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Full-Text Articles in Physical Sciences and Mathematics
Contributions Of Tunneling In 8Π-6Π Electrocyclic Cascade Reactions Of Bicyclo[4.2.0]Octa-2,4-Diene Moieties, Ishika Jain, Claire Castro, William L. Karney
Contributions Of Tunneling In 8Π-6Π Electrocyclic Cascade Reactions Of Bicyclo[4.2.0]Octa-2,4-Diene Moieties, Ishika Jain, Claire Castro, William L. Karney
Featured Student Work
Six-electron electrocyclic reactions usually require relatively high temperatures; however recent research has shown that such reactions can occur at significantly lower temperatures in biosynthetic and biomimetic pathways. Pathways resulting in bicyclo[4.2.0]octa-2,4-diene moieties arise from thermally allowed 8π-6π electrocyclization cascade reactions of 1,3,5,7-octatetraenes, as in the biosynthesis of endiandric acids, elysiapyrones, and numerous other natural products. We report multidimensional tunneling calculations to explore the possible contribution of heavy-atom tunneling (e.g. by carbon) to biosynthetic pathways and biomimetic syntheses, and thus to provide a more complete picture of biochemical kinetics. M06-2X/cc-pVDZ calculations on the 8π-6π cascade cyclizations of methylated octatetraene model systems …
First Measurement Of Λ Electroproduction Off Nuclei In The Current And Target Fragmentation Regions, T. Chetry, L. El Fassi, W. K. Brooks, R. Dupré, A. El Alaoui, K. Hafidi, P. Achenbach, K. P. Adhikari, Z. Akbar, W.R. Armstrong, M. Arratia, H. Atac, H. Avakian, L. Baashen, N.A. Baltzell, M. Bashkanov, M. Battaglieri, I. Bedlinsky, B. Benkel, M. Zurek, Et Al., Clas Collaboration
First Measurement Of Λ Electroproduction Off Nuclei In The Current And Target Fragmentation Regions, T. Chetry, L. El Fassi, W. K. Brooks, R. Dupré, A. El Alaoui, K. Hafidi, P. Achenbach, K. P. Adhikari, Z. Akbar, W.R. Armstrong, M. Arratia, H. Atac, H. Avakian, L. Baashen, N.A. Baltzell, M. Bashkanov, M. Battaglieri, I. Bedlinsky, B. Benkel, M. Zurek, Et Al., Clas Collaboration
Physics Faculty Publications
We report results of Λ hyperon production in semi-inclusive deep-inelastic scattering off deuterium, carbon, iron, and lead targets obtained with the CLAS detector and the Continuous Electron Beam Accelerator Facility 5.014 GeV electron beam. These results represent the first measurements of the Λ multiplicity ratio and transverse momentum broadening as a function of the energy fraction (z) in the current and target fragmentation regions. The multiplicity ratio exhibits a strong suppression at high zand an enhancement at low z. The measured transverse momentum broadening is an order of magnitude greater than that seen for light mesons. This …