeling to simulations. Simulation includes characterization of the various natural forces that "feet particle motion …

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Bedrock Geology Of West Fork Quadrangle, Washington County, Arkansas, Jack T. King, Maria E. King, Stephen K. Boss Jan 2002

Bedrock Geology Of West Fork Quadrangle, Washington County, Arkansas, Jack T. King, Maria E. King, Stephen K. Boss

Journal of the Arkansas Academy of Science

A digital geologic map of West Fork quadrangle was produced at 1:24,000 scale using the geographic information system (GIS) software Maplnfo. Data regarding stratigraphic relations observed in the field were digitized onto the United States Geological Survey (USGS) digital raster graphic (DRG) of West Fork quadrangle. The geology of West Fork quadrangle consists of sedimentary rocks of the Mississippian and Pennsylvanian systems. The Fayetteville Shale and Pitkin Formation represent the Mississippian system. The Hale, Bloyd, and Atoka Formations represent the Pennsylvanian System. Each of these formations consists of members that were mapped at 1:24,000 scale, and this mapping effort represents …

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Electrostatic Microencapsulation Of Composite Particulate Materials For Manufacturing And Environmental Applications, S. De, M. Pritchett, Malay K. Mazumder, Robert A. Sims, C. U. Yurteri, Alexandru S. Biris, A. Rego Jan 2002

Electrostatic Microencapsulation Of Composite Particulate Materials For Manufacturing And Environmental Applications, S. De, M. Pritchett, Malay K. Mazumder, Robert A. Sims, C. U. Yurteri, Alexandru S. Biris, A. Rego

Journal of the Arkansas Academy of Science

Electrostatic microencapsulation is a dry coating process where two powders, one containing the fines and the other relatively larger particles, are separately dispersed in air and pre-charged with opposite polarity, using corona charging for electrostatic coagulation. These oppositely charged core and guest particles experience attractive electrostatic forces and generate composite particles. Preliminary experiments of electrostatic microencapsulation were performed using Anionic Exchange Resin (AG 1-X8) as the host particle and Red Toner (Omega 4000) as the guest particles. An electrostatic microencapsulation tower has been designed for generation of composite particles using particles of different particle size distribution.

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Chemical Composition Of Particles Of D < 0.20 Mu In The Lower Stratospheric Aerosol, Spring 1993, Joseph D. Scott, David M. Chittenden Ii Jan 2002

Chemical Composition Of Particles Of D < 0.20 Mu In The Lower Stratospheric Aerosol, Spring 1993, Joseph D. Scott, David M. Chittenden Ii

Journal of the Arkansas Academy of Science

The majority of the mass of stratospheric aerosol collected during the spring of 1993 consisted principally of particles of d >0.20 mu containing a mixture of H2SO4 and (NaK)2SO4. However, the composition of the more numerous particles with d< 0.2 mu was very different. X-ray emission spectra (EDS) of individual particles indicated that there were three different chemical populations of small particles. The most numerous population was almost all C with only traces of S and Na. The second population contained metal sulfates and chlorides, possibly accreted to a C-containing matrix. The third population consisted of S- and Cl- containing species and trace amounts of Na and K ions. The number of equivalents of metal ion was much less than that of S and Cl species, indicating that most of the S and Cl was not ionic, but was covalently bonded, perhaps to a C matrix.

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Modification Of Surface Properties Of Polymeric Materials, Rajesh Sharma, Robert A. Sims, Malay K. Mazumder Jan 2002

Modification Of Surface Properties Of Polymeric Materials, Rajesh Sharma, Robert A. Sims, Malay K. Mazumder

Journal of the Arkansas Academy of Science

Polymeric materials are successfully used in virtually all industries ranging from semiconductors, and coatings, to household appliances, automotive, and biomedical implants. Polymers generally have excellent bulk physical and chemical properties. However, certain properties of polymers such as low surface energy, low wettability, and high electrical resistivity sometimes limit their applications. Changing the bulk formulation of the polymers can alter some of these properties, but in general this is not acceptable as it can affect "desirable" bulk properties. Surface modification techniques have been used to alter polymer surfaces without affecting the bulk properties of the material. Most polymers have very high …

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Alumina And Synthesis Intermediates Derived From Diethylkaluminum Amide, Benzaldehyde And Water, Stephen E. Hall, Lize Wilcox, William S. Tyree, David A. Lindquist, Malay K. Mazumder Jan 2002

Alumina And Synthesis Intermediates Derived From Diethylkaluminum Amide, Benzaldehyde And Water, Stephen E. Hall, Lize Wilcox, William S. Tyree, David A. Lindquist, Malay K. Mazumder

Journal of the Arkansas Academy of Science

The reaction of diethylaluminum amide [Et2AINH2] with benzaldehyde in toluene produces a solution of ethylaluminoxane polymer [EtAlO] and hydrobenzamide [PhCH=NCH(Ph)N=CHPh]. Alumina then is precipitated by the addition of water. Transition aluminas that may be useful in heterogeneous catalyst applications are obtained after calcining. Details of the chemistry of solution intermediates according to 1H NMR and the properties of the alumina product according to surface area analyses and powder x-ray diffraction are described.

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Revised Bedrock Geology Of War Eagle Quadrangle, Benton County, Arkansas, Robert A. Sullivan, Stephen K. Boss Jan 2002

Revised Bedrock Geology Of War Eagle Quadrangle, Benton County, Arkansas, Robert A. Sullivan, Stephen K. Boss

Journal of the Arkansas Academy of Science

A digital geologic map of War Eagle quadrangle (WEQ) was produced at the 1:24000 scale using the geographic information system (GIS) software ArcView® by digitizing geological contacts onto the United States Geological Survey (USGS) digital raster graphic (DRG). The geology of WEQ consists of sedimentary rocks of Ordovician (Cotter, Powell, and Everton Formations), Devonian (Clifty Formation and Chattanooga Shale), and Mississippian (St. Joe-Boone, Batesville, and Fayetteville Formations) systems. Impoundment of Beaver Lake in 1966 inundated most Ordovician rocks cropping out in WEQ, but all three formations were present in isolated outcrops along the present shoreline of the lake. The St. …

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Quantification Of Land-Use Impact On Stream Water Quality, Scott Dennis, Indrajeet Chaubey, Brian Haggard Jan 2002

Quantification Of Land-Use Impact On Stream Water Quality, Scott Dennis, Indrajeet Chaubey, Brian Haggard

Discovery, The Student Journal of Dale Bumpers College of Agricultural, Food and Life Sciences

Accelerated eutrophication of Beaver Lake in northwest Arkansas is a major environmental concern. When developing watershed-management plans to protect lake water quality, it is important that linkages among land-use activities and water quality of tributary streams be quantified. This study assessed longitudinal base-flow and storm-flow water quality at War Eagle Creek and quantified linkages between stream water quality and land-use conditions within the War Eagle Creek sub-watershed of the Beaver Lake watershed. We collected six water samples: three from base-flow conditions and three from storm-flow conditions during Spring 2002. In general, concentrations of nitrate nitrogen (NO3-N), total N (TN), total …

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