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Full-Text Articles in Physical Sciences and Mathematics

Mössbauer-Effect Studies Of The Phase Transitions In Antiferroelectric Pbzro₃ And Ferroelectric Pbti₀.₀₂Zr₀.₈O₃, James P. Canner, C. M. Yagnik, Robert Gerson, William Joseph James Nov 1971

Mössbauer-Effect Studies Of The Phase Transitions In Antiferroelectric Pbzro₃ And Ferroelectric Pbti₀.₀₂Zr₀.₈O₃, James P. Canner, C. M. Yagnik, Robert Gerson, William Joseph James

Physics Faculty Research & Creative Works

The Mössbauer spectra were studied for the antiferroelectric compound PbZrO3 and for the closely related ferroelectric PbTi0.2Zr0.8O3. In both cases, a substitution of 5-mol% BiFeO3 was made to permit the Mössbauer measurements. Little difference was found in the isomer shift in these compounds, whether they were in the ferroelectric, antiferroelectric, or cubic state, indicating that the bonding character is not affected by the transitions among the states. There was a pronounced and approximately equivalent dip in the recoil-free fraction at the Curie points of both the antiferroelectric and ferroelectric materials, associated with …


Excitation Of The 2s State Of Atomic Hydrogen By Electron Impact In The Distorted-Wave Approximation - Angular Distributions, W. Neil Shelton, E. S. Leherissey, Don H. Madison Jan 1971

Excitation Of The 2s State Of Atomic Hydrogen By Electron Impact In The Distorted-Wave Approximation - Angular Distributions, W. Neil Shelton, E. S. Leherissey, Don H. Madison

Physics Faculty Research & Creative Works

The excitation of ground-state hydrogen atoms to the 2s state by the impact of electrons with energies of 1 to 50 Ry (13.6 to 680.3 eV) has been calculated in the distorted-wave approximation with exchange included. The angular distributions of the scattered electrons at 1 and 4 Ry are compared with those derived from the close-coupling calculations by Burke, Schey, and Smith, and are compared with four different plane-wave theories at all energies calculated. Taking the close-coupling results as a standard, it is found that the distorted-wave angular distributions represent an improvement over those of the plane-wave theories.


Electron-Impact Excitation Of Auto-Ionizing Levels In Cesium, Yu Bong Hahn, Kaare J. Nygaard Jan 1971

Electron-Impact Excitation Of Auto-Ionizing Levels In Cesium, Yu Bong Hahn, Kaare J. Nygaard

Physics Faculty Research & Creative Works

Auto-ionizing states in Cs between 12 and 20 eV have been studied by electron impact. The retarding-potential-difference method was used to obtain an electron beam with energy spread of about 0.1 eV. To determine the threshold energies, inelastically scattered electrons were analyzed by the trapped-electron method. We have been able to identify about 20 levels, and the agreement with spectroscopic data is excellent. A peak appearing at 12.80 eV is probably due to the quartet states observed by Feldman and Novick. © 1971 The American Physical Society.


Surface Plasmons And The Reflectivity Of N-Type Insb, William E. Anderson, Ralph William Alexander, Robert John Bell Jan 1971

Surface Plasmons And The Reflectivity Of N-Type Insb, William E. Anderson, Ralph William Alexander, Robert John Bell

Physics Faculty Research & Creative Works

The Reflectivity of N-Type InSb Has Been Measured in the Far Infrared. the Doping of the Samples Was Such that the Free-Carrier Plasma Frequency Was Near the LO Mode Frequency. the Results Suggest that Samples with a Sufficiently Thick Damage Layer Show Effects Due to Surface Plasmons. Use of a Simple Model Indicates that the Surface-Plasma Excitations Are Coupled to the Phonons. © 1971 the American Physical Society.


Theory Of Nucleation Of Water Properties Of Some Clathrate Like Cluster Structures, Mehdi Daee Jan 1971

Theory Of Nucleation Of Water Properties Of Some Clathrate Like Cluster Structures, Mehdi Daee

Doctoral Dissertations

"The tranquility of classical homogeneous nucleation theory has been disturbed by the introduction of statistical mechanical correction factors to a basically thermodynamic theory. These factors, which appear to be essential, destroy much of the agreement with experiment in the case of water vapor. A molecular model for the pre-nucleation water clusters is proposed with a view toward resolving some of these difficulties. As a first step, the Properties of a few specific cluster configurations have been examined. Clathrate-like structures containing 16 to 57 water molecules are discussed. The hydrogen bonds were treated as simple harmonic oscillators for the purpose of …


Thermal Expansivity And Refractive Index Determinations For Some Hydrosol Systems And Their Similarity To Properties Ascribed To "Anomalous" Water, Gerald Wayne Chappue Jan 1971

Thermal Expansivity And Refractive Index Determinations For Some Hydrosol Systems And Their Similarity To Properties Ascribed To "Anomalous" Water, Gerald Wayne Chappue

Masters Theses

"The characteristic thermal expansion and refractive index of aqueous dispersions of SiO₂ and NaOH were determined for samples contained in quartz micro-capillaries. Comparison is made with the expansivity and refractive properties of anomalous water or polywater as reported by other investigators. The similarity between the properties and behavior of various hydrosol systems and those ascribed to anomalous water is cited as a serious challenge to the hypothesized existence of an allotropic modification of water"--Abstract, page ii.


Absolute Excitation Cross Sections Of He+ In 20-100-Kev He+-He Collisions Using Energy-Loss Spectrometry, D. R. Schoonover, John T. Park Jan 1971

Absolute Excitation Cross Sections Of He+ In 20-100-Kev He+-He Collisions Using Energy-Loss Spectrometry, D. R. Schoonover, John T. Park

Physics Faculty Research & Creative Works

Application of positive-ion energy-loss spectrometry has been extended to include experimental determination of absolute excitation cross sections of ground-state helium ions. Helium ion-atom collisions were studied for impact energies ranging between 20-100 keV, in 10-keV intervals. The data were taken with an apparatus resolution between 0.6-0.8 eV full width at half-maximum (FWHM). Cross sections for transitions from ground state to the second and third principal quantum levels of the ion plotted as a function of impact energy were still rapidly increasing at 100 keV. The cross sections at this energy were (1.64 ± 0.28) x 10-18 cm2 for He+(1s122)→He+ (n=2) …


Absolute Cross Sections For Excitation Of Neon By Impact Of 20-180 Kev H , H₂ And He Ions, George William York Jan 1971

Absolute Cross Sections For Excitation Of Neon By Impact Of 20-180 Kev H , H₂ And He Ions, George William York

Doctoral Dissertations

"The technique of heavy-ion energy-loss spectrometry has been used to measure excitation cross sections for the (2p⁵)3s and (2p⁵)3p electronic configurations of Neon. The incident particles used were H⁺ , H⁺₂ and He⁺ at impact energies from 20-180 keV. The results are compared with previous optical measurements of the emission cross sections of lines from these levels as excited by H⁺ and He⁺ impact. Agreement is not good, either in shape or in absolute magnitude for excitation of the (2p⁵)3s configuration. However, agreement is surprisingly good for excitation of the (2p⁵)3p configuration. A curve fitting technique has been applied to …


Homogeneous Nucleation Of Water Vapor In Inert Gas Atmospheres, Arthur Henry Biermann Jan 1971

Homogeneous Nucleation Of Water Vapor In Inert Gas Atmospheres, Arthur Henry Biermann

Doctoral Dissertations

"The homogeneous nucleation of water vapor in atmospheres of helium, neon, argon, krypton, and xenon was studied using an expansion type cloud chamber. A strong dependence of the nucleation rate on the particular inert carrier gas was observed. At present the only dependence upon the nature of the carrier gas included in classical nucleation theories is a small factor arising from kinetic considerations which is in the wrong direction to explain the observations. To explain the dependence of the rate on the nature of the carrier gas, a molecular cluster model is assumed allowing inert gas atoms to occupy the …


Calculation Of Anisotropic Hyperfine Constants For Lattice Nuclei Near A Shallow Donor, Edward B. (Boyd) Hale, Robert Lee Mieher Jan 1971

Calculation Of Anisotropic Hyperfine Constants For Lattice Nuclei Near A Shallow Donor, Edward B. (Boyd) Hale, Robert Lee Mieher

Physics Faculty Research & Creative Works

A method is presented for calculating the magnetic anisotropic (dipolar) hyperfine constants for lattice nuclei near a shallow-donor impurity. The method assumes that the wave function of the donor electron can be expressed in an effective-mass form, i.e., a slowly varying envelope function times conduction-band Bloch functions. For each dipolar hyperfine constant, two separate calculations are performed. One calculation is for a local region about the lattice nucleus of interest. The greatest part of the interaction occurs in this region (about 85 ± 10%). The second calculation is for the more distant region. The dipolar constants in the distant region …


Magnetostriction And Magnetic Breakdown In Cadmium, J. M. Carter, Don M. Sparlin Jan 1971

Magnetostriction And Magnetic Breakdown In Cadmium, J. M. Carter, Don M. Sparlin

Physics Faculty Research & Creative Works

Studies of the monotonic magnetostriction of cadmium at 4.2 °K in applied magnetic fields to 70 kG have shown that the angular variation of an extremal point Hm is proportional to secθ. The magnitude of Hm is in close agreement with the onset of a breakdown orbit γ13 observed for the applied field within 35 °of the c axis. The range of observation of Hm coincides with the range of the orbit γ. © 1971 The American Physical Society.


Second- And Third-Order Elastic Constants Of Aluminum And Lead, Tetsuro Suzuki Jan 1971

Second- And Third-Order Elastic Constants Of Aluminum And Lead, Tetsuro Suzuki

Physics Faculty Research & Creative Works

The second- and third-order elastic constants of Al and Pb are calculated as the second and third derivatives of the binding energy with respect to the finite deformation parameter. The binding energy is derived from a local pseudopotential by use of second-order perturbation theory. It is shown that the binding energy satisfied not only the diagonal equilibrium condition, but also the off-diagonal equilibrium condition, i.e., the first derivative of the binding energy with respect to a volume change as well as with respect to shear deformations is zero. Accordingly, the present method of calculation is based on a stable lattice …


Scattering Of Waves In Many Dimensions, I. Adawi Jan 1971

Scattering Of Waves In Many Dimensions, I. Adawi

Physics Faculty Research & Creative Works

Scattering by a spherical potential is discussed in all dimensions by one formulation using the partial-wave expansion method. The optical theorem relating the total scattering cross section σ to the forward scattering amplitude f(0) is derived.


Experimental And Theoretical Study Of The Sign Preference In The Nucleation Of Water Vapor, Daniel R. White, James L. Kassner Jan 1971

Experimental And Theoretical Study Of The Sign Preference In The Nucleation Of Water Vapor, Daniel R. White, James L. Kassner

Physics Faculty Research & Creative Works

The nucleation of water vapor on ions in atmospheres of helium and argon was studied using an expansion type cloud chamber. Separation of the positive and negative ions was achieved so that the nucleation could be studied as a function of both the sign of the ionic charge and the supersaturation. A semiphenominological theory was developed as an extension of the classical liquid drop theory to include the effects of the ionic charge on the nucleation process. The theoretical model of the prenucleation embryo was assumed to possess an oriented dipole surface layer with the direction of orientation dependent on …


Collision Cross Sections For The Excitation Of The Schumann-Runge Dissociation Continuum In Molecular Oxygen By 20-110-Kev Protons, John T. Park, F. D. Schowengerdt, D. R. Schoonover Jan 1971

Collision Cross Sections For The Excitation Of The Schumann-Runge Dissociation Continuum In Molecular Oxygen By 20-110-Kev Protons, John T. Park, F. D. Schowengerdt, D. R. Schoonover

Physics Faculty Research & Creative Works

Absolute cross sections for the excitation of the Schumann-Runge dissociation continuum of molecular oxygen have been obtained from inelastic energy-loss spectra induced by 20-110-keV protons incident on gaseous targets of molecular oxygen. Apparent differential energy loss cross sections, ionization cross sections, and total inelastic cross sections are also obtained from the energy-loss spectra. The proton energy-loss spectra have an energy resolution of about 2 eV. The energy location of the first peak in the energy-loss spectra of O2 is in general agreement with the findings of photo absorption and electron energy-loss-spectra measurements. The cross section for the Schumann-Runge dissociation continuum …


Heisenberg Ferromagnet With Biquadratic Exchange, Harry A. Brown Jan 1971

Heisenberg Ferromagnet With Biquadratic Exchange, Harry A. Brown

Physics Faculty Research & Creative Works

The usual Heisenberg Hamiltonian with bilinear exchange -2JS→1•S→2 has been extended to include a biquadratic term -2αJ(S→1•S→2)2, with an adjustable parameter α. A method equivalent to constant coupling was employed to calculate the effect of the biquadratic exchange term on the Curie temperature, magnetization, susceptibility, specific heat, and entropy for lattices with spin-1 atoms. As α goes from 0 to 1, the Curie temperature falls by a factor 2 to 3, while the asymptotic Curie temperature is reduced by the factor 2. The magnetization rises much more rapidly below TC, and the specific heat has a peak and discontinuity several …


X-Ray And Mössbauer Spectroscopy Studies Of The Silicon-Antimony And Bismuth-Antimony Alloys, James Ralph Teague Jan 1971

X-Ray And Mössbauer Spectroscopy Studies Of The Silicon-Antimony And Bismuth-Antimony Alloys, James Ralph Teague

Doctoral Dissertations

"X-ray and Mossbauer spectroscopy were used to investigate two antimony alloys, Bi-Sb and Si-Sb, showing semiconductorsemimetallic transitions or vice versa, depending on the antimony concentration in the host lattice. Resistivity and density measurements were found to be helpful in the analysis of the results. X-ray studies for dislocation-free antimony-doped silicon showed that the lattice constant of the alloy increased as the antimony concentration increased from 10¹⁸ to 10¹⁹ Sb atoms/cc. Rather good agreement was found between theoretical and experimental changes in lattice constant for dislocation-free silicon. Mössbauer studies showed that the isomer shift decreased linearly with increasing antimony concentration, which …


Surface Plasmon-Longitudinal Optical Phonon Contribution To The Reflectivity Of N-Type Insb, William Eugene Anderson Jan 1971

Surface Plasmon-Longitudinal Optical Phonon Contribution To The Reflectivity Of N-Type Insb, William Eugene Anderson

Doctoral Dissertations

"The reflectivity of n-type InSb has been measured in the far infrared. The doping of the samples was such that the free-carrier plasma frequency was near the longitudinal optical phonon frequency. The results suggest that samples with a sufficiently thick damage layer show effects due to surface plasmons. The results also indicate that the surface plasma excitations are coupled to the phonons. A simple model of this coupling is presented which agrees qualitatively with the observed reflectivity. A somewhat more rigorous theory of the coupling is also presented"--Abstract, page ii.


Photoionization Of Photoexcited Cesium, Robert E. Hebner Jan 1971

Photoionization Of Photoexcited Cesium, Robert E. Hebner

Doctoral Dissertations

"A new method for obtaining the cross section for photoionization of photoexcited cesium is presented. The salient feature of this experiment is to use three crossed beams, i.e., two light beams intersecting a beam of cesium atoms. The cross section is determined by counting the ions produced by the two step process: Cs (6S) + h[upsilon]₁ --> Cs (6P) ; Cs (6P) + [upsilon]₂ --> Cs⁺ + e⁻ The relative cross section for the second step has been obtained from threshold (5060 Å) to 2500 Å. The excitation light source used in obtaining this cross section was a rf resonance …


Mössbauer Studies Of Bifeo₃-Pbtio₃ Perovskite-Type Solid Solutions, C. M. Yagnik, Robert Gerson, William Joseph James Jan 1971

Mössbauer Studies Of Bifeo₃-Pbtio₃ Perovskite-Type Solid Solutions, C. M. Yagnik, Robert Gerson, William Joseph James

Physics Faculty Research & Creative Works

The Mössbauer spectra of the ferroelectric solid solutions (BiFeO3)x(PbTiO)1-x have been studied as a function of temperature, mainly between room temperature and 600°C, using 57Fe in the solutions as an absorber. The quadrupole splitting increased and the isomer shift decreased between x = 0.05 and x = 0.70, a range in which the solutions are tetragonal and paramagnetic, and in which the unit cell volume increases with increasing x. The isomer shift, in particular, was primarily determined by the unit cell volume. Data are presented on the internal magnetic field of the antiferromagnetic …