Physical Sciences and Mathematics Commons^™

Oxidation Pathways Of Monosulfidic Black Ooze, Diane Fyfe, Leigh Sullivan, Richard Bush, Nicholas Ward

Dr Nicholas J Ward

Monosulfidic Black Ooze (MBO) describes an organic material, enriched with iron monosulfides, commonly found in Acid Sulfate Soil (ASS) landscapes. Dominating the surficial sediment layer, this highly mobile material is easily incorporated into the water column when disturbed, resulting in severe deoxygenation and acidification. MBO has recently been implicated in massive fish kills associated with flood events in north eastern NSW, Australia. The process of acidification and the formation of intermediate sulfur species have been examined in ASS; however, there is little information on the chemical behaviour of MBO originating from drainage channels in ASS landscapes. Intermediate sulfur species are …

Improved Identification Of Sulfidic Soil Materials By A Modified Incubation Method, Leigh Sullivan, Nicholas Ward, Richard Bush, Edward Burton

Dr Nicholas J Ward

This study examines the acidification behaviour and rate of sulfidic-sulfur oxidation in the incubation method that is currently used in soil taxonomies to identify sulfidic materials, for some clayey textured soil materials. ‘Sulfidic’ in these taxonomies identifies that a soil material is capable of becoming extremely acidic (i.e. pH < 4) as a result of oxidation of sulfide minerals contained in that soil material. As well as examining incubation slabs of acid sulfate soil materials with the standard 10 mm thickness, the utility of thinner (i.e. 2 mm thick) incubation slabs of these soil materials for identification of sulfidic soil materials …

Miscanthus Establishment And Overwintering In The Midwest Usa: A Regional Modeling Study Of Crop Residue Management On Critical Minimum Soil Temperatures, Christopher J. Kucharik, Andy Vanloocke, John D. Lenters, Melissa M. Motew

Andy VanLoocke

Determination Of The Cec In Srs Soils And The Capability Of Epa Model 9081 For Cec Of Acidic Soils, Alexandra Simpson

Alexandra M Simpson

No abstract provided.

Determination Of The Cec In Srs Soils And The Capability Of Epa Model 9081 For Cec Of Acidic Soils, Alexandra Simpson

Alexandra M Simpson

No abstract provided.

Hydro-Geochemical Coupling In Seawater Inundation Acid Sulfate Soils: Mobilisation Of Arsenic And Hysteresis In Iron And Sulfur Cycling, Scott Johnston, Annabelle Keene, Edward Burton, Richard Bush, Leigh Sullivan

Associate Professor Edward D Burton

A large-scale field trial indicates that tidal seawater inundation of coastal acid sulfate soils (CASS) stimulates iron and sulfate reducing conditions, leading to the generation of internal alkalinity and greatly decreasing soil / groundwater acidity. This remediation technique can be considered highly effective from the relatively narrow perspective of decreasing acidity and raising pH. However, a broader perspective reveals that tidal seawater inundation initiates complex and tightly coupled hydrological and geochemical processes within sediments and porewaters. These processes have had a profound effect on the mobilisation, redistribution and transformation of Fe minerals in the landscape (Johnston et al., 2011a) – …

Arsenic Mobilization And Iron Transformations During Sulfidization Of As(V)-Bearing Jarosite, Scott Johnston, Edward Burton, Annabelle Keene, Britta Planer-Friedrich, Andreas Voegelin, Mark Blackford, Greg Lumpkin

Associate Professor Edward D Burton

Jarosite (KFe3(SO4) 2(OH)6) is an important host-phase for As in acid mine drainage (AMD) environments and coastal acid sulfate soils (CASS). In AMD and CASS wetlands, jarosite may encounter S(−II) produced by sulfate reducing bacteria. Here, we examine abiotic sulfidization of As(V)-bearing K-jarosite at pH 4.0, 5.0, 6.5 and 8.0. We quantify the mobilization and speciation of As and identify corresponding Fe mineral transformations. Sulfide-promoted dissolution of jarosite caused release of co-precipitated As and the majority of mobilized As was re-partitioned to a readily exchangeable surface complex (AsEx). In general, maximum As mobilization occurred in the highly sulfidized end-members of …

Climate Change Adaptation Chapter: Marshfield, Massachusetts, Joshua H. Chase, Jonathan G. Cooper, Rory Elizabeth Fitzgerald, Filipe Antunes Lima, Sally R. Miller, Toni Marie Pignatelli

Sally Miller

Climate change, understood as a statistically significant variation in the mean state of the climate or its variability, is the greatest environmental challenge of this generation (Intergovernmental Panel on Climate Change, 2001). Marshfield is already being affected by changes in the climate that will have a profound effect on the town’s economy, public health, coastal resources, natural features, water systems, and public and private infrastructure. Adaptation strategies have been widely recognized as playing an important role in improving a community’s ability to respond to climate stressors by resisting damage and recovering quickly. Based on review of climate projections for the …