Physical Sciences and Mathematics Commons^™

The Use Of Green Pond Conglomerate As Building Stone In Morris County, New Jersey, Gregory A. Pope

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Green Pond Conglomerate (GPC) is a maroon colored quartzite with white quartz pebbles, a classic “puddingstone”. GPC derives from a NW-SW-trending sliver of Paleozoic sediments, the “Green Pond Outlier”, surrounded by older metamorphic and igneous rocks of Morris and Passaic Counties. Buildings, retaining walls, field fences, and monuments incorporate the durable and attractive stone, in a distinct geographic area of Morris County. Several instances of structures completely constructed or faced with GPC occur in and around Morristown, limited to affluent houses and one prominent church. In these cases, GPC stones were dressed and faced, a labor-intensive effort. Elsewhere in the …

Effect Of Foliar Spray Application Of Zinc Oxide Nanoparticles On Quantitative, Nutritional, And Physiological Parameters Of Foxtail Millet (Setaria Italica L.) Under Field Conditions, Marek Kolenčík, Dávid Ernst, Matej Komár, Martin Šebesta, Martin Urík, Edmund Dobročka, Ivan Černý, Ramakanth Illa, Raghavendra Kanike, Qian Yu, Huan Feng, Denisa Orlová, Gabriela Kratošová

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

It has been shown that the foliar application of inorganic nano-materials on cereal plants during their growth cycle enhances the rate of plant productivity by providing a micro-nutrient source. We therefore studied the effects of foliarly applied ZnO nanoparticles (ZnO NPs) on Setaria italica L. foxtail millet’s quantitative, nutritional, and physiological parameters. Scanning electron microscopy showed that the ZnO NPs have an average particle size under 20 nm and dominant spherically shaped morphology. Energy dispersive X-ray spectrometry then confirmed ZnO NP homogeneity, and X-ray diffraction verified their high crystalline and wurtzite-structure symmetry. Although plant height, thousand grain weight, and grain …

A Sub-Millennial Sediment Record Of Ice-Stream Retreat And Meltwater Storage In The Baltic Ice Lake During The Bølling-Allerød Interstadial, April Lynn Kelly, Sandra Passchier

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The rapid retreat of the Baltic Ice Stream and the development of the Baltic Ice Lake is assessed using data from sediment cores retrieved from three sub-basins in the southern Baltic Sea. Hydraulic piston coring by the International Ocean Discovery Program (IODP) recovered for the first time intact glacial lake sequences overlying diamictons and other ice-contact deposits at Sites M0063, M0064 and M0065. Based on the particle size and bulk sediment chemical composition the glacial lake sediments were subdivided into a proximal and a distal varve sequence. The origin of a dark, lithologically distinct horizon between the proximal and distal …

A Sedimentological Record Of Early Miocene Ice Advance And Retreat, And-2a Drill Hole, Mcmurdo Sound, Antarctica, B. D. Field, G. H. Browne, Christopher R. Fielding, Fabio Florindo, David M. Harwood, Shelley Judge, Lawrence Krissek, Kurt S. Panter, Sandra Passchier, Stephen Pekar, Sonia Sandroni, Franco M. Talarico

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lowest 501 m (∼1139–638 m) of the AND-2A core from southern McMurdo Sound is the most detailed and complete record of early Miocene sediments in Antarctica and indicates substantial variability in Antarctic ice sheet activity during early Miocene time. There are two main pulses of diamictite accumulation recorded in the core, and three significant intervals with almost no coarse clasts. Each diamictite package comprises several sequences consistent with ice advance-retreat episodes.

The oldest phase of diamictite deposition, Composite Sequence 1 (CS1), has evidence for grounded ice at the drill site and has been dated around 20.2–20.1 Ma. It likely …

Microfeatures Of Modern Sea-Ice-Rafted Sediment And Implications For Paleo-Sea-Ice Reconstructions, Kristen E. St. John, Sandra Passchier, Brooke Tantillo, Dennis Darby, Lance Kearns

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Distinguishing sea-ice-rafted debris (SIRD) from iceberg-rafted debris is crucial to an interpretation of ice-rafting history; however, there are few paleo-sea-ice proxies. This study characterizes quartz grain microfeatures of modern SIRD from the Arctic Ocean, and compares these results with microfeatures from representative glacial deposits to potentially differentiate SIRD from ice-rafted sediments which have been recently subjected to glacial processes. This allows us to evaluate the use of grain microfeatures as a paleo-sea-ice proxy. SIRD grains were largely subrounded, with medium relief, pervasive silica dissolution and a high abundance of breakage blocks and microlayering. The glacial grains were more angular, with …

Morphodynamic Modeling Of Fluvial Channel Fill And Avulsion Time Scales During Early Holocene Transgression, As Substantiated By The Incised Valley Stratigraphy Of The Trinity River, Texas, Kaitlin Moran, Jeffrey Nittrouer, Mauricio Perillo, Jorge Lorenzo Trueba, John Anderson

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The Trinity River system provides a natural laboratory for linking fluvial morphodynamics to stratigraphy produced by sea-level rise, because the sediments occupying the Trinity incised valley are well constrained in terms of timing of deposition and facies distribution. Herein, the Trinity River is modeled for a range of base-level rise rates, avulsion thresholds, and water discharges to explore the effects of backwater-induced in-channel sedimentation on channel avulsion. The findings are compared to observed sediment facies to evaluate the capability of a morphodynamic model to reproduce sediment deposition patterns. Base-level rise produces mobile locations of in-channel sedimentation and deltaic channel avulsions. …

Anthropogenic Controls On Overwash Deposition: Evidence And Consequences, Laura Rogers, Laura Moore, Evan Goldstein, Christopher Hein, Jorge Lorenzo Trueba, Andrew Ashton

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Accelerated sea level rise and the potential for an increase in frequency of the most intense hurricanes due to climate change threaten the vitality and habitability of barrier islands by lowering their relative elevation and altering frequency of overwash. High-density development may further increase island vulnerability by restricting delivery of overwash to the subaerial island. We analyzed pre-Hurricane Sandy and post-Hurricane Sandy (2012) lidar surveys of the New Jersey coast to assess human influence on barrier overwash, comparing natural environments to two developed environments (commercial and residential) using shore-perpendicular topographic profiles. The volumes of overwash delivered to residential and commercial …

Rollover, Drowning, And Discontinuous Retreat: Distinct Modes Of Barrier Response To Sea-Level Rise Arising From A Simple Morphodynamic Model, Jorge Lorenzo Trueba, Andrew Dale Ashton

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

We construct a simple morphodynamic model to investigate the long-term dynamic evolution of a coastal barrier system experiencing sea-level rise. Using a simplified barrier geometry, the model includes a dynamic shoreface profile that can be out of equilibrium and explicitly treats barrier sediment overwash as a flux. With barrier behavior primarily controlled by the maximum potential overwash flux and the rate of shoreface response, the modeled barrier system demonstrates four primary behaviors: height drowning, width drowning, constant landward retreat, and a periodic retreat. Height drowning occurs when overwash fluxes are insufficient to maintain the landward migration rate required to keep …

Orbitally Paced Shifts In The Particle Size Of Antarctic Continental Shelf Sediments In Response To Ice Dynamics During The Miocene Climatic Optimum, Sandra Passchier, Candice J. Falk, Fabio Florindo

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The AND-2A drill hole (ANDRILL [Antarctic Geological Drilling Program] Southern McMurdo Sound Project), ∼10 km from the East Antarctica coastline, records nearly 6 m.y. of sedimentation across the Miocene climatic optimum at a high-latitude site. Sedimentological studies of bedforms and particle size distributions indicate that the paleoenvironment was strongly affected by waves and currents, consistent with deposition in a glacially influenced neritic environment. We document abrupt shifts in mud percent within glacial-interglacial cycles ca. 17.8 Ma and between ca. 16.7 and 15.7 Ma that we attribute to the hydrodynamic effects of wave stirring tied to episodes of ice growth and …

Exploring The Role Of Organic Matter Accumulation On Delta Evolution, Jorge Lorenzo Trueba, Vaughan Voller, Chris Paola, Robert Twilley, Azure Bevington

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

We explore the role of plant matter accumulation in the sediment column in determining the response of fluvial-deltas to base-level rise and simple subsidence profiles. Making the assumption that delta building processes operate to preserve the geometry of the delta plain, we model organic sedimentation in terms of the plant matter accumulation and accommodation (space made for sediment deposition) rates. A spatial integration of the organic sedimentation, added to the known river sediment input, leads to a model of delta evolution that estimates the fraction of organic sediments preserved in the delta. The model predicts that the maximum organic fraction …

The Vinylguaiacol/Indole Or Vgi ("Veggie") Ratio: Assessing Relative Contributions Of Terrestrial And Aquatic Organic Matter To Sediments, Michael A. Kruge, Kevin K. Olsen, Jaroslaw W. Slusarczyk, Elaine Gomez

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

In studies of the organic matter (OM) fraction of marine, estuarine, fluvial, or lacustrine sediments, one of the most fundamental distinctions to be made is that between terrestrial and aquatic OM. To supplement the parameters commonly used for this purpose (e.g., C/N and stable isotope ratios), we proposed the Vinylguaiacol/Indole or VGI ("Veggie") ratio, defined as [vinylguaiacol / (indole + vinylguaiacol)] using data produced by analytical pyrolysis-gas chromatography/mass spectrometry of dried, homogenized sediment samples [1]. The ratio employs the peak areas of these two compounds on the mass chromatograms of their molecular ions (m/z 150 and 117, respectively). Major pyrolysis …

The Vinylguaiacol/Indole Or Vgi ("Veggie") Ratio: A Novel Molecular Parameter To Evaluate The Relative Contributions Of Terrestrial And Aquatic Organic Matter To Sediments., Michael A. Kruge, Kevin K. Olsen, Jaroslaw W. Slusarczyk, Elaine Gomez

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The organic matter (OM) fraction of estuarine sediments is often distinctive and thus diagnostically useful in determinations of sedimentary provenance. Among the most fundamental distinctions to be made is that between terrestrial and aquatic OM. To supplement the parameters commonly used for this purpose (e.g., C/N and stable isotope ratios), we proposed the Vinylguaiacol/Indole or VGI ("Veggie") ratio, defined as [vinylguaiacol / (indole + vinylguaiacol)] using data produced by analytical pyrolysis-gas chromatography/mass spectrometry of dried, homogenized sediment samples. The ratio employs the peak areas of these two compounds on the mass chromatograms of their molecular ions (m/z 150 and 117). …

Organic Geochemical Analysis Of Late-Glacial And Early-Holocene Ecosystem Changes: A Case Study From Northern New England Lakes, Michael A. Kruge, Andrea Lini

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

The lacustrine sedimentary archive of organic remains provides important evidence for the reconstruction of the environmental histories of lakes and their watersheds, recording the response of the Earth's biota to changes on scales varying from the local to the global. The last Glacial-Interglacial transition presents an opportunity to investigate how, and at what rates, watershed and lake ecosystems were established on once glaciated, carbon and nutrient-poor landscapes. The small lakes of northern Vermont (USA) provide an appropriate setting in which to investigate such changes.

As part of a multidisciplinary study of three Vermont lake sediment cores, samples ranging in age …

An Environmental Geochemical Study Of Connecticut Marsh Sediments, Nicole A. Heller, Michael A. Kruge, Johan C. Varekamp, Tabitha Zierzow

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Core material from Spartina-dominated Housatonic and Connecticut River estuarine sites (ranging from low to high marsh) were investigated in order to test the hypothesis that organic and inorganic pollutants preferentially accumulate in the low marsh environment. Radiometric data indicate that the low marsh setting experienced sedimentation rates an order of magnitude greater than that of the mid to high marsh. The low marsh sediments from the Housatonic tend to have significantly higher concentrations of trace metals (e.g., Cu and Zn, likely contributed by brass mills formerly active upstream). Petrographic examination of the samples under reflected white and blue light …

Multibeam Sonar Backscatter Lineaments And Anthropogenic Organic Components In Lacustrine Silty Clay, Evidence Of Shipping In Western Lake Ontario, C F Michael Lewis, L A. Mayer, Prasanta K. Mukhopadhyay, Michael A. Kruge, John P. Coakley, M D. Smith

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

A multibeam sonar survey (95 kHz) covering more than 500 km² of western Lake Ontario revealed anomalous lineaments of relatively high backscatter. The lineaments did not align with or parallel the most prominent structural zones beneath the lake as expected. Instead, the principal lineaments lay on lines between ports on opposite sides of the lake, especially between Toronto and Welland Canal, and Toronto and Niagara River mouth. As the lineaments underlie current and historical shipping routes used during the steamship era, they are interpreted as an acoustic response to shipping debris cumulated in the near-surface bottom sediment. An exploratory …

Classification Of Torbanite And Cannel Coal. Ii. Insights From Organic Geochemical And Multivariate Statistical Analysis, Zhiwen Han, Michael A. Kruge

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Petrographic and megascopic criteria have traditionally been used as the basis for the classification of torbanite and cannel coal. For this study, it was hypothesized that modern analytical organic geochemical and multivariate statistical techniques could provide an alternative approach. Towards this end, the demineralized residues of 14 torbanite (rich in Botryococcus-related alginite) and cannel (essentially, rich in organic groundmass and/or sporinite) coal samples were analyzed by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Cluster analysis performed on the Py-GC/MS data clearly distinguished the torbanite from the cannel coal, demonstrating a consistency between the chemical properties and the petrographic composition. All the torbanite …

Classification Of Torbanite And Cannel Coal. I. Insights From Petrographic Analysis Of Density Fractions., Zhiwen Han, Michael A. Kruge, John C. Crelling, David F. Bensley

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Torbanite and cannel coal are considered to be coals because of their low mineral content and overall physical morphology. However, the texture and composition of the organic matter in torbanite and cannel coal are similar to the kerogen occurring in oil shales and lacustrine source rocks. Therefore, understanding the nature and origin of organic components in torbanite and cannel coal is of significance in the study of kerogen and petroleum formation. In this research, a set of torbanites and cannel coals from different locations throughout the world were petrographically characterized and processed using a density gradient centrifugation (DGC) technique. Microscopically, …

Environmental And Botanical Controls On Peatification - A Comparative Study Of Two New Zealand Restiad Bogs Using Py-Gc/Ms, Petrography And Fungal Analysis, Tomasz K. Kuder, Michael A. Kruge, J C. Shearer, S L. Miller

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

This study shows that chemical properties of two restiad species, Empodisma minus and Sporadanthus traversii, may contribute to their success as peat-formers in a climate of the North Island of New Zealand which is not conducive to raised mire development. Unlike Sphagnum, the equivalent northern hemisphere peat-former, restiads possess lignin in their tissues. In addition, the presence of non-lignin polyphenols (including tannins and phenolic acids) in restiads may be an important factor in peat formation due to the allelopathic decay retardation. Patterns of degradation of plant biopolymers have been examined and the pathway of degradation of monocotyledons (loss …

A Molecular Evaluation Of Contaminants And Natural Organic Matter In Surface Sediments From Western Lake Ontario, Michael A. Kruge, Prasanta K. Mukhopadhyay, C.F. Michael Lewis

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Pyrolysis-gas chromatography-mass spectrometry (Py-GC/MS) analysis of bottom sediment from Lake Ontario was shown to be effective in assessing organic contaminants, especially attractive as it is a rapid technique requiring little sample preparation. Pyrolyzates of samples richer in organic matter (OM) were relatively enriched in aliphatic hydrocarbons and pyrrolic nitrogen compounds, while leaner samples were more aromatic and pyridinic. Alkylbenzene and alkylphenol distributions in the pyrolyzates were most compatible with derivation from aquatic (algal, bacterial) OM. The organonitrogen compounds indicated the presence of degraded proteinaceous material from aquatic sources and/or sewage. Normal and polycyclic aromatic hydrocarbon distributions indicate, at least in …

Application Of Environmental Organic Petrology And Geochemistry To Fingerprint Organic Pollutants In The Recent Sediments Of Lake Ontario, Prasanta K. Mukhopadhyay, Michael A. Kruge, C.F. Michael Lewis

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

Selected surface sediment samples (sediment depth 0-10 cm) collected in the Niagara basin (western Lake Ontario) were chosen for organic matter characterization using organic petrological and geochemical techniques normally reserved for the study of coal, petroleum source rock and crude oil. The study was performed to assess the effectiveness of these techniques in discriminating between natural and anthropogenic organic matter and to determine the extent of organic pollution of the lake sediments. The organic carbon contents of the samples vary from 1.5 to 3.5%, with upper layer (0-5 cm) samples have higher TOC values than those from the lower layer …

Flash Pyrolysis Of Anthropogenic And Natural Organic Matter In Polluted Sediments, Sami T. Abdel Bagi, Michael A. Kruge, Gary L. Salmon

Department of Earth and Environmental Studies Faculty Scholarship and Creative Works

INTRODUCTION - Combustion products along with spilled petroleum and industrial chemicals contribute to environmental degradation by contaminating soils and sediments. Such anthropogenic organic matter (OM), if preserved in sediments, can serve an archival function, documenting the local, history of industrial pollution. Christensen and Zhang (1993) determined the sources of polycyclic aromatic hydrocarbons (P AH) to Lake Michigan from sedimentary records, finding that coal combustion was a major source for PAHs in these sediments. Bodzek and Luks-Betlej (1993) reported that atmospheric deposition is the main source of PAH in soils of the heavily industrialized Upper Silesia region of Poland. Smith and …