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Full-Text Articles in Physical Sciences and Mathematics
Branching Fractions Of The Cn + C3h6 Reaction Using Synchrotron Photoionization Mass Spectrometry: Evidence For The 3-Cyanopropene Product, Adam Trevitt, Talitha Selby, Craig Taatjes, Satchin Soorkia, J Savee, D L Osborn, S R Leone
Branching Fractions Of The Cn + C3h6 Reaction Using Synchrotron Photoionization Mass Spectrometry: Evidence For The 3-Cyanopropene Product, Adam Trevitt, Talitha Selby, Craig Taatjes, Satchin Soorkia, J Savee, D L Osborn, S R Leone
Adam Trevitt
The gas-phase CN + propene reaction is investigated using synchrotron photoionization mass spectrometry (SPIMS) over the 9.8 - 11.5 eV photon energy range. Experiments are conducted at room temperature in 4 Torr of He buffer gas. The CN + propene addition reaction produces two distinct product mass channels, C3H3N and C4H5N, corresponding to CH3 and H elimination, respectively. The CH3 and H elimination channels are measured to have branching fractions of 0.59 + 0.15 and 0.41 + 0.10, respectively. The absolute photoionization cross sections between 9.8 and 11.5 eV are measured for the three considered H-elimination coproducts: 1-, 2-, and …
Site-Specific Covalent Attachment Of Dna To Proteins Using A Photoactivatable Tus-Ter Complex, Dahdah B. Dahdah, Isabelle Morin, Morgane Moreau, Nicholas E. Dixon, Patrick M. Schaeffer
Site-Specific Covalent Attachment Of Dna To Proteins Using A Photoactivatable Tus-Ter Complex, Dahdah B. Dahdah, Isabelle Morin, Morgane Moreau, Nicholas E. Dixon, Patrick M. Schaeffer
Professor Nick E Dixon
Investigations into the photocrosslinking kinetics of the protein Tus with various bromodeoxyuridine-substituted Ter DNA variants highlight the potential use of this complex as a photoactivatable connector between proteins of interest and specific DNA sequences.
Reconstructing Recent Sedimentation In Two Urbanised Coastal Lagoons (Nsw, Australia) Using Radioisotopes And Geochemistry, Brian Jones, H Heijnis, J. Harrison, Suzanne Hollins, S Hankin, Atun Zawadzki
Reconstructing Recent Sedimentation In Two Urbanised Coastal Lagoons (Nsw, Australia) Using Radioisotopes And Geochemistry, Brian Jones, H Heijnis, J. Harrison, Suzanne Hollins, S Hankin, Atun Zawadzki
B. G. Jones
In this study, we combined grain size and geochemical analyses with radioisotope analysis of lead-210 (210Pb), caesium-137 (137Cs) and radiocarbon (14C) ages to reconstruct the sedimentation history of two urbanised coastal lagoons in south-east Australia. Towradgi and Fairy Lagoons were both found to exhibit slow initial sedimentation of less than 1 mm year-1 prior to anthropogenic influences. Land clearing in the catchments increased runoff and erosion in the creeks feeding into the estuaries, and has resulted in progradation of fluvial material into the estuarine systems with a marked increase in sedimentation to between 2 and 7 mm year-1. The upper …
Assessing Soil Remobilisation In Catchments Using A 137 Cs-Sediment Hillslope Model, Ava D. Simms, Colin D. Woodroffe, Brian G. Jones, Henk Heijnis, Jennifer Harrison, Rob Mann
Assessing Soil Remobilisation In Catchments Using A 137 Cs-Sediment Hillslope Model, Ava D. Simms, Colin D. Woodroffe, Brian G. Jones, Henk Heijnis, Jennifer Harrison, Rob Mann
B. G. Jones
Soil redistribution studies are important, especially in water supply catchments, because the rate at which denudation is occurring has implications for offsite water quality. However, the extent to which soil is redistributed within the landscape can be difficult to determine. This challenge can be overcome using fallout caesium-137 (137Cs). This paper describes the rates of soil loss and remobilisation in two sub-catchments within the Sydney Basin region, namely Kembla and Kentish Creeks, which drain to the Cordeaux reservoir. The total inventories of 137Cs in catchment soils were determined, a 137Cs-regression equation and a theoretical diffusion and migration model were used …
Investigation Of Large-Scale Washover Of A Small Barrier System On The Southeast Australian Coast Using Ground Penetrating Radar, Brian G. Jones, C Bristow, Adam D. Switzer
Investigation Of Large-Scale Washover Of A Small Barrier System On The Southeast Australian Coast Using Ground Penetrating Radar, Brian G. Jones, C Bristow, Adam D. Switzer
B. G. Jones
Prehistoric depositional signatures for large-scale washover involving marine inundation events such as storm and tsunami have been the subject of considerable research over the last 15 years. Much of this research has focused on the identification of sand sheets in back-barrier environments as depositional records for extreme washover events. All these deposits must have a sediment source, and by their nature, the most likely source of sediment for washover into back-barrier environments is the barrier itself. This study identifies an erosional signature for large-scale washover from a small coastal barrier on the southeast Australian coast. A distinct lense of marine …
A Dual-Aliquot Regenerative-Dose Protocol (Dap) For Thermoluminescence (Tl) Dating Of Quartz Sediments Using The Light-Sensitive And Isothermally Stimulated Red Emissions, Richard Roberts, Kira Westaway
A Dual-Aliquot Regenerative-Dose Protocol (Dap) For Thermoluminescence (Tl) Dating Of Quartz Sediments Using The Light-Sensitive And Isothermally Stimulated Red Emissions, Richard Roberts, Kira Westaway
Richard G Roberts
No abstract provided.
Fabrication Of Chemical Sensors Using Inkjet Printing And Application To Gas Detection, Karl H. Crowley, Aoife Morrin, Malcolm R. Smyth, Anthony J. Killard, Roderick Shepherd, Marc In Het Panhuis, Gordon G. Wallace
Fabrication Of Chemical Sensors Using Inkjet Printing And Application To Gas Detection, Karl H. Crowley, Aoife Morrin, Malcolm R. Smyth, Anthony J. Killard, Roderick Shepherd, Marc In Het Panhuis, Gordon G. Wallace
Gordon Wallace
This work describes the fabrication of gas sensors using inkjet printing. Sensors were constructed by building up a film of sensing material, such as polyaniline, from aqueous nanoparticulate dispersions. These films were printed over patterned silver interdigitated array designs for the purposes of conductimetric analysis. Unlike screen printing or lithography, inkjet printing does not require stencils or masks, therefore allowing rapid design and prototyping. For this study, polyaniline and modified polyaniline sensors were inkjet printed and assessed for the purposes of gas sensing applications, specifically hydrogen sulfide monitoring.
Photocatalytic Oxidation Of Methanol Using Titanium Dioxide/Single-Walled Carbon Nanotube Composite, Jun Chen, Carol M. Lynam, Chonlada Dechakiatkrai, Gordon G. Wallace, Sukon Phanichphant
Photocatalytic Oxidation Of Methanol Using Titanium Dioxide/Single-Walled Carbon Nanotube Composite, Jun Chen, Carol M. Lynam, Chonlada Dechakiatkrai, Gordon G. Wallace, Sukon Phanichphant
Gordon Wallace
Titanium dioxide/single-walled carbon nanotube TiO2/SWNT composites were prepared for photocatalytic applications. Thecomposites were characterized using UV-visible and Raman spectroscopy, zeta-potential measurements, cyclic voltammetrycoupled with a photoreactor, scanning electron microscopy, and transmission electron microscopy coupled with energy dispersiveX-ray spectroscopy. The photocatalytic activity of TiO2 and the TiO2/SWNT composite was investigated using the photo-oxidationof methanol in sulfuric acid as supporting electrolyte. The results indicate that the TiO2/SWNT composite enhances the photocatalyticactivity compared to TiO2 alone. Electrochemical studies of the TiO2/SWNT composite were also carried out in varioussupporting electrolytes and the presence of SWNTs was shown to increase the current achieved in voltammetric …