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The Effect Of Hydrogen Peroxide On The Corrosion Dynamics Of Carbon Steel, Kwang Soak Gabriel O'Donnell
The Effect Of Hydrogen Peroxide On The Corrosion Dynamics Of Carbon Steel, Kwang Soak Gabriel O'Donnell
Electronic Thesis and Dissertation Repository
The Used Fuel Container (UFC) is a key barrier in Canada’s nuclear fuel disposal plan. Understanding the radiation-induced corrosion of the carbon steel (CS) vessel is critical for predicting the long-term integrity of the UFC. Developing a mechanistic understanding of CS corrosion and the effect of solution parameters is essential.
This work investigates the effects of H2O2, the key radiolytic oxidant, on CS corrosion dynamics in small, stagnant solutions. Elementary processes are identified, corrosion rates are calculated, and the effects of H2O2 concentration are investigated. Corrosion was studied by quantifying the concentrations of …