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Full-Text Articles in Physical Sciences and Mathematics

Condensation Coefficient Measurement For Water In The Umr Cloud Simulation Chamber, Donald E. Hagen, John L. Schmitt, Max B. Trueblood, John C. Carstens, Daniel R. White, Darryl J. Alofs Mar 1989

Condensation Coefficient Measurement For Water In The Umr Cloud Simulation Chamber, Donald E. Hagen, John L. Schmitt, Max B. Trueblood, John C. Carstens, Daniel R. White, Darryl J. Alofs

Physics Faculty Research & Creative Works

A systematic series of condensation coefficient measurements of water have been made using the University of Missouri-Rolla cooled-wall expansion chamber which simulates the thermodynamics of cloud. This coefficient is seen to decrease from a value near unity, at the outset of simulation, to a value in the neighborhood of 0.01 toward the end of a simulation. Final values of this coefficient are sufficiently low as to contribute significantly to the broadening of the drop-size distribution in cloud.


Measured Spectra Of The Hygroscopic Fraction Of Atmospheric Aerosol Particles, Darryl J. Alofs, Donald E. Hagen, Max B. Trueblood Feb 1989

Measured Spectra Of The Hygroscopic Fraction Of Atmospheric Aerosol Particles, Darryl J. Alofs, Donald E. Hagen, Max B. Trueblood

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The relation between dry diameter (X0) and critical supersaturation (Sc) for atmospheric submicron aerosol particles is investigated using a long term air sampling program at Rolla, Missouri. The particles are passed through an electrostatic aerosol size classifier, and then through an isothermal haze chamber. Results are reported in terms of an apparent volume fraction of soluble material, εv defined such that for particles composed only of ammonium sulfate and water insoluble compounds, εv is the actual volume fraction of soluble material. The probability distribution of εv is found to be approximately Gaussian in …


Measured Spectra Of The Hygroscopic Fraction Of Atmospheric Aerosol Particles, Darryl J. Alofs, Donald E. Hagen, Max B. Trueblood Jan 1989

Measured Spectra Of The Hygroscopic Fraction Of Atmospheric Aerosol Particles, Darryl J. Alofs, Donald E. Hagen, Max B. Trueblood

Mechanical and Aerospace Engineering Faculty Research & Creative Works

The Relation between Dry Diameter (Xo) and Critical Supersaturation (Sc) for Atmospheric Submicron Aerosol Particles is Investigated. the Particles Are Passed through an Electrostatic Aerosol Size Classifier, and Then through an Isothermal Haze Chamber. Results Are Reported in Terms of an Apparent Volume Fraction of Soluble Material, Εv, Defined Such that for Particles Composed Only of Ammonium Sulfate and Water Insoluble Compounds, Εv is the Actual Volume Fraction of Soluble Material. the Probability Distribution of Εv is Found to Be Approximately Gaussian in the Εv Range 0.2 to 1.3. the Mean Εv is 0.5, for Electrostatic Aerosol Classifier Settings of …


Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3 Nonstoichiometry And Defect Structure, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin Jan 1989

Oxidation-Reduction Behavior Of Undoped And Sr-Doped Lamno3 Nonstoichiometry And Defect Structure, J. H. Kuo, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Undoped and Sr-doped LaMnO3 showed reversible oxidation-reduction behavior. These perovskites can be excess, stoichiometric or deficient in oxygen content depending on the specific conditions. Under very reducing conditions decomposition into new phases occurs. Phase stabilities for these oxides were determined. The results showed that Sr doping caused the LaMnO3 to dissociate at higher oxygen activities than those necessary for undoped LaMnO3. Defect models are proposed to interpret the thermogravimetric results in which metal vacancies are assumed for the oxygen excess condition and oxygen vacancies are assumed for the oxygen deficient condition. Thermodynamic properties were calculated which …


High-Temperature Defect Structure Of Nb-Doped Lacro3, Chikung J. Yu, Harlan U. Anderson, Don M. Sparlin Jan 1989

High-Temperature Defect Structure Of Nb-Doped Lacro3, Chikung J. Yu, Harlan U. Anderson, Don M. Sparlin

Materials Science and Engineering Faculty Research & Creative Works

Electrical conductivity and Seebeck measurements on LaCr0.98Nb0.02CrO3 show that the defect structure of the material is mainly controlled by the extrinsic electrons formed by the Nb donors through the electronic compensation process. The experimental results also indicate that this material conducts electricity via a small polaron mechanism with an electron mobility around 0.004-0.01 cm2/V sec between 1100 and 1300°C. © 1989.