Physical Sciences and Mathematics Commons^™

Electronic Effect Of Platinum Alloy Catalysts On Olefin Hydrogenation Kinetics, Colin Reedy, Jeff Miller, Stephen Purdy

The Summer Undergraduate Research Fellowship (SURF) Symposium

Dehydrogenation of alkanes is the first step in transforming light hydrocarbons into liquid fuels and chemicals. This process has traditionally used platinum alloys as catalysts. Alloys are used industrially because they have a greater selectivity than monometallic platinum. Alloying platinum with an inactive promoter modifies the crystalline structure of the surface (geometric effect), and the 5d electrons in platinum responsible for chemistry (electronic effect); both have been suggested to be primarily responsible for dehydrogenation selectivity in platinum alloys. Alloy catalysts have been synthesized using early 3d transition metal promoters with the same Pt₃M crystal structure. X-Ray Absorption Spectroscopy …

Raman Spectroscopy Of Oxygen Evolution Catalysts And Psii Manganese Model Compounds, Sergei Shmakov, Daniel A. Hartzler, Alireza Karbakhsh Ravari, Yulia Pushkar

The Summer Undergraduate Research Fellowship (SURF) Symposium

Photosynthesis is the basis of life on earth, and oxygen evolution catalysts are key components of this complicated, yet not fully understood process. Photosystem II, a large membrane bound pigment-protein complex, is the key system that facilitates oxygenic photosynthesis via the oxygen evolving complex (a natural oxygen evolving catalyst). It is a key component in oxygen producing catalysts, which can be used in fields such as energy production and biomimetic catalysts. The oxygen evolution cycle, or Kok cycle going within it is still not studied completely. In this project, we were studying the vibrational (and structural) state of a Manganese …

Development Of A Novel Polymer-Garnet Solid State Composite Electrolyte Incorporating Li-La-Zr-Bi-O And Polyethylene Oxide, Muhammed Ramazan Oduncu

Open Access Theses

Current lithium ion batteries are comprised of organic liquid electrolytes - a mixture of lithium salts and binary solvents such as ethylene carbonate (EC) and dimethyl carbonate (DMC). The main drawbacks of this liquid mixture related to safety are flammability of the organic solvents and chemical instability with the electrode materials. To date, various ceramic and polymer materials have been considered which overcome safety issues. However, a common problem of these solid state materials is that they are not able to provide high ionic conductivity at ambient temperatures. Garnet-type cubic Li7La 3Zr2O12 ceramic material has attracted much interest because of …

How Effective Is Group Feedback In Encouraging Occupants Of An Office Building To Reduce Energy Consumption?, Ushik D. Shah

Open Access Theses

Lighting contributes to a high percentage of the total energy use in office buildings. The lack of financial incentive often dissuades office workers from trying to save electricity at their work place. This thesis aims at reducing the total power consumed by an office building by using persuasive technologies on the occupants to promote environmentally conscious and energy saving behavior. ^ A three week field study was conducted by providing occupants of an office building feedback about their energy consumption along with messages to encourage them to save energy. Feedback was provided via television screens and flyers placed strategically at …

Energy Conservation And Efficiency In Manufacturing: Employee Decisions And Actions, Marla Dee Corson

Open Access Dissertations

Energy conservation and intensity reduction efforts are becoming increasingly more prevalent and ultimately necessary, especially for energy-intensive manufacturing companies in particular to stay in business. Typical actions are to change technology, and thus, realize an energy cost savings in overall utilities. However, in today's competitive market, with climate change and other environmental impacts as well, it is necessary for the cost of energy to be valued as a cost of making a product, and thus, managed at the same level as the cost of labor or materials. This research assessed human behavior at the individual and organizational levels both at …

Waste Heat Recovery Options In A Large Gas-Turbine Combined Power Plant, Ularee Upathumchard

Open Access Theses

This study focuses on power plant heat loss and how to utilize the waste heat in energy recovery systems in order to increase the overall power plant efficiency. The case study of this research is a 700-MW natural gas combined cycle power plant, located in a suburban area of Thailand. An analysis of the heat loss of the combustion process, power generation process, lubrication system, and cooling system has been conducted to evaluate waste heat recovery options. The design of the waste heat recovery options depends to the amount of heat loss from each system and its temperature. Feasible waste …

Cztsse Thin Film Solar Cells : Surface Treatments, Chinmay S. Joglekar

Open Access Theses

Chalcopyrite semiconducting materials, specifically CZTS, are a promising alternative to traditional silicon solar cell technology. Because of the high absorption coefficient; films of the order of 1 micrometer thickness are sufficient for the fabrication of solar cells. Liquid based synthesis methods are advantageous because they are easily scalable using the roll to roll manufacturing techniques.

Various treatments are explored in this study to enhance the performance of the selenized CZTS film based solar cells. Thiourea can be used as a sulfur source and can be used to tune band gap of CZTSSe. Bromine etching can be used to manipulate the …

Solar Cell Temperature Dependent Efficiency And Very High Temperature Efficiency Limits, John Robert Wilcox

Open Access Dissertations

Clean renewable solar energy is and will continue to be a critically important source of electrical energy. Solar energy has the potential of meeting all of the world's energy needs, and has seen substantial growth in recent years. Solar cells can convert sun light directly into electrical energy, and much progress has been made in making them less expensive and more efficient. Solar cells are often characterized and modeled at 25 °C, which is significantly lower than their peak operating temperature. In some thermal concentrating systems, solar cells operate above 300 °C. Since increasing the temperature drastically affects the terminal …

Role Of Natural Gas In America's Energy Future: Focus On Transportation, Dharik Mallapragada, Rakesh Agrawal

Purdue Policy Research Institute (PPRI) Policy Briefs

The energy landscape of the United States for the past century has been dominated by the use of fossil fuels namely coal, petroleum, and natural gas (NG). While coal usage was dominant during the early 1900’s, petroleum has been dominant ever since the second half of the 20^th century owing to increasing use of liquid fuels, gasoline and diesel, for transportation. In contrast, NG consumption in the U.S., currently at ~25% of total primary energy use, has only been steadily increasing since the early 1990’s (BP, 2012). However, the last decade has seen rapid growth in U.S. NG consumption …

Energy Independence In The Usa, Janice Ringler

Student Papers in Public Policy

During President Barack Obama’s first term and throughout the recent presidential campaign, there was much discussion about becoming energy-independent as a nation. Indeed, one of the most pressing issues facing the country today is our energy future. This is especially a concern in areas where mainstream energy sources (coal, gas, oil) do not exist, and thus must be imported. Many believe that this is a problem that communities and states are better suited to tackle than the federal government due to the flexibility and knowledge of state policy initiatives. In this brief I will propose a variety of measures that …