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Full-Text Articles in Physical Sciences and Mathematics

The Kinetics Following Photolysis Of Nitrosyl Bromide, Lori A. Mahoney Dec 2004

The Kinetics Following Photolysis Of Nitrosyl Bromide, Lori A. Mahoney

Theses and Dissertations

One candidate for the development of a tunable laser in the mid-infrared for use as a defensive countermeasure against passive sensors exploits the nitric oxide (NO) transition at 5.4 μm. However, the difficulty with this mechanism is that when bromine (Br2) and NO are present in a mixture, nitrosyl bromide (BrNO) is also created. The absorption bands present in BrNO complicate the design of such a laser. This thesis determines the forward and reverse rate constants of the reaction of Br2 and NO to form BrNO following the photolysis of BrNO using Fourier Transform Infrared absorption spectroscopy. …


Scaling And Characterization Of Direct Current Glow Discharge Plasma In Atmospheric Air, Abdel-Aleam Hefney Mohamed Apr 2004

Scaling And Characterization Of Direct Current Glow Discharge Plasma In Atmospheric Air, Abdel-Aleam Hefney Mohamed

Electrical & Computer Engineering Theses & Dissertations

A microhollow cathode discharge was used as a plasma cathode to sustain a stable direct current glow discharge in atmospheric pressure air. The volumetric scale of glow discharge increased from the millimeter to the centimeter range by extending the plasma in lateral and axial directions. In the axial direction, the length of the glow discharge column was varied from 1 mm to 2 cm, with the sustaining voltage increasing linearly with the glow discharge column length. Extension in the lateral direction was obtained by operating discharges in parallel. The glow discharge plasma of the parallel discharge columns was found to …


Microdischarge Arrays, Wenhui Shi Apr 2004

Microdischarge Arrays, Wenhui Shi

Electrical & Computer Engineering Theses & Dissertations

Microhollow cathode discharges (MHCDs) are DC or pulsed gas discharges between two electrodes, separated by a dielectric, and containing a concentric hole. The diameter of the hole, in this hollow cathode configuration, is in the hundred-micrometer range. MHCDs satisfy the two conditions necessary for an efficient excimer radiation sources: (1) high energy electrons which are required to provide a high concentration of excited or ionized rare gas atoms; (2) high pressure operation which favors excimer formation (a three-body process). Flat panel excimer sources require parallel operation of MHCDs. Based on the current-voltage characteristics of MHCD discharges, which have positive slopes …


Control Of Integrable Hamiltonian Systems And Degenerate Bifurcations, Christopher W. Kulp Jan 2004

Control Of Integrable Hamiltonian Systems And Degenerate Bifurcations, Christopher W. Kulp

Dissertations, Theses, and Masters Projects

In this dissertation, we study the control of near-integrable systems. A near-integrable system is one whose phase space has a similar structure to an integrable system during short time periods and for some parameter regime. We begin by studying the control of integrable Hamiltonian systems. The controller targets an exact solution to the integrable system using dissipative and conservative terms. We find that a Takens-Bogdanov bifurcation occurs in the limit of no dissipative control. The presence of a Takens-Bogdanov bifurcation implies that the control is highly susceptible to noise. We illustrate our results using a two- and four-dimensional integrable systems …


Ultraviolet Sources For Advanced Applications In The Vacuum Uv And Near Uv, Sheng Peng Jan 2004

Ultraviolet Sources For Advanced Applications In The Vacuum Uv And Near Uv, Sheng Peng

Dissertations, Theses, and Masters Projects

This dissertation documents a systematic study consisting of experimental investigations and theoretical analyses of intense ultraviolet sources in VUV and near-UV. Some engineering issues regarding two prototypes of electrodeless lamps using rf and microwave are discussed.;Various excimers that produce intense UV light are investigated, including: (1) A benchmark Xe2 excimer which has been proven to be very efficient in our novel rf capacitively coupled discharge lamp; (2) A rarely studied excimer, KrI, which suffers from predissociation and was reported to be very weak or invisible by most of other studies; (3) XeI excimer whose emission dominates around 253 nm and …