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Full-Text Articles in Physical Sciences and Mathematics

The Application Of Laser Intracavity Absorption Detector To Gas Chromatography Of Trace Organic Pollutants In Water, Robert B. Green Dec 1982

The Application Of Laser Intracavity Absorption Detector To Gas Chromatography Of Trace Organic Pollutants In Water, Robert B. Green

Technical Reports

A helium-neon (HeNe) laser operating simultaneously at 3.39 um (infrared) and 0.63 um (visible) has been used as a selective detector for hydrocarbons in the effluent of a gas chromatograph. The infrared and visible laser transitions originate at the same energy level and are competitive. When a hydrocarbon enters the laser's resonant cavity, the 3.39 um energy is absorbed due to the C-H stretching vibration and the visible emission is enhanced. The visible laser emission is monitored with a photodiode as a quantitative measure of the concentration of the absorbing molecule. The minimum detectable concentration for propane using the double-beam …


A Faunal And Seasonal Study Of The Aquatic Insects In Two Water Ecosystems In South Arkansas: Degray Reservoir And The Upper Cadda River, Robert T. Allen Oct 1982

A Faunal And Seasonal Study Of The Aquatic Insects In Two Water Ecosystems In South Arkansas: Degray Reservoir And The Upper Cadda River, Robert T. Allen

Technical Reports

The impounding of the lower Caddo River to create DeGray Reservoir radically changed the water habitats in that portion of the Caddo River. A number of new and different habitats were created by the lake. The objective of this study was to determine what, if any, differences existed between the aquatic insect biotas of DeGray Reservoir and the upper Caddo River. Four collecting stations along the shore of DeGray Reservoir and four stations along the upper Caddo River were selected as sampling sites. Collections were made at one month (March, April, Oct., Nov.) intervals or at two week intervals (May, …


Effects Of Water On The Fate Of Herbicides In Irrigated Soils, Terry L. Lavy Aug 1982

Effects Of Water On The Fate Of Herbicides In Irrigated Soils, Terry L. Lavy

Technical Reports

The wide use of soil-applied herbicides necessitates an understanding of their fate in soil if we are to use them in the most beneficial manner. All herbicides have some degree of water solubility and the field performance of many are dependent on ample, timely availability of soil moisture. It is important that different aspects of soil-herbicide-water interactions be thoroughly investigated. An excess use of water for irrigation purposes can result in the downward movement of herbicides in the soil profile. Subsoils are less adsorptive and a decreased degradation potential exists when herbicides move below the top 15 cm. In sandy …


Atrazine Degradation, Sorption And Bioconcentration In Water Systems, Duane C. Wolf, Ramon L. Jackson Aug 1982

Atrazine Degradation, Sorption And Bioconcentration In Water Systems, Duane C. Wolf, Ramon L. Jackson

Technical Reports

The herbicide atrazine is used extensively to control broadleaf and grass weeds in such crops as sorghum and corn. A small portion of the atrazine may be lost from the area of application by surface runoff and could enter a stream or lake. The objective of this study was to evaluate atrazine degradation, sorption, and bioconcentration in watersediment systems. The results indicated that sediments with lower pH values and higher organic matter levels adsorbed higher levels of atrazine than sediments with neutral pH values and lower organic matter levels. Microbial decomposition of the herbicide was slow under the conditions of …