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Full-Text Articles in Physical Sciences and Mathematics
Mass Spectrometric Characterization Of Remotely Charged Amino Acids And Peptides, Damodar Koirala
Mass Spectrometric Characterization Of Remotely Charged Amino Acids And Peptides, Damodar Koirala
Open Access Dissertations
Ion–molecule reactions in a flowing afterglow are used to examine the electronic structure of 3- and 4-pyridinylnitrene-n-oxide radical anions. Reactions with nitric oxide are generally similar to those reported previously for other aromatic nitrene radical anions. In particular, phenoxide formation by nitrogen–oxygen exchange is observed with both isomers. Oxygen atom abstraction by NO is also observed with both isomers. Very significant differences in the reactivity are observed in the reactions of the two isomers with carbon disulfide. The reactivity of the 3-noxide isomer with CS2 is similar to that observed previously for nitrene radical anions, and reactions of the n-oxide …
Data Driven Low-Bandwidth Intelligent Control Of A Jet Engine Combustor, Nathan L. Toner
Data Driven Low-Bandwidth Intelligent Control Of A Jet Engine Combustor, Nathan L. Toner
Open Access Dissertations
This thesis introduces a low-bandwidth control architecture for navigating the input space of an un-modeled combustor system between desired operating conditions while avoiding regions of instability and blow-out. An experimental procedure is discussed for identifying regions of instability and gathering sufficient data to build a data-driven model of the system's operating modes. Regions of instability and blow-out are identified experimentally and a data-driven operating point classifier is designed. This classifier acts as a map of the operating space of the combustor, indicating regions in which the flame is in a "good" or "bad" operating mode. A data-driven predictor is also …